Dispersion behavior of ultra-low dosage graphene oxide and its effect on structures and performances of cement-based materials

WU Lei; LV Shenghua; LI Zexiong; LI Yao; LIU Leipeng

doi:10.13801/j.cnki.fhclxb.20220623.004

Volume 40 Issue 4

Apr. 2023

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WU Lei, LV Shenghua, LI Zexiong, et al. Dispersion behavior of ultra-low dosage graphene oxide and its effect on structures and performances of cement-based materials[J]. Acta Materiae Compositae Sinica, 2023, 40(4): 2296-2307. doi: 10.13801/j.cnki.fhclxb.20220623.004

Citation:

WU Lei, LV Shenghua, LI Zexiong, et al. Dispersion behavior of ultra-low dosage graphene oxide and its effect on structures and performances of cement-based materials[J]. Acta Materiae Compositae Sinica, 2023, 40(4): 2296-2307. doi: 10.13801/j.cnki.fhclxb.20220623.004

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Dispersion behavior of ultra-low dosage graphene oxide and its effect on structures and performances of cement-based materials

doi: 10.13801/j.cnki.fhclxb.20220623.004

College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China

Funds: Regional Cooperative Research Project of Shaanxi Province of China (2021 QFY04-04); National Natural Science Foundation of China (21276152)

Received Date: 2022-04-12
Accepted Date: 2022-06-10
Rev Recd Date: 2022-05-22

Available Online: 2022-06-24

Publish Date: 2023-04-15

Abstract

Abstract

The existence state and dispersion behavior of graphene oxide (GO) nanosheets in aqueous phase and dispersant were studied. It is found that the main reason for the large dosage, high cost and unstable and insignificant application effect of GO when it is applied to cement-based materials is that GO nanosheets are easy to agglomerate and cannot be evenly dispersed in the cement matrix. Amphoteric polycarboxylate dispersant (APC) and its composite with GO (APC-GO) were prepared. The result finds that GO no longer exists in the cluster state in APC-GO composite , and is mainly adsorbed on APC multi-chain molecules and presents a multi-chain dispersion state. The mechanical properties and durability of cement-based materials can be significantly improved by the addition of APC-GO composite with ultra-low content (mass ratio to cement) of GO of 0.0003%. SEM results show that cement-based materials have regular and compact microstructure morphology. The results show that GO can be uniformly dispersed in cement matrix and has regular regulation effect on the morphology and structure of cement hydration products. The research results have guiding significance for the application of GO.
- graphene oxide,
- amphoteric polycarboxylate superplasticizer,
- composite,
- dispersion behavior,
- ultra-low dosage
Long Abstrsct
Innovation Points

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References(29)

