Preparation of ZIF-67/waste cotton cellulose composite aerogels and the removal performance on dyes

ZHAI Jianyu; BAI Wenhao; LI Ang; CUI Ce; GUO Ronghui

doi:10.13801/j.cnki.fhclxb.20210521.001

Volume 39 Issue 3

Mar. 2021

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ZHAI Jianyu, BAI Wenhao, LI Ang, et al. Preparation of ZIF-67/waste cotton cellulose composite aerogels and the removal performance on dyes[J]. Acta Materiae Compositae Sinica, 2022, 39(3): 1259-1267. doi: 10.13801/j.cnki.fhclxb.20210521.001

Citation:

ZHAI Jianyu, BAI Wenhao, LI Ang, et al. Preparation of ZIF-67/waste cotton cellulose composite aerogels and the removal performance on dyes[J]. Acta Materiae Compositae Sinica, 2022, 39(3): 1259-1267. doi: 10.13801/j.cnki.fhclxb.20210521.001

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Preparation of ZIF-67/waste cotton cellulose composite aerogels and the removal performance on dyes

doi: 10.13801/j.cnki.fhclxb.20210521.001

College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China

Received Date: 2021-03-22
Accepted Date: 2021-05-11
Rev Recd Date: 2021-04-29

Available Online: 2021-05-24

Publish Date: 2021-03-01

Abstract

Abstract

In order to efficiently remove organic dyes from waste water, ZIF-67/waste cotton cellulose composite aerogels (ZIF-67/WCCA) were prepared by freeze drying technology using waste cotton fabrics as cellulose raw materials, alkali/urea as dissolution system, N, N’-Methylenediacrylamide (MBA) as cross-linking agent, and cobalt-based zeolite imidazolate metal-organic framework (ZIF-67) nanoparticles were grown in situ on the surface of WCCA. ZIF-67/WCCA were prepared and used to adsorb malachite green (MG) and degrade methylene blue (MB) with peroxymonosulfate (PMS) activation. The structure and composition of the ZIF-67/WCCA were characterized by scanning electron microscopy and X-ray diffraction. The conditions affecting the adsorption and degradation properties of the dyes were also discussed. The results show that ZIF-67 nanoparticles of dodecahedron are loaded on the network framework of cellulose aerogels from waste cotton. The adsorption capacity of MG can reach 1474.01 mg·g⁻¹ at room temperature, and the degradation rate of MB at 100 s can reach 100% by using ZIF-67/WCCA. ZIF-67/WCCA can be applied in fields of dye adsorption and catalytic degradation in sewage.
- waste cotton,
- cellulose aerogel,
- ZIF-67,
- dye,
- adsorption,
- catalytic degradation
Long Abstrsct
Innovation Points

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References(25)

References

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