Preparation and electrochemical performance of Co Prussian blue analogue/ multi-walled carbon nanotubes nanocomposite for supercapacitors

DU Jiaqi; CHEN Junlin; JI Jiashuai; ZHANG Li; LIU Wei; SONG Zhaoxia

doi:10.13801/j.cnki.fhclxb.20210805.002

Volume 39 Issue 6

Jun. 2022

Turn off MathJax

Article Contents

Article Navigation > Acta Materiae Compositae Sinica > 2022 > 39(6): 2724-2733

DU Jiaqi, CHEN Junlin, JI Jiashuai, et al. Preparation and electrochemical performance of Co Prussian blue analogue/ multi-walled carbon nanotubes nanocomposite for supercapacitors[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2724-2733. doi: 10.13801/j.cnki.fhclxb.20210805.002

Citation:

DU Jiaqi, CHEN Junlin, JI Jiashuai, et al. Preparation and electrochemical performance of Co Prussian blue analogue/ multi-walled carbon nanotubes nanocomposite for supercapacitors[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2724-2733. doi: 10.13801/j.cnki.fhclxb.20210805.002

Citation:

DU Jiaqi, CHEN Junlin, JI Jiashuai, et al. Preparation and electrochemical performance of Co Prussian blue analogue/ multi-walled carbon nanotubes nanocomposite for supercapacitors[J]. Acta Materiae Compositae Sinica, 2022, 39(6): 2724-2733. doi: 10.13801/j.cnki.fhclxb.20210805.002

PDF( 4387 KB)

Preparation and electrochemical performance of Co Prussian blue analogue/ multi-walled carbon nanotubes nanocomposite for supercapacitors

doi: 10.13801/j.cnki.fhclxb.20210805.002

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China
2.
College of Life Science, Dalian Minzu University, Dalian 116600, China

Received Date: 2021-06-11
Accepted Date: 2021-07-24
Rev Recd Date: 2021-07-07

Available Online: 2021-08-05

Publish Date: 2022-06-01

Abstract

Abstract

Co Prussian blue analogue (CoPBA) has attracted much attentions as a promising anode material of supercapacitors due to its high capacity and long cycle life. But CoPBA suffers from poor electrical conductivity, leading to unsatisfied rate performance. A nanocomposite of Co Prussian blue analogue/multi-walled carbon nano-tubes (CoPBA/MWCNT) composite was synthesized using ZIF-67 as a precursor. The structure and morphology of CoPBA/MWCNT were characterized by XRD, SEM and TEM. In a three-electrode system, the specific capacitance of the CoPBA/MWCNT electrode reaches up to 312 F·g⁻¹ at a current density of 1 A·g⁻¹. The fabrication of CoPBA/MWCNT is beneficial for improving electronic conductivity and mechanical stability, resulting in high electrochemical performance. An asymmetric supercapacitor cell is assembled with CoPBA/MWCNT as cathode and activated carbon (AC) as anode. Its capacity retention rate is 83.1% after 5000 cycles, exhibiting excellent cycling stability.
- Co Prussian blue analogue,
- supercapacitor,
- template conversion,
- multi-walled carbon nanotube,
- asymmetric supercapacitor
Long Abstrsct
Innovation Points

FullText(HTML)

References(34)