References

[1]	CHEN Y, LI X, DONG B, et al. High-temperature properties of cement paste with graphene oxide agglomerates[J]. Construction and Building Materials,2022,320:126286. doi: 10.1016/j.conbuildmat.2021.126286
[2]	李欣, 罗素蓉. 氧化石墨烯增强水泥复合材料的断裂性能[J]. 复合材料学报, 2021, 38(2):612-621. LI Xin, LUO Surong. Fracture properties of graphene oxide reinforced cement composites[J]. Acta Materiae Compositae Sinica,2021,38(2):612-621(in Chinese).
[3]	彭晖, 戈娅萍, 杨振天, 等. 氧化石墨烯增强水泥基复合材料的力学性能及微观结构[J]. 复合材料学报, 2018, 35(8):2132-2139. PENG Hui, GE Yaping, YANG Zhentian, et al. Mechanical properties and microstructure of graphene oxide reinforced cement-based composites[J]. Acta Materiae Compositae Sinica,2018,35(8):2132-2139(in Chinese).
[4]	罗素蓉, 李欣, 林伟毅, 等. 氧化石墨烯分散方式对水泥基材料性能的影响[J]. 硅酸盐通报, 2020, 39(3):677-684. LUO S R, LI X, LIN W Y, et al. Effect of graphene oxide dispersion method on properties of cement-based materials[J]. Bulletin of the Chinese Ceramic Society,2020,39(3):677-684(in Chinese).
[5]	QIN W, GUODONG Q, DAFU Z, et al. Influence of the molecular structure of a polycarboxylate superplasticizer on the dispersion of graphene oxide in cement pore solutions and cement-based composites[J]. Construction and Building Materials,2021,272:121969. doi: 10.1016/j.conbuildmat.2020.121969
[6]	魏致强, 王远贵, 齐孟, 等. 没食子酸协同聚羧酸减水剂分散氧化石墨烯及其对水泥砂浆性能的影响[J]. 材料导报, 2021, 35(10):10042-10047. doi: 10.11896/cldb.20040258 WEI Zhiqiang, WANG Yuangui, QI Meng, et al. The synergistic effect of gallic acid and polycarboxylic water-reducer on aqueous GO dispersion and the enhanced mechanical properties of cement mortar composites[J]. Materials Reports,2021,35(10):10042-10047(in Chinese). doi: 10.11896/cldb.20040258
[7]	徐亦冬, 王瑶. 氧化石墨烯对水泥基复合材料徐变的调控机制[J]. 复合材料学报, 2022, 39(10): 4839-4846. XU Yidong, WANG Yao. Control mechanism of graphene oxide on creep of cement-based composites[J]. Acta Materiae Compositae Sinica, 2022, 39(10): 4839-4846(in Chinese).
[8]	李东波, 苏梦龙, 芦苇, 等. 复掺氧化石墨烯与矿渣粉的水泥基材料力学性能研究[J]. 应用力学学报, 2021, 38(3):877-885. LI Dongbo, SU Menglong, LU Wei, et al. Study on mechanical properties of cement-based materials mixed with graphene oxide and slag powder[J]. Chinese Journal of Applied Mechanics,2021,38(3):877-885(in Chinese).
[9]	SABZIPARVAR A M, HOSSEINI E, CHINIFORUSH V, et al. Barriers to achieving highly dispersed graphene oxide in cementitious composites: An experimental and computational study[J]. Construction and Building Materials,2019,199:269-278. doi: 10.1016/j.conbuildmat.2018.12.030
[10]	ZHAO L, GUO X, LIU Y, et al. Investigation of dispersion behavior of GO modified by different water reducing agents in cement pore solution[J]. Carbon,2018,127:255-269. doi: 10.1016/j.carbon.2017.11.016
[11]	YAN X, ZHENG D, YANG H, et al. Study of optimizing graphene oxide dispersion and properties of the resulting cement mortars[J]. Construction and Building Materials,2020,257:119477. doi: 10.1016/j.conbuildmat.2020.119477
[12]	ZHAO L, GUO X, LIU Y, et al. Hydration kinetics, pore structure, 3D network calcium silicate hydrate, and mechanical behavior of graphene oxide reinforced cement composites[J]. Construction and Building Materials,2018,190:150-163. doi: 10.1016/j.conbuildmat.2018.09.105
[13]	SHENG K, LI D, YUAN X. Methyl orange assisted dispersion of graphene oxide in the alkaline environment for improving mechanical properties and fluidity of ordinary Portland cement composites[J]. Journal of Building Engineering,2021,43:103166. doi: 10.1016/j.jobe.2021.103166
[14]	AMINI K, GHASEMI A, AMIRI S S, et al. The synergic effects of metakaolin and polycarboxylate-ether on dispersion of graphene oxide in cementitious environments and macro-level properties of graphene oxide modified cement composites[J]. Construction and Building Materials,2021,270:121462. doi: 10.1016/j.conbuildmat.2020.121462
