Modification of coconut shell biochar by ball milling with an alkali for enrofloxacin adsorption

XIAO Dao; ZHENG Lili; ZHENG Xiaoyan; YANG Yang; AI Binling; SHENG Zhanwu

doi:10.13801/j.cnki.fhclxb.20240003.001

Volume 41 Issue 8

Aug. 2024

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XIAO Dao, ZHENG Lili, ZHENG Xiaoyan, et al. Modification of coconut shell biochar by ball milling with an alkali for enrofloxacin adsorption[J]. Acta Materiae Compositae Sinica, 2024, 41(8): 4324-4333. doi: 10.13801/j.cnki.fhclxb.20240003.001

Citation:

XIAO Dao, ZHENG Lili, ZHENG Xiaoyan, et al. Modification of coconut shell biochar by ball milling with an alkali for enrofloxacin adsorption[J]. Acta Materiae Compositae Sinica, 2024, 41(8): 4324-4333. doi: 10.13801/j.cnki.fhclxb.20240003.001

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Modification of coconut shell biochar by ball milling with an alkali for enrofloxacin adsorption

doi: 10.13801/j.cnki.fhclxb.20240003.001

Institute of Tropical Bioscience and Biotechnology, Chinese Academy of Tropical Agricultural Sciences, Haikou 571101, China

Funds: Key Research and Development Projects of Hainan Province (ZDYF2023XDNY049; ZDYF2019187); Hainan Provincial Natural Science Fund Project (319QN267); Central Public-interest Scientiffc Institution Basal Research Fund for Innovative Research Team Program of CATAS (17CXTD-05)

Received Date: 2023-10-25
Accepted Date: 2023-12-18
Rev Recd Date: 2023-12-08

Available Online: 2024-01-04

Publish Date: 2024-08-01

Abstract

Abstract

In order to efficiently adsorb enrofloxacin (EFA) in water, coconut shell biochar (BM-KOH-BC) was prepared by modifying coconut shell through ball milling and KOH activation, and in-depth research was conducted on the adsorption of EFA. BM-KOH-BC was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. The results revealed that KOH activation and ball milling modification significantly improved the pore structure and specific surface area of BM-KOH-BC. Under optimized conditions (Initial EFA concentration is 80 mg·L⁻¹, pH value is 7, temperature is 25℃, adsorbent dosage is 0.14 g·mg·L⁻¹, stirring speed is 200 r/min, contact time under the conditions of 35 h), BM-KOH-BC showed good adsorption performance, with a removal rate of 77.4% and a maximum adsorption capacity of 481.1 mg·g⁻¹. The adsorption process is consistent with the second-order kinetic model and Freundlich isotherm model. In addition, BM-KOH-BC still maintains efficient EFA removal rate after 5 adsorption-desorption cycles. This low-cost, efficient adsorption and recyclability feature makes BM-KOH-BC show potential application prospects in treating EFA in water bodies.
- ball-milling,
- biochar,
- coconut shell,
- enrofloxacin,
- adsorption
Long Abstrsct
Innovation Points

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References(33)

References

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