Research progress on metal phosphides anode materials for sodium ion batteries

WANG Haihua; JIN Qianqian; SHU Kewei

doi:10.13801/j.cnki.fhclxb.20220120.009

Volume 39 Issue 6

Jun. 2022

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WANG Haihua, JIN Qianqian, SHU Kewei. Research progress on metal phosphides anode materials for sodium ion batteries[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2586-2598. doi: 10.13801/j.cnki.fhclxb.20220120.009

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WANG Haihua, JIN Qianqian, SHU Kewei. Research progress on metal phosphides anode materials for sodium ion batteries[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2586-2598. doi: 10.13801/j.cnki.fhclxb.20220120.009

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Research progress on metal phosphides anode materials for sodium ion batteries

doi: 10.13801/j.cnki.fhclxb.20220120.009

College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China

Received Date: 2021-11-22
Accepted Date: 2022-01-11
Rev Recd Date: 2021-12-24

Available Online: 2022-01-20

Publish Date: 2022-06-01

Abstract

Abstract

Sodium ion batteries (SIBs) have attracted more and more attention because of their low cost and high safety. Due to the extremely high theoretical capacity, phosphorus-based material has been considered as one of the most promising anode materials for SIBs. However, phosphorus has shortcomings such as low conductivity and large volume expansion during sodiation-desodiation cycles, which significantly deteriorate its rate performance and cycle stability. Constructing metal phosphides by combining P with germanium, tin, copper or other metals can not only enhance their conductivity, but also significantly improve the reversibility and cycle performance of phosphorus-based anode materials. In this review, recent progress on metal phosphides and their composites with carbon nanotubes and graphene for SIBs anode materials were summarized. Furthermore, the current issues of metal phosphides anodes for SIBs were discussed, such as low practical capacity, poor cycle performance and so no. Meanwhile, various approaches and techniques to address these issues were proposed, including design and construction of composite materials, surface modification, regulation of size and morphology, advanced in-situ characterizations, etc. Finally, future perspectives of metal phosphides anode materials for SIBs were also presented.
- sodium-ion batteries,
- metal phosphides,
- anode materials,
- composite,
- electrochemical performance
Long Abstrsct
Innovation Points

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References(53)

References

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