Volume 38 Issue 12
Dec.  2021
Turn off MathJax
Article Contents
XIAO Wei, ZHANG Kejie, FU Yangjie, et al. Preparation of Bi/WO3 composite photocatalytic materials with antibacterial properties[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4198-4204. doi: 10.13801/j.cnki.fhclxb.20210312.002
Citation: XIAO Wei, ZHANG Kejie, FU Yangjie, et al. Preparation of Bi/WO3 composite photocatalytic materials with antibacterial properties[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4198-4204. doi: 10.13801/j.cnki.fhclxb.20210312.002

Preparation of Bi/WO3 composite photocatalytic materials with antibacterial properties

doi: 10.13801/j.cnki.fhclxb.20210312.002
  • Received Date: 2020-12-30
  • Accepted Date: 2021-02-23
  • Available Online: 2021-03-12
  • Publish Date: 2021-12-01
  • Bi/WO3 composite materials with visible-light-response were prepared. Semi-metal Bi0 with SPR effect was deposited on WO3 surface via UV reduction method using bismuth pentahydrate Bi(NO3)3·5H2O as bismuth source. Using E. coli and S. aureus as experimental objects, the photocatalytic antibacterial properties of the prepared composite materials were investigated, and the Bi loading amount was optimized via considering both the structure and photoelectrochemical properties. It is found that 0.6 mmol Bi/WO3 can kill more than 99% of bacteria within 120 min. The antibacterial mechanism was further investigated. By adding different kinds of capture agents and combining with electron spin resonance (ESR) technology, it is found that hydroxyl radical (·OH) and superoxide radical (·O2) are the main active species causing E. coli deactivation.

     

  • loading
  • [1]
    XIONG H, ZHOU H, SUN G, et al. Solvent-free self-assembly for scalable preparation of highly crystalline mesoporous metal oxides[J]. Angewandte Chemie International Edtion. in English,2020,27(59):11053-11060.
    [2]
    MOHAMMADI S, SOHRABI M, GOLIKAND A N, et al. Preparation and characterization of zinc and copper co-doped WO3 nanoparticles: Application in photocatalysis and photobiology[J]. Journal of Photochemistry and Photobiology B: Biology,2016(161):217-221.
    [3]
    WANG P, HUANG B, QIN X, et al. Ag/AgBr/WO3·H2O: Visible-light photo-catalyst for bacteria destruction[J]. Inorganic Chemistry,2009,22(48):10697-10702.
    [4]
    ZHU W, LIU J, YU S, et al. Ag loaded WO3 nanoplates for efficient photocatalytic degradation of sulfanilamide and their bactericidal effect under visible light irradiation[J]. Journal of Hazardous Materials,2016(318):407-416.
    [5]
    ARSHAD M, BILAL M, AHMAD N, et al. Synthesis and characteri-zation of Zn doped WO3 nanoparticles: Photocatalytic, antifungal and antibacterial activities evaluation[J]. Materials Research Express,2020,1(7):015407.
    [6]
    MOHAMMADI S, SOHRABI M, et al. Preparation and characterization of zinc and copper co-doped WO3 nanoparticles: Application in photocatalysis and photobiology[J]. Journal of Photochemistry and Photobiology B: Biology, 2016, 161: 217-221.
    [7]
    HASHEMI E, POURSALEHI R, DELAVARI H. Formation mechanisms, structural and optical properties of Bi/Bi2O3 one dimensional nanostructures prepared via oriented aggregation of bismuth based nanoparticles synthesized by DC arc discharge in water[J]. Materials Science in Semiconductor Processing,2019(89):51-58.
    [8]
    CHANG C, ZHU L, FU Y, et al. Highly active Bi/BiOI composite synthesized by one-step reaction and its capacity to degrade bisphenol a under simulated solar light irradiation[J]. Chemical Engineering Journal,2013(233):305-314.
    [9]
    CUI Z, DONG X, SUN Y, et al. Simultaneous introduction of oxygen vacancies and Bi metal onto the facet of Bi3O4Cl woven nanobelts for synergistically enhanced photocatalysis[J]. Nanoscale,2018,35(10):16928-16934.
    [10]
    ZHOU Y, REN S, DONG Q, et al. One-pot preparation of Bi/Bi2WO6 reduced graphene oxide as a plasmonic photocatalyst with improved activity under visible light[J]. RSC Advances,2016,105(6):102875-102885.
    [11]
    MAO J, ZHANG Q, LI P, et al. Geometric architecture design of ternary composites based on dispersive WO3 nanowires for enhanced visible-light-driven activity of refractory pollutant degradation[J]. Chemical Engineering Journal,2018(334):2568-2578.
    [12]
    KARIMI-NAZARABAD M, GOHARSHADI E K, ENTEZARI M H, et al. Rheological properties of the nanofluids of tungsten oxide nanoparticles in ethylene glycol and glycerol[J]. Microfluidics and Nanofluidics,2015,5(19):1191-1202.
    [13]
    WANG Q, WU H, GAO Q Y, et al. Fabrication of visible-light-active Bi/BiOI-Bi2O3 composite with enhanced photocatalytic activity[J]. Journal of Colloid and Interface Science,2019(548):255-264.
    [14]
    WANG J, TANG L, ZENG G, et al. Plasmonic Bi metal deposition and g-C3N4 coating on Bi2WO6 microspheres for efficient visible-light photocatalysis[J]. ACS Sustainable Chemistry & Engineering,2016,1(5):1062-1072.
    [15]
    JIANG L, YUAN X, ZENG G, et al. In-situ synthesis of direct solid-state dual Z-scheme WO3/g-C3N4/Bi2O3 photocatalyst for the degradation of refractory pollutant[J]. Applied Catalysis B: Environmental,2018(227):376-385.
    [16]
    LIU X, XIONG X, DING S, et al. Bi metal-modified Bi4O5I2 hierarchical microspheres with oxygen vacancies for improved photocatalytic performance and mechanism insights[J]. Catalysis Science & Technology,2017,16(7):3580-3590.
    [17]
    DI L, YANG H, XIAN T, et al. Photocatalytic and photo-Fenton catalytic degradation activities of Z-scheme Ag2S/BiFeO3 Heterojunction composites under visible-light irradiation[J]. Nanomaterials,2019,3(9):399.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)

    Article Metrics

    Article views (1188) PDF downloads(55) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return