References

[1]	肖谧, 宿玉鹏, 杜伯学. 超级电容器研究进展[J]. 电子元件与材料, 2019, 38(9):1-12. XIAO Mi, SU Yupeng, DU Boxue. Research progress of supercapacitors[J]. Electronic Components and Materials,2019,38(9):1-12(in Chinese).
[2]	胡方圆, 刘冬明, 李佳乐, 等. 高性能聚合物在新型储能领域的应用进展[J]. 中国材料进展, 2019, 38(10):990-998. HU Fangyuan, LIU Dongming, LI Jiale, et al. Advances in application of high- performance polymers in the new energy storage field[J]. Materials China,2019,38(10):990-998(in Chinese).
[3]	MATHIS T S, KURRA N, WANG X, et al. Energy storage data reporting in perspective-guidelines for interpreting the performance of electrochemical energy storage systems[J]. Advanced Energy Materials,2019,9(39):1902007. doi: 10.1002/aenm.201902007
[4]	WANG J, ZHUANG S, LIU Y. Metal hexacyanoferrates-based adsorbents for cesium removal[J]. Coordination Chemistry Reviews,2018,374:430-438. doi: 10.1016/j.ccr.2018.07.014
[5]	POONAM, SHARMA K, ARORA A, et al. Review of supercapacitors: Materials and devices[J]. Journal of Energy Storage,2019,21:801-825. doi: 10.1016/j.est.2019.01.010
[6]	王攀, 刘羽熙, 王永贵. PPy/MWNTs/GO复合材料的制备与电化学性能研究[J]. 材料科学与工艺, 2016, 24(3):92-96. WANG Pan, LIU Yuxi, WANG Yonggui. Preparation and electrochemical performance of PPy/MWNTs/GO compo-sites[J]. Materials Science & Technology,2016,24(3):92-96(in Chinese).
[7]	刘连梅, 赵健伟, 陈超. 聚苯胺-石墨烯/聚酰亚胺复合导电纱的制备及其超电容特性[J]. 复合材料学报, 2020, 37(4):786-793. LIU Lianmei, ZHAO Jianwei, CHEN Chao. Preparation and supercapacitance characteristics of polyaniline-graphene/polyimide composite conductive yarn[J]. Acta Materiae Compositae Sinica,2020,37(4):786-793(in Chinese).
[8]	张政, 刘洪达, 宋朝霞, 等. 聚苯胺包覆CoFe类普鲁士蓝复合材料的超电容性能[J]. 复合材料学报, 2020, 37(3):731-739. ZHANG Zheng, LIU Hongda, SONG Zhaoxia, et al. Supercapacitive performance of polyaniline coated CoFe Prussian blue analogue composite[J]. Acta Materiae Compositae Sinica,2020,37(3):731-739(in Chinese).
[9]	NAI J, LOU X W. Hollow structures based on prussian blue and its analogs for electrochemical energy storage and conversion[J]. Advanced Materials,2019,31(38):1706825. doi: 10.1002/adma.201706825
[10]	DASSANAYAKE A C, WICKRAMARATNE N P, HOSSAIN M A, et al. Prussian blue-assisted one-pot synthesis of nitrogen-doped mesoporous graphitic carbon spheres for supercapacitors[J]. Journal of Materials Chemistry A,2019,7(38):22092-22102. doi: 10.1039/C9TA08454A
[11]	CHEN J, WEI L, MAHMOOD A, et al. Prussian blue, its analogues and their derived materials for electrochemical energy storage and conversion[J]. Energy Storage Materials,2020,25:585-612. doi: 10.1016/j.ensm.2019.09.024
[12]	LISOWSKA-OLEKSIAK A, NOWAK A P. Metal hexacyanoferrate network synthesized inside polymer matrix for electrochemical capacitors[J]. Journal of Power Sources,2007,173(2):829-836. doi: 10.1016/j.jpowsour.2007.05.046
[13]	ZHAO F, WANG Y, XU X, et al. Cobalt hexacyanoferrate nanoparticles as a high-rate and ultra-stable supercapacitor electrode material[J]. ACS Applied Materials & Interfaces,2014,6(14):11007-11012. doi: 10.1021/am503375h
[14]	WANG J G, ZHANG Z, ZHANG X, et al. Cation exchange formation of prussian blue analogue submicroboxes for high-performance Na-ion hybrid supercapacitors[J]. Nano Energy,2017,39:647-653. doi: 10.1016/j.nanoen.2017.07.055
[15]	SONG Z, LIU W, ZHOU Q, et al. Cobalt hexacyanoferrate/ MnO₂ nanocomposite for asymmetrical supercapacitors with enhanced electrochemical performance and its charge storage mechanism[J]. Journal of Power Sources,2020,465:228266. doi: 10.1016/j.jpowsour.2020.228266
[16]	RAWOOL C R, PUNDE N S, RAJPUROHIT A S, et al. High energy density supercapacitive material based on a ternary hybrid nanocomposite of cobalt hexacyanoferrate/carbon nanofibers/polypyrrole[J]. Electrochimica Acta,2018,268:411-423. doi: 10.1016/j.electacta.2018.02.111
[17]	ZHANG X, TAO L, HE P, et al. A novel cobalt hexacyanoferrate/multi-walled carbon nanotubes nanocomposite: Spontaneous assembly synthesis and application as electrode materials with significantly improved capacitance for supercapacitors[J]. Electrochimica Acta,2018,259:793-802. doi: 10.1016/j.electacta.2017.11.007
