LIU Feng, ZHENG Qiu-hong, LI Xiao-hong, et al. Sil icone rubber reinforced by a dispersible nano-sil ica[J]. Acta Materiae Compositae Sinica, 2006, 23(6): 57-63.
Citation: LIU Feng, ZHENG Qiu-hong, LI Xiao-hong, et al. Sil icone rubber reinforced by a dispersible nano-sil ica[J]. Acta Materiae Compositae Sinica, 2006, 23(6): 57-63.

Sil icone rubber reinforced by a dispersible nano-sil ica

  • Received Date: 2006-01-11
  • Rev Recd Date: 2006-04-03
  • Publish Date: 2006-12-15
  • A novel nano-silica surface-modified by silane was used as a reinforcing filler for HTV (heat vulcanization) silicone rubber. The dispersion morphologies and network st ructure of the composites were analysed by scanning elect ronic microscopy (SEM) and Payne effect ; the crystal behavior at low temperature was studied by differential scanning calorimet ry(DSC) . And the effect of these fillers on the mechanical properties of silicone rubber was investigated. Because the surface of these nanoparticles was enwrapped by apolar methyl , they can disperse in therubber perfectly without adding any dispersant . The result s indicate that at respective optimum content , the catenarian nano-silica (DNS-3) has evidently better reinforcement to silicone rubber in the tensile st rength , tear st rengthand elongation at break than the silica nanoparticle synthesized by aerosol method (A-200) . The DNS-2 nano-silicahas a similar reinforcing effect to nanO2silica compared with A-200 , but the gross rubber of the DNS-2 system wassof ter and has better processability than that of A-200.

     

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      沈阳化工大学材料科学与工程学院 沈阳 110142

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