Modification strategies of transition metal phosphide-based materials in electrocatalytic hydrogen evolution: Current status and prospect

LEI Wanying; WU Pan; SI Weibin; ZHAO Liang; TAN Ziqiang; YANG Xinxin; QIAO Mingtao; ZHANG Tingting

doi:10.13801/j.cnki.fhclxb.20231120.002

Volume 41 Issue 4

Apr. 2024

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LEI Wanying, WU Pan, SI Weibin, et al. Modification strategies of transition metal phosphide-based materials in electrocatalytic hydrogen evolution: Current status and prospect[J]. Acta Materiae Compositae Sinica, 2024, 41(4): 1737-1749. doi: 10.13801/j.cnki.fhclxb.20231120.002

Citation:

LEI Wanying, WU Pan, SI Weibin, et al. Modification strategies of transition metal phosphide-based materials in electrocatalytic hydrogen evolution: Current status and prospect[J]. Acta Materiae Compositae Sinica, 2024, 41(4): 1737-1749. doi: 10.13801/j.cnki.fhclxb.20231120.002

Citation:

LEI Wanying, WU Pan, SI Weibin, et al. Modification strategies of transition metal phosphide-based materials in electrocatalytic hydrogen evolution: Current status and prospect[J]. Acta Materiae Compositae Sinica, 2024, 41(4): 1737-1749. doi: 10.13801/j.cnki.fhclxb.20231120.002

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Modification strategies of transition metal phosphide-based materials in electrocatalytic hydrogen evolution: Current status and prospect

doi: 10.13801/j.cnki.fhclxb.20231120.002

1.
College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
2.
Dingxi, Products Quality Supervision and Inspection Institute, Dingxi 743000, China

Funds: National Natural Science Foundation of China (51902443); Key Research Project of Shaanxi Education Department (22JY039; 22JY037)

Received Date: 2023-09-05
Accepted Date: 2023-11-09
Rev Recd Date: 2023-11-03

Available Online: 2023-11-21

Publish Date: 2024-04-15

Abstract

Abstract

Hydrogen, a zero-carbon fuel, is supposed to be the potential alternative for fossil energy. Electrocatalytic hydrogen evolution reaction (HER) is a green technology that could split water molecules to produce hydrogen. Therefore, exploring the low-cost, efficient and long-stable noble metal-free catalysts is particularly important for solving the problems of energy crisis and sustainable development. Transition metal phosphides (TMPs) possess excellent electrical conductivity, variable chemical composition, abundant reserves and stable physicochemical properties, which is one of the critical catalysts in HER. Herein, the HER mechanism and the structural characteristics of TMPs are introduced at first, then the fabrication approaches of TMPs like liquid phase formation, gas-solid synthesis, etc. are summarized. This paper are mainly focusing on the recent modification strategies for TMPs-based nanostructures, such as morphology regulation, vacancy creation, elemental doping and interface engineering. Finally, the future directions for the development of TMPs is proposed.
- transition metal phosphide,
- hydrogen,
- electrocatalysis,
- hydrogen evolution reaction,
- modification strategies
Long Abstrsct
Innovation Points

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References(88)

References

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