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HU Dexin, SHAN Yuxi, WANG Hailiang, et al. Microstructure and self-repairing performance of granular loaded graphene oxide composite cement-based materials[J]. Acta Materiae Compositae Sinica, 2024, 41(6): 3079-3091. DOI: 10.13801/j.cnki.fhclxb.20231025.002
Citation: HU Dexin, SHAN Yuxi, WANG Hailiang, et al. Microstructure and self-repairing performance of granular loaded graphene oxide composite cement-based materials[J]. Acta Materiae Compositae Sinica, 2024, 41(6): 3079-3091. DOI: 10.13801/j.cnki.fhclxb.20231025.002
shu

Microstructure and self-repairing performance of granular loaded graphene oxide composite cement-based materials

  • 1.

    School of Materials Science and Engineering, Anhui University of Technology, Ma'anshan 243002, China

  • 2.

    School of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China

Funds: Natural Science Foundation of China (51872137)
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  • Received Date: August 27, 2023
  • Revised Date: September 30, 2023
  • Accepted Date: October 19, 2023
  • Available Online: October 24, 2023
    Abstract
  • To improve the dispersion performance of graphene oxide (GO) in the cement materials, nano SiO2 and CaCO3 powder were used as support of the GO and the SiO2-GO (SG) and SiO2-CaCO3-GO (SCG) were prepared. The effects of the SG and SCG on the mechanical strength, self-repairing performance, hydration products and microstructure of the cement materials were studied. The results show that the mechanical strength of the cement material is improved as the addition of SG and SCG, the flexural strength and compressive strength of the cement-based materials with SCG at 28 days are improved by 7.3% and 18.7%, respectively. The self-repairing performance of SCG composite cement is also improved which shows a higher compressive strength repairing rate of about 110.6% and a higher water permeability repairing rate of 100%. The crack area testing shows that SCG has a more significant repair effect on cracks in the cement materials. XRD analysis shows that the early stage cement hydration is accelerated as the addition of SG and SCG, especially for the SCG, the hydration degree at 3 days is obviously improved. TG analysis shows that with the extension of hydration age, a higher reaction degree of Ca(OH)2 and SiO2 is achieved in the SCG composite cement, compared with the early 3 days hydration stage, the Ca(OH)2 content of SCG composite cement at 28 days reduces to 14.90%. Microstructure analysis shows that the SCG has better compatibility with the cement, more hydrate calcium silicate (C-S-H) gels in the late hydration stage is generated and the microcracks of cement could be filled, which makes the excellent self-repairing performance of the SCG composite cement.
    • Summary

  • Summary

    Objective 

    The self-repairing of cement-based materials is an effective way for the improvement of the durability performance. The addition of graphene oxide (GO) has a toughening and strengthening effect on cement-based materials, which has a positive effect on the micro-crack self-healing of the cement-based materials. In this paper, highly dispersion of GO in cement-based materials is achieved by granular loaded method, and the effects of GO incorporation on mechanical properties, self-repairing properties, hydration products and microstructure of cement-based materials were studied.

    Method 

    SiO-GO (SG) and SiO-CaCO-GO (SCG) were prepared by granular loaded method, nano-SiO and CaCO powder as the support of GO, the effects of incorporation of SG and SCG on the mechanical properties of cement-based materials were studied. The self-repairing properties of the cement-based materials were characterized by compressive strength repairing rate, water permeability repairing rate and crack repairing rate. The effects of granular loaded GO on the hydration products of cement-based materials were analyzed by XRD; the hydration process of cement-based materials were analyzed by TG; the effect of granular loaded GO on the microstructure of cement-based materials were analyzed by SEM-EDS, and the related mechanism of granular loaded GO on the self-repairing properties of cement-based materials was proposed.