[15]	LIU H, YU Y, LIU H, et al. Hybrid effects of nano-silica and graphene oxide on mechanical properties and hydration products of oil well cement[J]. Construction and Building Materials,2018,191:311-319. doi: 10.1016/j.conbuildmat.2018.10.029
[16]	LI X, LU Z, CHUAH S, et al. Effects of graphene oxide aggregates on hydration degree, sorptivity, and tensile splitting strength of cement paste[J]. Composites Part A: Applied Science and Manufacturing,2017,100:1-8. doi: 10.1016/j.compositesa.2017.05.002
[17]	MUNGSE H P, GUPTA K, SINGH R, et al. Alkylated graphene oxide and reduced graphene oxide: Grafting density, dispersion stability to enhancement of lubrication properties[J]. Journal of Colloid and Interface Science,2019,541:150-162. doi: 10.1016/j.jcis.2019.01.064
[18]	YANG S, JIA W, WANG Y, et al. Hydroxylated graphene: A promising reinforcing nanofiller for nanoengineered cement composites[J]. ACS Omega,2021,6(45):30465-30477. doi: 10.1021/acsomega.1c03844
[19]	ZHANG X, ZHOU S, ZHOU H, et al. The effect of the modification of graphene oxide with γ-aminopropyltriethoxysilane (KH550) on the properties and hydration of cement[J]. Construction and Building Materials,2022,322:126497. doi: 10.1016/j.conbuildmat.2022.126497
[20]	RAHMANI S, SHARIF A, KORAYEM A H. Dispersion stability of chitosan grafted graphene oxide nanosheets in cementitious environments and their effects on the fluidity of cement mortar nanocomposites[J]. Journal of Applied Polymer Science,2022,139(19):52095. doi: 10.1002/app.52095
[21]	WANG M, YAO H. Comparison study on the adsorption behavior of chemically functionalized graphene oxide and graphene oxide on cement[J]. Materials,2020,13(15):3274. doi: 10.3390/ma13153274
[22]	NGUYEN H D, ZHANG Q, SAGOE-CRENTSIL K, et al. Graphene oxide-coated sand for improving performance of cement composites[J]. Cement and Concrete Composites,2021,124:104279. doi: 10.1016/j.cemconcomp.2021.104279
[23]	袁小亚, 曾俊杰, 高军, 等. 氧化石墨烯与石墨烯复掺对水泥砂浆性能影响研究[J]. 重庆交通大学学报, 2019, 38(9):45-50. YUAN Xiaoya, ZENG Junjie, GAO Jun, et al. Effect of addition of graphene oxide and graphene on properties of cement mortar[J]. Journal of Chongqing Jiaotong University,2019,38(9):45-50(in Chinese).
[24]	王琴, 齐国栋, 王悦, 等. 氧化石墨烯在水泥基复合材料中应用的研究进展[J]. 新型炭材料, 2021, 36(4):729-750. doi: 10.1016/S1872-5805(21)60071-9 WANG Qin, QI Guodong, WANG Yue, et al. Research progress on the effect of graphene oxide on the properties of cement-based composites[J]. New Carbon Materials,2021,36(4):729-750(in Chinese). doi: 10.1016/S1872-5805(21)60071-9
[25]	LV S, MA Y, QIU C, et al. Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites[J]. Construction and Building Materials,2013,49:121-127. doi: 10.1016/j.conbuildmat.2013.08.022
[26]	YAO X, SHAMSAEI E, SAGOE-CRENTSIL K, et al. The interaction of graphene oxide with cement mortar: Implications on reinforcing mechanisms[J]. Journal of Materials Science,2022,57:3405-3415. doi: 10.1007/s10853-021-06808-y
[27]	吕生华, 孙婷, 刘晶晶, 等. 氧化石墨烯纳米片层对水泥基复合材料的增韧效果及机制[J]. 复合材料学报, 2014, 31(3):644-652. LV Shenghua, SUN Ting, LIU Jingjing, et al. Toughening effect and mechanism of graphene oxide nanosheets on cement matrix composites[J]. Acta Materiae Compositae Sinica,2014,31(3):644-652(in Chinese).
[28]	GLASS D E, GALVAN V, PRAKASH G K S. Reassessing the necessity of the drying step in hummer's method for graphene oxide synthesis[J]. Electroanalysis,2021,33(11):2323-2334. doi: 10.1002/elan.202100188
[29]	中华人民共和国住房和城乡建设部. 普通混凝土长期性能和耐久性能试验方法标准: GB/T 50082—2009[S]. 北京: 中国建筑工业出版社, 2009. Ministry of Housing and Urban-Rural Development of thePeople's Republic of China. Standard test method for long-term performance and durability of ordinary concrete: GB/T 50082—2009[S]. Beijing: China Construction Industry Press, 2009(in Chinese).