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ZHENG Weilu, ZHANG Honghua, JIANG Longfa, et al. Progress in noble metal/MOFs nanocomposite structure materials and their applications[J]. Acta Materiae Compositae Sinica, 2024, 41(12): 6399-6413. DOI: 10.13801/j.cnki.fhclxb.20240616.002
Citation: ZHENG Weilu, ZHANG Honghua, JIANG Longfa, et al. Progress in noble metal/MOFs nanocomposite structure materials and their applications[J]. Acta Materiae Compositae Sinica, 2024, 41(12): 6399-6413. DOI: 10.13801/j.cnki.fhclxb.20240616.002

Progress in noble metal/MOFs nanocomposite structure materials and their applications

Funds: National Natural Science Foundation of China (52063015; 51861008); Postgraduate Innovation Fund of Jiangxi Science and Technology Normal University (YC2023-X23)
More Information
  • Received Date: April 18, 2024
  • Revised Date: May 27, 2024
  • Accepted Date: May 30, 2024
  • Available Online: June 24, 2024
  • Published Date: June 16, 2024
  • Metal-organic frameworks (MOFs) have attracted much attention due to their large specific surface area, high porosity, easy modification, large number of active sites and porous structures, and have been widely used in many fields, such as gas storage, sensors, catalysts and other fields. However, due to its inherent defects, their further practical applications in the above fields have been limited. Noble metal nanomaterials have excellent electrical conductivity, good catalysis and unique localized surface plasmon resonance (LSPR) effect. Therefore, researchers have delicately constructed nanocomposite structural materials by combining noble metal nanomaterials and MOFs in various forms in recent years. Due to the synergistic effect of the two, a series of novel characteristics have been generated, enriching the application fields of MOFs materials and significantly improving their performance. In this paper, the application progress of Au, Ag, Pt and other noble metal/MOFs nanocomposite structural materials in catalysis, sensing, biomedicine and hydrogen storage in recent years is reviewed, which provides new ideas for preparing new nanocomposite materials and exploring new applications.

  • Objective 

    Metal-organic frameworks (MOFs) are widely used in catalysis, sensors, biomedicine and hydrogen storage due to their unique characteristics, but their own shortcomings further limit their application. In terms of catalytic applications, MOFs materials have low charge separation and energy transfer efficiency, and high photogenerated electron-hole pair (e-h) recombination rate, which affects their catalytic efficiency. In terms of sensing applications, the low sensitivity, small detection range and insufficient conductivity of MOFs materials limit their further application. In terms of biomedical applications, MOFs materials have insufficient oxygen supply, poor antibacterial performance and therapeutic effect. For hydrogen storage applications, because the storage of H molecules depends on weak physical adsorption, it must be carried out at very low temperatures, while MOFs have low hydrogen storage at room temperature. Therefore, it is necessary to expand the application of MOFs with the help of auxiliary materials and their synergies.

    Methods 

    Noble metal nanomaterials (Au, Ag and Pt) have excellent electrical conductivity, good catalytic performance and unique LSPR effect, which make them auxiliary materials that can improve MOFs defects. If noble metal nanomaterials are optimally combined with MOFs materials to form composite materials, its performance in catalysis, sensor, biomedicine and hydrogen storage can be further enhanced. Based on this, the applications of noble metal /MOFs nanocomposites at home and abroad in recent years are summarized, and the composite materials in the field of catalysis and sensor are classified in detail. The main content is to illustrate the synergistic effect of noble metal materials in these applications to improve the performance of MOFs materials.

    Results 

    ① There are two main applications in catalysis. First of all, in catalytic applications, noble metal nanoparticles act as electronic traps to promote the separation of e-h; the LSPR effect of noble metal nanoparticles broadened the light absorption range of MOFs; noble metal nanoparticles form heterojunctions with MOFs, which inhibit the recombination of photogenerated carriers. These effects can improve the catalytic performance of MOFs, and the introduction of noble metal nanoparticles into MOFs materials can improve the stability of photocatalysts, and the location and content of noble metal nanoparticles can affect the performance of MOFs. Secondly, in electrocatalytic applications, the addition of noble metal nanoparticles increases the active site of electrochemical reaction, making MOFs have efficient energy conversion and storage performance, and can also improve the electrocatalytic activity, further improving the catalytic performance of the catalyst. ② There are two main applications in the field of sensors. One is the electrochemical sensor, the noble metal nanoparticles provide good electrical conductivity; the electrochemical performance of the sensor is improved by providing more active sites. The other is SERS sensor, the noble metal nanoparticles provide more SERS hot spots, which is conducive to improving the detection sensitivity. ③ In the biomedical field, noble metal nanoparticles (Ag NPs) release Ag and produce reactive oxygen species to fight bacteria and improve the antibacterial properties of the materials; oxygen self-supply induced by noble metal nanoparticles improves the effectiveness of cancer therapy. ④ In the field of hydrogen storage, the adsorption rate of the composite increases significantly, which is attributed to the H overflow caused by the addition of noble metal nanoparticles (Pt NPs).Conclusion: The composite materials composed of noble metal nanomaterials and MOFs have a wide range of applications in catalysis, sensors, biomedicine and hydrogen storage, but there are still some areas that need to be improved. In catalytic applications, it is necessary to consider the cyclic stability of the composite catalyst and introduce other auxiliary materials. In sensor applications, the sensitivity and stability of composite materials need to be further improved. In biomedical applications, the biosafety evaluation of composite materials is strengthened. In hydrogen storage applications, the adsorption/desorption performance and capacity loss of the material need to be considered, and new hydrogen storage mechanisms or catalysts can be introduced.

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