    Results 

    According to the test results of mechanical properties, under the same dosage, the flexural strength of SCG/CE sample at 28d reached 8.8 MPa, increased by 7.3% compared with the blank sample, and the flexural strength of SiO/CE and SG/CE decreased slightly. The compressive strength of SCG/CE sample at 28d was 57.2 MPa, increased by 18.7% compared with the blank sample, which was significantly higher than that of SiO/CE and SG/CE samples. SCG/CE specimens showed better repair ability than the other specimens. Among them, the compressive strength repair rate reached 110.6%, and the water permeability repair rate and surface crack repair rate reached 100% after 28d repairing. XRD and TG analysis showed that SCG/CE had a higher hydration degree at different curing age, the content of Ca(OH) further decreased from 15.77% at 3d to 14.90% at 28d. It also can be seen from the SEM of each sample that the connection between the particles and the cement matrix in the SCG/CE specimen is more close, more hydration products produced on the surface of the plate SCG particles. EDS spectra also showed that the Ca/Si mass ratio of SCG/CE was higher than the other samples, with the advancement of hydration age, particles participate in hydration, and the hydration degree of SCG is higher, which also take a good explanation for the better self-repairing performance of SCG/CE samples: due to the high dispersion of SCG and good interfacial compatibility with cement, SCG/CE samples have better self-repairing properties. When micro-cracks appeared, SCG in the micro-crack could react with the Ca, the generation of C-S-H gel products filled the micro-cracks of the cement, resulting in the improvement of the mechanical strength of the cement, the self-repairing behavior is beneficial for the enhancement of the durability of the cement-based materials.Conclusions: With the special two-dimensional nanostructure, GO can be used as a nucleation site to promote cement hydration and regulate hydration products of cement-based materials, and the mechanical performance, microstructure and durability of cement-based materials could be improved by the high dispersion of GO in the cement. In this paper, SCG particles with a stronger compatibility with cement-based materials were prepared by granular loaded method, which allowed GO to be highly dispersed and realized the self-repairing properties of cement-based materials，the mechanism of the action of SCG on the self-repairing performance of cement-based materials was analyzed, the study provide some guidance for the self-repairing performance of GO in cement-based materials.

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    • References (36)
  • [1]
    花素珍, 张家广, 高沛, 等. 增强再生骨料固载混菌的混凝土裂缝自修复性能[J]. 复合材料学报, 2023, 40(11): 6299-6310. DOI: 10.13801/j.cnki.fhclxb.20230222.006

    HUA Suzhen, ZHANG Jiaguang, GAO Pei, et al. Self-healing of concrete cracks by immobilizing non-axenic bacteria with enhanced recycled aggregates[J]. Acta Materiae Compositae Sinica, 2023, 40(11): 6299-6310(in Chinese). DOI: 10.13801/j.cnki.fhclxb.20230222.006
    [2]
    MAC M J, YIO M H N, DESBOIS G, et al. 3D imaging techniques for characterising microcracks in cement-based materials[J]. Cement and Concrete Research, 2021, 140: 106309. DOI: 10.1016/j.cemconres.2020.106309
    [3]
    张旋, 傅昌皓, 詹其伟, 等. 基于接触电阻的水泥基材料裂缝自修复效果定量表征方法[J]. 硅酸盐通报, 2023, 42(6): 1950-1959, 1979. DOI: 10.16552/j.cnki.issn1001-1625.2023.06.015

    ZHANG Xuan, FU Changhao, ZHAN Qiwei, et al. Quantitative characterization method of crack self-healing effect of cement-based materials based on contact resistance theory[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(6): 1950-1959, 1979(in Chinese). DOI: 10.16552/j.cnki.issn1001-1625.2023.06.015
    [4]
    马衍轩, 吴睿, 葛亚杰, 等. 粘土固化型微胶囊复合水泥基材料的设计与力学损伤自修复行为[J]. 复合材料学报, 2023, 40(9): 5288-5301.

    MA Yanxuan, WU Rui, GE Yajie, et al. Design and self-repair behavior of clay-cured microcapsule composite cementitious materials[J]. Acta Materiae Compositae Sinica, 2023, 40(9): 5288-5301(in Chinese).
    [5]
    SUN D W, MA W X, MA J K, et al. The synthesis of DMTDA microcapsules and investigation of self-healing cement paste through an isocyanate-amine system[J]. Cement and Concrete Composites, 2021, 122: 104132. DOI: 10.1016/j.cemconcomp.2021.104132
    [6]
    DU W, LIU Q, LIN R. Effects of toluene-di-isocyanate microcapsules on the frost resistance and self-repairing capability of concrete under freeze-thaw cycles[J]. Journal of Building Engineering, 2021, 44: 102880. DOI: 10.1016/j.jobe.2021.102880
    [7]
    朱康杰, 钱春香, 李敏, 等. 微生物自修复混凝土中微胶囊修复剂尺寸及掺量对修复剂释放率的影响[J]. 材料导报, 2020, 34(Z2): 1212-1216.

