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Volume 40 Issue 7
Apr.  2023
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SU Xinyue, KONG Cunhui, QING Da, et al. Preparation of Ti3C2/SrTiO3 composites and their photoelectrochemical cathodic protection[J]. Acta Materiae Compositae Sinica, 2023, 40(7): 3964-3972. DOI: 10.13801/j.cnki.fhclxb.20220909.004
Citation: SU Xinyue, KONG Cunhui, QING Da, et al. Preparation of Ti3C2/SrTiO3 composites and their photoelectrochemical cathodic protection[J]. Acta Materiae Compositae Sinica, 2023, 40(7): 3964-3972. DOI: 10.13801/j.cnki.fhclxb.20220909.004
shu

Preparation of Ti3C2/SrTiO3 composites and their photoelectrochemical cathodic protection

  • 1.

    Hebei Province Laboratory of Inorganic Nonmetallic Materials, College of Material Science and Engineering, North China University of Science and Technology, Tangshan 063210, China

  • 2.

    Hebei (Tangshan) Ceramic Industry Technology Research Institute, Tangshan 063007, China

Funds: Natural Science Foundation-Steel and Iron Foundation of Hebei Province (E2021209002); Tangshan Science and Technology Bureau Project (21130211D)
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  • Received Date: July 20, 2022
  • Revised Date: September 01, 2022
  • Accepted Date: September 01, 2022
  • Available Online: September 12, 2022
    Abstract
  • Due to the shortcomings of strontium titanate (SrTiO3) with large band gap and low separation rate of photogenerating carriers, its photoelectrochemical cathodic protection performance is limited. And in order to solve this problem, SrTiO3 can be modified with the supporting cocatalyst Ti3C2. Firstly, SrTiO3 was prepared by hydrothermal method and Ti3C2 was obtained by etching. Then, Ti3C2/SrTiO3 composites were prepared by mechanical mixing. XRD, XPS, SEM, UV-vis DRS, and PL had characterized the phase structure, chemical state, microscopic morphology, and light absorption performance of the samples. Finally, the photoelectrochemical cathodic protection performance of Ti3C2/SrTiO3 composites to 304 stainless steel (304SS) was analyzed. The results show that Ti3C2/SrTiO3 composites are broadened to absorb visible light. Among them, the photogenerated carrier separation rate of the 15%-Ti3C2/SrTiO3 composite with a mass fraction of 15wt% of Ti3C2 has a higher separation rate and an optical current density of 2.5 μA·cm−2. In the 3.5wt% NaCl solution, after the coupling of 304SS to the composite, its photomotive potential drops by 200 mV under light conditions, which can effectively protect 304SS. After four open and closed light cycle tests, the performance of Ti3C2/SrTiO3 composites are stable.
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