Preparation of titanium dioxide/ZIF-8 composite superhydrophobic sponge and its oil-water separation performance

JI Haonan; YI Changfeng; XU Zushun; YANG Xiaoxin

doi:10.13801/j.cnki.fhclxb.20211217.001

Volume 39 Issue 12

Dec. 2022

Turn off MathJax

Article Contents

Article Navigation > Acta Materiae Compositae Sinica > 2022 > 39(12): 5758-5767

JI Haonan, YI Changfeng, XU Zushun, et al. Preparation of titanium dioxide/ZIF-8 composite superhydrophobic sponge and its oil-water separation performance[J]. Acta Materiae Compositae Sinica, 2022, 39(12): 5758-5767. doi: 10.13801/j.cnki.fhclxb.20211217.001

Citation:

JI Haonan, YI Changfeng, XU Zushun, et al. Preparation of titanium dioxide/ZIF-8 composite superhydrophobic sponge and its oil-water separation performance[J]. Acta Materiae Compositae Sinica, 2022, 39(12): 5758-5767. doi: 10.13801/j.cnki.fhclxb.20211217.001

Citation:

PDF( 5324 KB)

Preparation of titanium dioxide/ZIF-8 composite superhydrophobic sponge and its oil-water separation performance

doi: 10.13801/j.cnki.fhclxb.20211217.001

School of Materials Science and Engineering, Hubei Key Laboratory of Polymer Materials, Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan 430062, China

Received Date: 2021-10-08
Accepted Date: 2021-12-08
Rev Recd Date: 2021-12-02

Available Online: 2021-12-20

Publish Date: 2022-12-01

Abstract

Abstract

Treatment of oily wastewater problem of oil spills at sea and the discharge of oily wastewater have brought huge damage to the economy and the environment. This paper used polydopamine to adhere the self-made dual-scale ZIF-8/TiO₂ nanoparticles to the polyurethane sponge, and prepared the superhydrophobic oil-water separation sponge by modification with octadecylamine. The structure was characterized and analyzed by FTIR, XRD, etc.. ZIF-8 and TiO₂ two kinds of nano-particles constructed a two-scale rough structure, and the influence of the amount of the two kinds of particles on the surface performance of the composite coating was deeply explored. The results show that when the molar ratio of ZIF-8 and TiO₂ nanoparticles is 2∶1, the contact angle reaches the maximum value of 153°.The composite sponge has good oil-water separation performance, the absorption capacity is 40 to 118 times its own weight, and the separation efficiency is on average more than 96%. The temperature can rise by 55℃ within 10 s under 808 nm laser irradiation, and it has good light-to-heat conversion performance.
- superhydrophobic,
- ZIF-8,
- titanium dioxide,
- oil-water separation,
- polyurethane sponge
Long Abstrsct
Innovation Points

FullText(HTML)

References(28)