    ZHU Kangjie, QIAN Chunxiang, LI Min, et al. Effect of the size and dosage of microcapsule healing agent on the release rate of healing agent in microbial self-healing concrete[J]. Material Review, 2020, 34(Z2): 1212-1216(in Chinese).
    [8]
    FU C, ZHAN Q, ZHANG X, et al. Self-healing properties of cement-based materials in different matrix based on microbial mineralization coupled with bimetallic hydroxide[J]. Construction and Building Materials, 2023, 400: 132686. DOI: 10.1016/j.conbuildmat.2023.132686
    [9]
    黄浩良, 吴欣桐, 刘昊, 等. 固化海水离子裂缝自修复剂制备及其在硬化水泥浆体中的作用机理[J]. 硅酸盐学报, 2021, 49(8): 1619-1630.

    HUANG Haoliang, WU Xintong, LIU Hao, et al. Seawater-ion-bound self-healing agents and the working mechanism in cracked hardened cement paste[J]. Journal of the Chinese Ceramic Society, 2021, 49(8): 1619-1630(in Chinese).
    [10]
    常洪雷, 李晨聪, 王晓龙, 等. 复合矿物掺合料对砂浆自修复性能的影响[J]. 材料导报, 2023, 37(2): 62-68.

    CHANG Honglei, LI Chencong, WANG Xiaolong, et al. Effect of composite mineral admixtures on self-healing properties of mortar[J]. Materials Reports, 2023, 37(2): 62-68(in Chinese).
    [11]
    YU L, BAI S, GUAN X. Effect of graphene oxide on microstructure and micromechanical property of ultra-high performance concrete[J]. Cement and Concrete Composites, 2023, 138: 104964. DOI: 10.1016/j.cemconcomp.2023.104964
    [12]
    FU Q, WANG Z, XUE Y, et al. Catalysis and regulation of graphene oxide on hydration properties and microstructure of cement-based materials[J]. ACS Sustainable Chemistry & Engineering, 2023, 11(14): 5626-5643.
    [13]
    VANTADORI S, MAGNANI G, MANTOVANI L, et al. Effect of GO nanosheets on microstructure, mechanical and fracture properties of cement composites[J]. Construction and Building Materials, 2022, 361: 129368. DOI: 10.1016/j.conbuildmat.2022.129368
    [14]
    徐亦冬, 王瑶. 氧化石墨烯对水泥基复合材料徐变的调控机制[J]. 复合材料学报, 2022, 39(10): 4839-4846.

    XU Yidong, WANG Yao. Regulation mechanism of graphene oxide on creep of cement-based composites[J]. Acta Materiae Compositae Sinica, 2022, 39(10): 4839-4846(in Chinese).
    [15]
    SOUZA F B, SHAMSAEI E, SAGOE-CRENTSIL K, et al. Proposed mechanism for the enhanced microstructure of graphene oxide-portland cement composites[J]. Journal of Building Engineering, 2022, 54(5): 635-641.
    [16]
    LIU H T, YU Y J, LIU H M, et al. Hybrid effects of nano-silica and graphene oxide on mechanical properties and hydration products of oil well cement[J]. Construction and Building Materials, 2018, 191: 311-319. DOI: 10.1016/j.conbuildmat.2018.10.029
    [17]
    陈妤, 李创创, 李国浩, 等. 氧化石墨烯改性水泥砂浆抗氯离子渗透性能[J]. 硅酸盐通报, 2022, 41(5): 1539-1546.

    CHEN Yu, LI Chuangchuang, LI Guohao, et al. Chloride penetration resistance of cement mortar modified by graphene oxide[J]. Bulletin of the Chinese Ceramic Society, 2022, 41(5): 1539-1546(in Chinese).
    [18]
    LI W, LI X, CHEN S J, et al. Effects of graphene oxide on early-age hydration and electrical resistivity of portland cement paste[J]. Construction and Building Materials, 2017, 136(4): 506-514.
    [19]
    WANG Q, LI S, PAN S, et al. Effect of graphene oxide on the hydration and microstructure of fly ash-cement system[J]. Construction and Building Materials, 2019, 198(2): 106-119.
    [20]
    GHAZIZADEH S, DUFFOUR P, SKIPPER N T, et al. An investigation into the colloidal stability of graphene oxide nano-layers in alite paste[J]. Cement and Concrete Research, 2017, 99(9): 116-128.
    [21]
    ZHAO L, GUO X L, LIU Y Y, et al. Investigation of dispersion behavior of GO modified by different water reducing agents in cement pore solution[J]. Carbon, 2018, 127(2): 255-269.
    [22]
    ZHAO L, GUO X L, GE C, et al. Investigation of the effectiveness of PC@GO on the reinforcement for cement composites[J]. Construction and Building Materials, 2016, 113(6): 470-478.
    [23]
    LIN J, SHAMSAEI E, DE SOUZA F B, et al. Dispersion of graphene oxide-silica nanohybrids in alkaline environment for improving ordinary portland cement composites[J]. Cement and Concrete Composites, 2020, 106(2): 678-688.
    [24]
    吴磊, 吕生华, 李泽雄, 等. 超低掺量氧化石墨烯的分散行为及其对水泥基材料结构与性能的影响[J]. 复合材料学报, 2022, 6(6): 35-46.

