Volume 39 Issue 7
Jul.  2022
Turn off MathJax
Article Contents
WEI Huige, LI Guixing, LEI Xiangnan, et al. Polyaniline-corn husk fiber composite based flexible self-standing electrode: Preparation and electrochemical properties[J]. Acta Materiae Compositae Sinica, 2022, 39(7): 3462-3468. doi: 10.13801/j.cnki.fhclxb.20210906.006
Citation: WEI Huige, LI Guixing, LEI Xiangnan, et al. Polyaniline-corn husk fiber composite based flexible self-standing electrode: Preparation and electrochemical properties[J]. Acta Materiae Compositae Sinica, 2022, 39(7): 3462-3468. doi: 10.13801/j.cnki.fhclxb.20210906.006

Polyaniline-corn husk fiber composite based flexible self-standing electrode: Preparation and electrochemical properties

doi: 10.13801/j.cnki.fhclxb.20210906.006
  • Received Date: 2021-06-18
  • Accepted Date: 2021-08-21
  • Rev Recd Date: 2021-08-07
  • Available Online: 2021-09-07
  • Publish Date: 2022-07-30
  • In order to meet the increasing requirements of wearable electronic devices, low-cost, high-performance flexible supercapacitors have become a research hotspot. In this work, flexible, self-standing PANI-CHF-GEL electrode was obtained by growing polyaniline (PANI) on the surface of corn husk fiber (CHF) and mixed with polyvinyl alcohol/sulfuric acid (PVA/H2SO4) gel, followed by a facile frozen-thawing method. PANI-CHF-GEL exhibits excellent mechanical properties (a fracture strength of 259 kPa at a fracture strain of 121%) and good toughness (a fracture energy of 0.167 MJ·cm−3). Employing PVA/H2SO4 as the gel electrolyte, the symmetric PANI-CHF-GEL//PANI-CHF-GEL solid supercapacitor delivers an areal capacitance of 1789.74 mF·cm−2, a power density of 0.34 mW·cm−2, and a corresponding energy density of 3.51 mW·h·cm−2 (@3.00 mA·cm−2). Moreover, the device retains its original properties even bent 90°, indicating its promise potentials for wearable electronics.

     

  • loading
  • [1]
    CHOI C, KIM S H, SIM H J, et al. Weavable coiled carbon nanotube/MnO2/polymer fiber solid-state supercapacitors[J]. Scientific Reports,2015,5:9387. doi: 10.1038/srep09387
    [2]
    WANG C, HU K, LI W, et al. Wearable wire-shaped symmetric supercapacitors based on activated carbon-coated graphite fibers[J]. ACS Applied Materials & Interfaces,2018,10(40):34302-34310. doi: 10.1021/acsami.8b12279
    [3]
    陈美玉, 孙润军, 夏斌斌, 等. 玉米苞叶纤维可降解育果袋材料制备及其性能分析[J]. 农业工程学报, 2021, 37(5):248-255. doi: 10.11975/j.issn.1002-6819.2021.05.029

    CHEN Meiyu, SUN Runjun, XIA Binbin, et al. Preparation of a degradable fruit bagging material from corn bracts and its relative performance[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE),2021,37(5):248-255(in Chinese). doi: 10.11975/j.issn.1002-6819.2021.05.029
    [4]
    LI Z, GONG L. Research progress on applications of polyaniline (PANI) for electrochemical energy storage and conversion[J]. Materials (Basel),2020,13(3):13-45.
    [5]
    LEI T, GUAN M, LIU J, et al. Biocompatible and totally disintegrable semiconducting polymer for ultrathin and ultralightweight transient electronics[J]. Proceedings of the National Academy of Sciences of the United States of America,2017,114(20):5107-5112. doi: 10.1073/pnas.1701478114
    [6]
    CHEN L F, HUANG Z H, LIANG H W, et al. Flexible all-solid-state high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose[J]. Energy & Environmental Science,2013,6(11):42366.
    [7]
    LU C, CHEN X. Latest advances in flexible symmetric supercapacitors: From material engineering to wearable applications[J]. Accounts of Chemical Research,2020,53(8):1468-1477. doi: 10.1021/acs.accounts.0c00205
    [8]
    GUO L, MA W B, WANG Y, et al. A chemically crosslinked hydrogel electrolyte based all-in-one flexible supercapacitor with superior performance[J]. Journal of Alloys and Compounds,2020,843:155895. doi: 10.1016/j.jallcom.2020.155895
    [9]
    韦会鸽, 李桂星, 万同, 等. 聚乳酸基聚苯胺柔性可降解超级电容器的制备及性能[J]. 复合材料学报, 2022, 39(1):193-202.

