Preparation and properties of reduced graphene oxide-chitosan composite film

GUO Mingyuan; MA Yongning; CHEN Tengfei

doi:10.13801/j.cnki.fhclxb.20210819.001

Volume 39 Issue 3

Mar. 2021

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GUO Mingyuan, MA Yongning, CHEN Tengfei. Preparation and properties of reduced graphene oxide-chitosan composite film[J]. Acta Materiae Compositae Sinica, 2022, 39(3): 1291-1299. doi: 10.13801/j.cnki.fhclxb.20210819.001

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GUO Mingyuan, MA Yongning, CHEN Tengfei. Preparation and properties of reduced graphene oxide-chitosan composite film[J]. Acta Materiae Compositae Sinica, 2022, 39(3): 1291-1299. doi: 10.13801/j.cnki.fhclxb.20210819.001

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Preparation and properties of reduced graphene oxide-chitosan composite film

doi: 10.13801/j.cnki.fhclxb.20210819.001

1.
College of Chemistry and Materials Science, Weinan Normal University, Weinan 714099, China
2.
College of Chemistry and Chemical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China
3.
Xi’an Changqing Chemical Group Co., Ltd., Changqing Oil Field Branch Company, Petro China, Xi’an 710018, China

Received Date: 2021-04-01
Accepted Date: 2021-08-07
Rev Recd Date: 2021-07-30

Available Online: 2021-08-19

Publish Date: 2021-03-01

Abstract

Abstract

In order to study the effect of reduced graphene oxide (RGO) on the properties of chitosan (CS) films, graphite oxide and CS were used as raw materials to prepare reduced graphene oxide-chitosan film (RGO-CS) by ultrasonic dispersion and vacuum induced self-assembly and various properties of the film was characterized in this paper. In addition, CS and RGO were used as surface sizing agents to study the effects on the water resistance of corrugated paper. The results show that: the RGO-CS film was successfully prepared. SEM images reveal the surface of the RGO-CS film is flat and smooth. Besides, GO-CS composite film has the highest resistivity (17310 mΩ·cm), while resistivity of the RGO-CS film is only about 52.7 mΩ·cm. Using RGO-CS and RGO as additives to coat corrugated paper, compared with the blank sample, it is found that the water resistance is significantly improved. The sizing degree reached 78 s and 74 s, and the maximum contact angle reached 112° and 110°, respectively.
- reduced graphene oxide,
- chitosan,
- composite film,
- water resistance,
- sizing degree,
- electrical property
Long Abstrsct
Innovation Points

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References(22)