    WU Lei, LYU Shenghua, LI Zexiong, et al. Dispersion behavior of ultra-low dosage graphene oxide and its effect on structures and performances of cement-based materials[J]. Acta Materiae Compositae Sinica, 2022, 6(6): 35-46(in Chinese).
    [25]
    WU Z, KHAYAT K H, SHO C. Effect of nano-SiO2 particles and curing time on development of fiber-matrix bond properties and microstructure of ultra-high strength concrete[J]. Cement and Concrete Research, 2017, 95: 247-256. DOI: 10.1016/j.cemconres.2017.02.031
    [26]
    BAI S, GUAN X, LI G, et al. Effect of the early-age frost damage and nano-SiO2 modification on the properties of portland cement paste[J]. Construction and Building Materials, 2020, 262(10): 91-101.
    [27]
    DE OLIVEIRA T A, BRAGANCA M D O G P, PINKOSKI I M, et al. The effect of silica nanocapsules on self-healing concrete[J]. Construction and Building Materials, 2021, 300: 124010. DOI: 10.1016/j.conbuildmat.2021.124010
    [28]
    程子扬, 陈国夫, 屠艳平. 纳米CaCO3对粉煤灰再生骨料混凝土性能及微结构的影响[J]. 建筑材料学报, 2023, 26(3): 228-235. DOI: 10.3969/j.issn.1007-9629.2023.03.002

    CHENG Ziyang, CHEN Guofu, TU Yanping. Effect of nano CaCO3 on properties and microstructure of fly ash recycled aggregate concrete[J]. Journal of Building Materials, 2023, 26(3): 228-235(in Chinese). DOI: 10.3969/j.issn.1007-9629.2023.03.002
    [29]
    KAKALI G, TSIVILIS S, AGGELI E, et al. Hydration products of C3A, C3S and portland cement in the presence of CaCO3[J]. Cement and Concrete Research, 2000, 30(7): 1073-1077. DOI: 10.1016/S0008-8846(00)00292-1
    [30]
    SHEN D, KANG J, SHAO H, et al. Cracking failure behavior of high strength concrete containing nano-CaCO3 at early age[J]. Cement and Concrete Composites, 2023, 139: 104996. DOI: 10.1016/j.cemconcomp.2023.104996
    [31]
    HOSAN A, SHAIKH F U A, SARKER P, et al. Nano- and micro-scale characterisation of interfacial transition zone (ITZ) of high volume slag and slag-fly ash blended concretes containing nano SiO2 and nano CaCO3[J]. Construction and Building Materials, 2021, 269: 121311. DOI: 10.1016/j.conbuildmat.2020.121311
    [32]
    SHAIKH F U A, SUPIT S W M, BARBHUIYA S. Microstructure and nanoscaled characterization of HVFA cement paste containing nano-SiO2 and nano-CaCO3[J]. Journal of Materials in Civil Engineering, 2017, 29(8): 04017063. DOI: 10.1061/(ASCE)MT.1943-5533.0001898
    [33]
    中国国家标准化管理委员会. 通用硅酸盐水泥: GB/T 175—2007[S]. 北京: 中国标准出版社, 2007.

    Standardization Administration of the People's Republic of China. Common portland cement: GB/T 175—2007[S]. Beijing: China Standards Press, 2007(in Chinese).
    [34]
    国家质量技术监督局. 水泥胶砂强度检验方法: GB/T 17671—1999[S]. 北京: 中国标准出版社, 1999.

    The State Bureau of Quality and Technical Supervision. Method of testing cements—Determination of strength: GB/T 17671—1999[S]. Beijing: China Standards Press, 1999(in Chinese).
    [35]
    WEI Z, GU K, CHEN B, et al. Comparison of sawdust bio-composites based on magnesium oxysulfate cement and ordinary portland cement[J]. Journal of Building Engineering, 2023, 63: 105514. DOI: 10.1016/j.jobe.2022.105514
    [36]
    WU Z, KHAYAT K H, SHI C, et al. Mechanisms underlying the strength enhancement of UHPC modified with nano-SiO2 and nano-CaCO3[J]. Cement and Concrete Composites, 2021, 119: 103992. DOI: 10.1016/j.cemconcomp.2021.103992
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