Laser assisted eutectic-driven fabrication of thermally conductive Al/AlN composites substrate and joining mechanism
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Abstract
Direct bonded aluminium (DBA) substrates have been widely implemented in high-power electronic devices. However, the oxidation-prone nature of molten aluminum has been a long-term reliability issue. Herein, we have proposed a novel DBA fabrication process utilising laser-assisted electrochemical copper plating to prepare a metallic transition layer. Through the Al-Cu eutectic method, bonding between pure aluminium and aluminium nitride ceramic substrates has been achieved at sintering temperatures ranging from 610 to 650 ℃. The bonding mechanism of Al/AlN was elucidated, along with the influence of the CuAl2 phase at the interface on joint fracture behaviour. Based on theoretical analysis of interfacial diffusion, the formation and growth of the eutectic phase at the Al/Cu interface were controlled, thereby enhancing the bonding strength and achieving an average shear strength of 55.1 MPa for the Al/AlN substrate. This eutectic process not only avoids the oxidation issues associated with liquid aluminium, but also forms a robust bond at the joint, thereby providing a new strategy for the development of high-performance DBA substrates.
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