HUANG Jun, JIANG De-sheng, GUAN Jian-guo, et al. COMPLEX MECHANISM OF PHTHALOCYANINE NICKEL WITH Fe3O4 NANOPARTICLES AND THE STRUCTURE MODEL OF THE NANOPARTICLES COMPOSITE[J]. Acta Materiae Compositae Sinica, 2001, 18(2): 81-84.
Citation: HUANG Jun, JIANG De-sheng, GUAN Jian-guo, et al. COMPLEX MECHANISM OF PHTHALOCYANINE NICKEL WITH Fe3O4 NANOPARTICLES AND THE STRUCTURE MODEL OF THE NANOPARTICLES COMPOSITE[J]. Acta Materiae Compositae Sinica, 2001, 18(2): 81-84.

COMPLEX MECHANISM OF PHTHALOCYANINE NICKEL WITH Fe3O4 NANOPARTICLES AND THE STRUCTURE MODEL OF THE NANOPARTICLES COMPOSITE

  • Received Date: 1999-08-20
  • Rev Recd Date: 1999-10-15
  • Publish Date: 2001-05-15
  • In this article, the complex process of phthalocyanine nickel with Fe3O4 nanoparticles has been analyzed, the complex mechanism and the structure model for NiPc-Fe3O4 nanoparticles composite have been studied. For the complexes mechanism of NiPc with Fe3O4 nanoparticles, first, there are complex between NiPc and all Fe3O4 nanoparticles. Then, Fe3O4 nanoparticles accumulate together to form the accumulators; NiPc have the function of cohering Fe3O4 nanoparticles. A considerable number of NiPc combine with Fe3O4 nanoparticles and on the surface of the accumulators to form NiPc-Fe3O4 nanoparticles composite. All the processes above take place spontaneously. Inside the NiPc-Fe3O4 nanoparticles complex, Fe3O4 nanoparticles accumulate together without order, on the surface of composite, NiPc form a molecular dispersion layer. The threshold of the molecular dispersion layer is 0.06 g/g(Fe3O4).

     

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      沈阳化工大学材料科学与工程学院 沈阳 110142

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