[18]	REN L, WANG J G, LIU H, et al. Metal-organic-framework-derived hollow polyhedrons of prussian blue analogues for high power grid-scale energy storage[J]. Electrochimica Acta,2019,321:134671. doi: 10.1016/j.electacta.2019.134671
[19]	DENG L, HAO Z, WANG J, et al. Preparation and capacitance of graphene/multiwall carbon nanotubes/MnO₂ hybrid material for high-performance asymmetrical electrochemical capacitor[J]. Electrochimica Acta,2013,89:191-198. doi: 10.1016/j.electacta.2012.10.106
[20]	KHAN A, ALI M, ILYAS A, et al. ZIF-67 filled PDMS mixed matrix membranes for recovery of ethanol via pervaporation[J]. Separation and Purification Technology,2018,206:50-58.
[21]	KETTLE S F A, DIANA E, MARCHESE E M C, et al. The vibrational spectra of the cyanide ligand revisited: The ν(CN) infrared and Raman spectroscopy of Prussian blue and its analogues[J]. Journal of Raman Spectroscopy,2011,42(11):2006-2014. doi: 10.1002/jrs.2944
[22]	YIN X, LI H, WANG H, et al. Self-templating synthesis of cobalt hexacyanoferrate hollow structures with superior performance for Na-ion hybrid supercapacitors[J]. ACS Applied Materials & Interfaces,2018,10(35):29496-29504.
[23]	LEE P K, NIA P M, WOI P M. Self-assembled Prussian blue-polypyrrole nanocomposites for energy storage application[J]. Journal of Applied Electrochemistry,2019,49(6):631-638. doi: 10.1007/s10800-019-01310-5
[24]	SONG Z, LIU W, YUAN Q, et al. Microporous/mesoporous cobalt hexacyanoferrate nanocubes for long-cycle life asymmetric supercapacitors[J]. Journal of Materials Science: Materials in Electronics,2018,29(17):14897-14905. doi: 10.1007/s10854-018-9628-5
[25]	LU K, SONG B, GAO X, et al. High-energy cobalt hexacyanoferrate and carbon micro-spheres aqueous sodium-ion capacitors[J]. Journal of Power Sources,2016,303:347-353. doi: 10.1016/j.jpowsour.2015.11.031
[26]	ZHANG D, ZHANG J, YANG Z, et al. Nickel hexacyanoferrate/carbon composite as a high-rate and long-life cathode material for aqueous hybrid energy storage[J]. Chemical Communications,2017,53(76):10556-10559. doi: 10.1039/C7CC04914E
[27]	KRISHNAMOORTHY K, PAZHAMALAI P, SAHOO S, et al. A high-energy aqueous sodium-ion capacitor with nickel hexacyanoferrate and graphene electrodes[J]. ChemElectroChem,2017,4(12):1-8.
[28]	MAIER M A, SURESH BABU R, SAMPAIO D M, et al. Binder-free polyaniline interconnected metal hexacyanoferrates nanocomposites (Metal=Ni, Co) on carbon fibers for flexible supercapacitors[J]. Journal of Materials Science: Materials in Electronics,2017,28(23):17405-17413. doi: 10.1007/s10854-017-7674-z
[29]	YAO H, ZHANG F, ZHANG G, et al. A new hexacyanoferrate nanosheet array converted from copper oxide as a high-performance binder-free energy storage electrode[J]. Electrochimica Acta,2019,294:286-296. doi: 10.1016/j.electacta.2018.10.056
[30]	SENTHILKUMAR S T, KIM J, WANG Y, et al. Flexible and wearable fiber shaped high voltage supercapacitors based on copper hexacyanoferrate and porous carbon coated carbon fiber electrodes[J]. Journal of Materials Chemistry A,2016,4(13):4934-4940. doi: 10.1039/C6TA00093B
[31]	元宝. 石墨烯/铁氰化镍电极材料及其非对称超级电容器的组装[D]. 哈尔滨: 哈尔滨工程大学, 2017. YUAN Bao. The assembly of asymmetric supercapacitor based on graphene/nickel hexacyanoferrate composites[D]. Harbin: Harbin Engineering University, 2017(in Chinese).
[32]	LAFORGUE P, SIMON P, FAUVARQUE J F, et al. Activated carbon/conducting polymer hybrid supercapacitors[J]. Journal of the Electrochemical Society,2003,150(5):A645-A651. doi: 10.1149/1.1566411
[33]	XU K, ZOU R, LI W, et al. Design and synthesis of 3D interconnected mesoporous NiCo₂O₄@Co_xNi₁-x(OH)₂ core-shell nanosheet arrays with large areal capacitance and high rate performance for supercapacitors[J]. Journal of Materials Chemistry A,2014,2(26):10090-10097. doi: 10.1039/c4ta01489h
[34]	LIU W, LI X, ZHU M, et al. High-performance all-solid state asymmetric supercapacitor based on Co₃O₄ nanowires and carbon aerogel[J]. Journal of Power Sources,2015,282:179-186. doi: 10.1016/j.jpowsour.2015.02.047