    WEI Huige, LI Guixing, WAN Tong, et al. Polyaniline growing on polylactic acid substrate towards flexible and biodegradable supercapacitors[J]. Acta Materiae Compositae Sinica,2022,39(1):193-202(in Chinese).
    [10]
    WEI H, WANG H, LI A, et al. Advanced porous hierarchical activated carbon derived from agricultural wastes toward high performance supercapacitors[J]. Journal of Alloys and Compounds,2020,820:153111. doi: 10.1016/j.jallcom.2019.153111
    [11]
    LIAO H, LIU Y, WANG Q, et al. Structure and properties of porous poly(vinyl alcohol) hydrogel beads prepared through a physical-chemical crosslinking method[J]. Journal of Applied Polymer Science,2018,135(26):1-9.
    [12]
    冯龙, 金克霞, 刘杏娥, 等. 黄藤细胞壁微纤丝取向偏振光拉曼光谱研究[J]. 光谱学与光谱分析, 2019, 39(9):2758-2762.

    FENG Long, JIN Kexia, LIU Xinge, et al. Studyt on microfibrils orientation in Daemonorops jekinsiana cell wall by polarized laser raman spectroscopy[J]. Spectroscopy and Spectral Analysis,2019,39(9):2758-2762(in Chinese).
    [13]
    刘杏娥, 金克霞, 崔贺帅, 等. 黄藤细胞壁木质素区域化学分子光谱成像研究[J]. 光谱学与光谱分析, 2017, 37(10):3138-3144.

    LIU Xinge, JIN Kexia, CUI Heshuai, et al. The lignin topochemistry of Daemonorops margaritae (Hance) Becc. by molecular spectroscopic imaging[J]. Spectroscopy and Spectral Analysis,2017,37(10):3138-3144(in Chinese).
    [14]
    祁明辉, 易锬, 莫琪, 等. 硫酸水解辅助高压均质法制备小麦秸秆纳米纤维素[J]. 中国造纸学报, 2020, 35(3):1-8.

    QI Minghui, YI Tan, MO Qi, et al. Preparation of wheat straw nanocellulose by acid hydrolysis assisted high pressure homogenization[J]. Transactions of China Pulp and Paper,2020,35(3):1-8(in Chinese).
    [15]
    吴迪超, 陈超, 侯兴隆, 等. 热解温度对纤维素和木质素成炭结构的影响[J]. 生物质化学工程, 2021, 55(3):1-9. doi: 10.3969/j.issn.1673-5854.2021.03.001

    WU Dichao, CHEN Chao, HOU Xinglong, et al. Effect of pyrolysis temperature on structures of chars forming from cellulose and lignin[J]. Biomass Chemical Engineering,2021,55(3):1-9(in Chinese). doi: 10.3969/j.issn.1673-5854.2021.03.001
    [16]
    TCHOUANK TEKOU CAROL T, MOHAMMED J, BASANDRAI D, et al. X-band shielding of electromagnetic interference (EMI) by Co2Y barium hexaferrite, bismuth copper titanate (BCTO), and polyaniline (PANI) composite[J]. Journal of Magnetism and Magnetic Materials,2020,501:166433. doi: 10.1016/j.jmmm.2020.166433
    [17]
    郭云霞, 刘杰, 梁节英. 电化学改性对PAN基碳纤维表面状态的影响[J]. 复合材料学报, 2005, 22(3):49-54. doi: 10.3321/j.issn:1000-3851.2005.03.010

    GUO Yunxia, LIU Jie, LIANG Jieying. Effect of electrochemical modification on the surfacestate of pan-based carbon fibers[J]. Acta Materiae Compositae Sinica,2005,22(3):49-54(in Chinese). doi: 10.3321/j.issn:1000-3851.2005.03.010
    [18]
    SHENG Z H, SHAO L, CHEN J J, et al. Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis[J]. American Chemical Society Nano,2020,5(6):4350-4358.
    [19]
    JIANG Z, ZHAI S, HUANG M, et al. 3D carbon nanocones/metallic MoS2 nanosheet electrodes towards flexible supercapacitors for wearable electronics[J]. Energy,2021,227:120419. doi: 10.1016/j.energy.2021.120419
    [20]
    YANG C, YANG J, LIANG C, et al. Flexible supercapacitors with tunable capacitance based on reduced graphene oxide/tannin composite for wearable electronics[J]. Journal of Electroanalytical Chemistry,2021,894:115354. doi: 10.1016/j.jelechem.2021.115354
    [21]
    YU N, XIONG R, WANG Y, et al. Facile fabrication of low-cost and scalable graphite tape as novel current collectors for flexible supercapacitors[J]. Journal of Alloys and Compounds,2021,861:158476. doi: 10.1016/j.jallcom.2020.158476
    [22]
    BHARGAVA P, LIU W, POPE M, et al. Substrate comparison for polypyrrole-graphene based high-performance flexible supercapacitors[J]. Electrochimica Acta,2020,358:136846. doi: 10.1016/j.electacta.2020.136846
    [23]
    BARAKZEHI M, MONTAZER M, SHARIF F, et al. A textile-based wearable supercapacitor using reduced graphene oxide/polypyrrole composite[J]. Electrochimica Acta,2019,305:187-196. doi: 10.1016/j.electacta.2019.03.058
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(6)  / Tables(1)

    Article Metrics

    Article views (1124) PDF downloads(43) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return