References

[1]	WANG B, YANG X, SHA D, et al. Silane functionalized polyvinyl-alcohol formaldehyde sponges on fast oil absorption[J]. ACS Applied Polymer Materials,2020,2(11):5309-5317. doi: 10.1021/acsapm.0c01052
[2]	NISTICO R, FRANZOSO F, CESANO F, et al. Chitosan-derived iron oxide systems for magnetically guided and efficient water purification processes from polycyclic aromatic hydrocarbons[J]. ACS Sustainable Chemistry & Engineering,2017,5(1):793-801.
[3]	GE J, ZHAO H Y, ZHU H W, et al. Advanced sorbents for oil-spill cleanup: Recent advances and future perspectives[J]. Advanced Materials,2016,28(47):10459-10490. doi: 10.1002/adma.201601812
[4]	TANG X, SHEN C, ZHU W, et al. A facile procedure to modify filter paper for oil–water separation[J]. RSC Advances,2017,7(48):30495-30499. doi: 10.1039/C7RA03754F
[5]	EMELYANENKO A M, BOINOVICH L B, BEZDOMNIKOV A A, et al. Reinforced superhydrophobic coating on silicone rubber for longstanding anti-icing performance in severe conditions[J]. ACS Applied Materials & Interfaces,2017,9(28):24210-24219.
[6]	GUPTA R K, DUNDERDALE G J, ENGLAND M W, et al. Oil/water separation techniques: A review of recent progresses and future directions[J]. Journal of Materials Chemistry A,2017,5(31):16025-16058. doi: 10.1039/C7TA02070H
[7]	WANG B, LIANG W, GUO Z, et al. Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: A new strategy beyond nature[J]. Chemical Society Reviews,2015,44(1):336-361. doi: 10.1039/C4CS00220B
[8]	CAI Y, CHEN D, LI N, et al. Self-healing and superwettable nanofibrous membranes for efficient separation of oil-in-water emulsions[J]. Journal of Materials Chemistry A,2019,7(4):1629-1637. doi: 10.1039/C8TA10254F
[9]	ZHU Y, WANG D, JIANG L, et al. Recent progress in developing advanced membranes for emulsified oil/water separation[J]. NPG Asia Materials,2014,6(5):e101. doi: 10.1038/am.2014.23
[10]	WEN Q, DI J, JIANG L, et al. Zeolite-coated mesh film for efficient oil-water separation[J]. Chemical Science,2013,4(2):591-595. doi: 10.1039/C2SC21772D
[11]	WEI Y, QI H, GONG X, et al. Specially wettable membranes for oil-water separation[J]. Advanced Materials Interfaces,2018,5(23):1800576. doi: 10.1002/admi.201800576
[12]	SUN S, TANG S, CHANG X, et al. A bifunctional melamine sponge decorated with silver-reduced graphene oxide nanocomposite for oil-water separation and antibacterial applications[J]. Applied Surface Science,2019,473:1049-1061. doi: 10.1016/j.apsusc.2018.12.215
[13]	DONG B, GUO Y, SUN S, et al. Shish–kebab-structured UHMWPE coating for efficient and cost-effective oil–water separation[J]. ACS Applied Materials & Interfaces, 2020, 12(52): 58252-58262.
[14]	ZHANG Y, ZHANG N, ZHOU S, et al. Facile preparation of ZIF-67 coated melamine sponge for efficient oilwater separation[J]. Industrial & Engineering Chemistry Research,2019,58(37):17380-17388.
[15]	AZAM T, PERVAIZ E, JAVED S, et al. Tuning the hydrophobicity of MOF sponge for efficient oil/water separation[J]. Chemical Physics Impact,2020,1:100001. doi: 10.1016/j.chphi.2020.100001
[16]	YU F, CAO L, MENG Z, et al. Crosslinked waterborne polyurethane with high waterproof performance[J]. Polymer Chemistry,2016,7(23):3913-3922. doi: 10.1039/C6PY00350H
[17]	何影格, 陈媛媛, 刘维仪, 等. 超浸润性可逆切换的超双疏复合海绵材料的制备及油水分离应用[J]. 复合材料学报, 2021, 38(3):854-862. HE Yingge, CHEN Yuanyuan, LIU Weiyi, et al. Preparation of superamphiphobic composite sponge material with super-wetting reversible switching and applicationin oil-water separation[J]. Acta Materiae Compositae Sinica,2021,38(3):854-862(in Chinese).
[18]	谢俊. 亲油疏水海绵和纺织布的制备及其性能研究[D]. 广州: 华南理工大学, 2020. XIE Jun. Preparation and properties of oleophilic and hydrophobic sponge and textile fabric[D]. Guangzhou: South China University of Technology, 2020(in Chinese).
[19]	ZHU H, YANG S, CHEN D, et al. A robust absorbent material based on light-responsive superhydrophobic melamine sponge for oil recovery[J]. Advanced Materials Interfaces,2016,3(5):1500683. doi: 10.1002/admi.201500683
[20]	WANG Y B, SHANG B, HU X X, et al. Temperature control of mussel-inspired chemistry toward hierarchical superhydrophobic surfaces for oil/water separation[J]. Advanced Materials Interfaces, 2017, 4(2): 1095-1105.
[21]	GAO Z, ZHOU S, ZHOU Y, et al. Bio-inspired magnetic superhydrophobic PU-PDA-Fe₃O₄-Ag for effective oil-water separation and its antibacterial activity[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2021,613:126122. doi: 10.1016/j.colsurfa.2020.126122
[22]	LIU C, YANG J, TANG Y, et al. Versatile fabrication of the magnetic polymer-based graphene foam and applications for oil-water separation[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2015,468:10-16.
[23]	袁鹏程. 光响应g-C₃N₄/TiO₂-PVDF膜的制备及油水分离性能研究[D]. 济南: 山东大学, 2021. YUAN Pengcheng. Preparation of photoresponsive g-C₃N₄/TiO₂-PVDF membrane and its oil/water separation performance[D]. Jinan: Shandong University, 2021(in Chinese).
[24]	TAN H, ZHAO Z, NIU M, et al. A facile and versatile method for preparation of colored TiO₂ with enhanced solar-driven photocatalytic activity[J]. Nanoscale,2014,6(17):10216-10223. doi: 10.1039/C4NR02677B
[25]	CHEN S, WANG Y, LI J, et al. Synthesis of black TiO₂ with efficient visible-light photocatalytic activity by ultraviolet light irradiation and low temperature annealing[J]. Mate-rials Research Bulletin,2018,98:280-287. doi: 10.1016/j.materresbull.2017.10.036
[26]	谢浩, 杜晴, 刘俊逸. Ti³⁺自掺杂黑色TiO₂薄膜的制备及可见光催化性能研究[J]. 化工新型材料, 2021, 49(9):267-275. XIE Hao, DU Qing, LIU Junyi. Syntheise of Ti³⁺ self-doped black TiO₂ film with visible-light photocatalytic performance[J]. New Chemical Materials,2021,49(9):267-275(in Chinese).
[27]	DANN T, RAPJEL J, GAMMON S T, et al. Anatase titanium dioxide imparts photoluminescent properties to PA2200 commercial 3D printing material to generate complex optical imaging phantoms[J]. Materials, 2021, 14(7): 1813.
[28]	樊婷玥, 任煜, 赵紫瑶, 等. Ag₆Si₂O₇-TiO₂/PP复合光催化材料的制备及其抗菌性能[J]. 复合材料学报, 2022, 39(8):3915-3921. FAN Tingyue, REN Yu, ZHAO Ziyao, et al. Preparation and antibacterial properties of Ag₆Si₂O₇-TiO₂/PP composite photocatalytic material[J]. ActaMateriae Compositae Sinica,2022,39(8):3915-3921(in Chinese).