Preparation and freeze-thaw damage evolution of n-tetradecane/graphite low-temperature phase change cement-based materials

YU Bentian; CHEN Yanfei; LI Shuangyang; YANG Yuxiang; HU Baichun; LIU Tao

doi:10.13801/j.cnki.fhclxb.20211110.002

Volume 39 Issue 6

Jun. 2022

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YU Bentian, CHEN Yanfei, LI Shuangyang, et al. Preparation and freeze-thaw damage evolution of n-tetradecane/graphite low-temperature phase change cement-based materials[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2864-2874. doi: 10.13801/j.cnki.fhclxb.20211110.002

Citation:

YU Bentian, CHEN Yanfei, LI Shuangyang, et al. Preparation and freeze-thaw damage evolution of n-tetradecane/graphite low-temperature phase change cement-based materials[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2864-2874. doi: 10.13801/j.cnki.fhclxb.20211110.002

Citation:

YU Bentian, CHEN Yanfei, LI Shuangyang, et al. Preparation and freeze-thaw damage evolution of n-tetradecane/graphite low-temperature phase change cement-based materials[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2864-2874. doi: 10.13801/j.cnki.fhclxb.20211110.002

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Preparation and freeze-thaw damage evolution of n-tetradecane/graphite low-temperature phase change cement-based materials

doi: 10.13801/j.cnki.fhclxb.20211110.002

YU Bentian^{1, 2, 3
,
,},
CHEN Yanfei^1
,,
LI Shuangyang⁴,
YANG Yuxiang¹,
HU Baichun⁵,
LIU Tao⁵

1.
School of Civil Engineering, Lanzhou Jiao tong University, Lanzhou 730070, China
2.
China Railway 14th Bureau Group Co. Ltd., Jinan 250014, China
3.
School of Civil Engineering, Southwest Jiao tong University, Chengdu 610031, China
4.
State Key Laboratory of Frozen Soil Engineering, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China
5.
Power China Guiyang Engineering Corporation Limited, Guiyang 550081, China

Received Date: 2021-08-17
Accepted Date: 2021-11-01
Rev Recd Date: 2021-10-30

Available Online: 2021-11-11

Publish Date: 2022-06-01

Abstract

Abstract

C14/EG composite phase change material was prepared by physical adsorption method with n-tetradecane (C14) as phase change material and expanded graphite (EG) as carrier. The micro-morphology, phase change temperature, phase change latent heat and chemical structure of C14/EG composite phase change material were tested by SEM, DSC and FTIR. The quick freeze-thaw cycle tests of phase change energy storage cement-based materials (PCESM) doped (mass ratio to cement) with 0%, 2%, 4% and 6% phase change materials were carried out. The effects of freeze-thaw cycle on the surface damage, mass loss, dynamic modulus loss, compressive strength and pore structure were analyzed, and the deterioration mechanism of PCESM during freeze-thaw cycle was revealed. The experimental results show that C14 can be well adsorbed in the pores of EG, and C14 has good compatibility with EG, and there is no chemical reaction between them. With the increase of C14/EG phase change material content, the porosity increases and the mechanical properties decrease, but the frost resistance increases first and then decreases. The frost resistance of PCESM with 4% C14/EG phase change material is the best.
- phase-change material,
- phase change energy storage cement-based material,
- mechanical properties,
- freezing-thawing cycle,
- pore structure,
- damage
Long Abstrsct
Innovation Points

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References(52)

References

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