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Rao FAN, Senyang WANG, Chengyang LIANG, Ying CAO, Shitong GENG, Ling LI. Effects of NiS2-FeS2/CNFs counter electrodes with different concentrations on the photovoltaic performance of quantum dot sensitized solar cells[J]. Acta Materiae Compositae Sinica.
Citation: Rao FAN, Senyang WANG, Chengyang LIANG, Ying CAO, Shitong GENG, Ling LI. Effects of NiS2-FeS2/CNFs counter electrodes with different concentrations on the photovoltaic performance of quantum dot sensitized solar cells[J]. Acta Materiae Compositae Sinica.

Effects of NiS2-FeS2/CNFs counter electrodes with different concentrations on the photovoltaic performance of quantum dot sensitized solar cells

Funds:  National Natural Science Foundation of China (No.51772073); Key project of Natural Science Foundation of Hebei Province (No. E2020201030); The Beijing-Tianjin-Hebei Collaborative Innovation Community Construction Project (No. 21344301D); Hebei University 2022 College Students' Innovation and Entrepreneurship Plan Training Grant Project (No. 2022169, 2022165, 2022170)
  • Received Date: 2023-01-12
  • Accepted Date: 2023-02-16
  • Rev Recd Date: 2023-02-09
  • Available Online: 2023-03-04
  • In order to compensate for the defects of the traditional Cu2S counter electrode in the liquid polysulfide electrolyte, it shows higher electrocatalytic activity against the electrode. In this paper, carbon nanofibra-supported bimetallic sulfide NiS2-FeS2 (NiS2-FeS2/CNFs) counterelectrode has been successfully prepared by electrospinning technology and a simple one-step hydrothermal method, which shows excellent electrochemical performance when applied to quantum dot sensitized solar cells (QDSSCs). At the same time, NiS2-FeS2 composites with different concentrations show great differences under scanning electron microscopy (SEM), and the preparation of paired electrodes loaded with carbon nanofibers also has a great impact on the battery performance. Therefore, this paper focuses on exploring the effect of NiS2-FeS2/CNFs counter electrode with different concentrations prepared by hydrothermal method on the photoelectric performance of QDSSCs assembled by the counter electrode, so as to obtain the best counter electrode concentration. The experimental results show that when the NiS2-FeS2/CNFs concentration ratio is 0.8, the maximum photoelectric conversion efficiency (PCE) of the battery is 8.05%.

     

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      沈阳化工大学材料科学与工程学院 沈阳 110142

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