References

[1]	KHAN B, ADELEYE A S, BURGESS R M, et al. Effects of graphene oxide nanomaterial exposures on the marine bivalve, Crassostrea virginica[J]. Aquatic Toxicology,2019,216:105297. doi: 10.1016/j.aquatox.2019.105297
[2]	TIAN H, LIU Y W, SHU G Q, et al. Theoretical and experimental research on the influence of initial temperature on the flammability of hydrocarbon-CO₂ mixture using in organic Rankine cycle[J]. Energy,2019,167:939-949. doi: 10.1016/j.energy.2018.10.136
[3]	SHIN J, GUO J, ZHAO T, et al. Functionalized carbon dots on graphene as outstanding non-metal bifunctional oxygen electrocatalyst[J]. Small,2019(16):1900296.
[4]	LIU M, ZHAO H, CHEN S, et al. Interface engineering catalytic graphene for smart colorimetric biosensing[J]. ACS Nano,2012,6(4):3142-3151. doi: 10.1021/nn3010922
[5]	YU D, WANG H, YANG J, et al. Dye wastewater cleanup by graphene composite paper for tailorable supercapacitors[J]. ACS Applied Materials & Interfaces,2017,9(25):21298-21306.
[6]	LIU L, YE D, DONG R, et al. Work function-tunable graphene-polymer composite electrodes for organic light-emitting diodes[J]. ACS Applied Energy Materials,2020,3(4):4067-4077.
[7]	张钊滟, 马帅, 卢鑫, 等. 壳聚糖-氧化石墨烯/热塑性聚氨酯复合材料的原位溶液聚合及性能[J]. 复合材料学报, 2020, 37(11):2726-2734. ZHANG Z, MA S, LU X, et al. In-situ solution polymerization and properties of chitosan-graphene oxide/thermoplastic polyurethane composites[J]. Journal of Composite Materials,2020,37(11):2726-2734(in Chinese).
[8]	YANG H, ZHANG Y, ZHOU F, et al. Preparation, bioactivities and applications in food industry of chitosan-based maillard products: A review[J]. Molecules,2020,26(1):166. doi: 10.3390/molecules26010166
[9]	徐广鹏, 肖瑶, 李苗苗, 等. 功能化壳聚糖改性中空介孔SiO₂[J]. 复合材料学报, 2018, 35(6):1490-1496. XU G P, XIAO Y, LI M M, et al. Functionalized chitosan modified hollow mesoporous SiO₂[J]. Journal of Compo-site Materials,2018,35(6):1490-1496(in Chinese).
[10]	赵益华, 贾凯悦, 季民, 等. 壳聚糖改性硅藻土除藻性能及生态安全性评价[J]. 生态环境学报, 2020, 29(12):2441-2448. ZHAO Y H, JIA K Y, JI M, et al. Algae removal performance and ecological safety evaluation of diatomite modified by chitosan[J]. Journal of Ecological Environment,2020,29(12):2441-2448(in Chinese).
[11]	WANG Q, TANG Y, KE Q, et al. Magnetic lanthanum-doped hydroxyapatite/chitosan scaffolds with endogenous stem cell-recruiting and immunomodulatory properties for bone regeneration[J]. Journal of Materials Chemistry B,2020,8:5280-5292. doi: 10.1039/D0TB00342E
[12]	FURLANI F, SACCO P, DECLEVA E, et al. Chitosan acetylation degree influences the physical properties of polysaccharide nanoparticles: Implication for the innate immune cells response[J]. ACS Applied Materials & Interfaces,2019,11(10):9794-9803.
[13]	FANG L, WEI L, ZHANG J, et al. Preparation and characterization of quaternized chitosan derivatives and assessment of their antioxidant activity[J]. Molecules,2018,23(3):516. doi: 10.3390/molecules23030516
[14]	刘水莲, 周洋, 陈福花, 等. 新型羧甲基壳聚糖水凝胶流变性能, 药物释放及细胞相容性研究[J]. 化学学报, 2015, 73(1):47-52. doi: 10.6023/A14100710 LIU S L, ZHOU Y, CHEN F H, et al. Research on rheological properties, drug release and cytocompatibility of a novel carboxymethyl chitosan hydrogel[J]. Acta Chimica Sinica,2015,73(1):47-52(in Chinese). doi: 10.6023/A14100710
[15]	ZENG S, YU K, LIU Y, et al. Synthesis and antidiabetic properties of chitosan-stabilized selenium nanoparticles[J]. Colloids and surfaces B: Biointerfaces,2018,170:115-121. doi: 10.1016/j.colsurfb.2018.06.003
[16]	SWAGHATHA A, CINDRELLA L. Enhanced self-humidification and proton conductivity in magnetically aligned NiO-Co₃O₄/chitosan nanocomposite membranes for high-temperature PEMFCs[J]. Polymer Journal,2021,53:679-693.
[17]	ALTAF F, BATOOL R, GILL R, et al. Novel N-p-carboxy benzyl chitosan/poly (vinyl alcohol/functionalized zeolite mixed matrix membranes for DMFC applications[J]. Carbohydrate Polymers,2020,237:116111. doi: 10.1016/j.carbpol.2020.116111
[18]	陈新, 李文俊, 钟伟, 等. 壳聚糖-丝心蛋白合金膜的研究(Ⅰ)−合金膜的结构及其对丝心蛋白吸水性和机械性能的改善[J]. 高等学校化学学报, 1998, 19(2):300-304. doi: 10.3321/j.issn:0251-0790.1998.02.022 CHEN X, LI W J, ZHONG W, et al. Studies on chitosan-fibroin blend membrane (Ⅰ)−Structure of the blend membrane and the improvement on the water absorption and the mechanical property of fibroin[J]. Chemical Journal of Chinese Universities,1998,19(2):300-304(in Chinese). doi: 10.3321/j.issn:0251-0790.1998.02.022
[19]	杨富杰, 王亮, 阮文红, 等. 石墨烯基聚合物复合电解质的设计、性能及其应用研究进展[J]. 复合材料学报, 2021, 38(3):680-697. YANG F J, WANG L, RUAN W H, et al. Research progress in the design, performance and application of graphene-based polymer composite electrolytes[J]. Journal of Composite Materials,2021,38(3):680-697(in Chinese).
[20]	YE X, WANG H, TIAN X, et al. Potential features of a 3D compatible polyethyleneimine-graphene oxide interface in WPCs via nano-self-assembly-modification[J]. Polymer Composites,2019,40(8):25177.
[21]	周浪, 王涛. 石墨烯/功能聚合物复合材料[J]. 复合材料学报, 2020, 37(5):997-1014. ZHOU L, WANG T. Graphene/functional polymer compo-sites[J]. Journal of Composite Materials,2020,37(5):997-1014(in Chinese).
[22]	中华人民共和国国家质量监督检验检疫总局. GB/T 5405—2002 纸施胶度的测定(液体渗透法)[S]. 北京: 中国标准出版社, 2002. General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China. GB/T 5405—2002 Paper-determination of the sizing value(Liquid permeance method)[S]. Beijing: China Standards Press, 2002(in Chinese).