Adcanced Search
Volume 38 Issue 12
Nov.  2021
Turn off MathJax
Article Contents
Abstract
References
Related Articles
TIAN Li, WANG Jinjing, LIU Qiang, et al. Synthesis and emulsifying performance of polyester sodium olefin sulfonate polymer as a CO2-switchable surfactant[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 3996-4003. DOI: 10.13801/j.cnki.fhclxb.20210531.004
Citation: TIAN Li, WANG Jinjing, LIU Qiang, et al. Synthesis and emulsifying performance of polyester sodium olefin sulfonate polymer as a CO2-switchable surfactant[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 3996-4003. DOI: 10.13801/j.cnki.fhclxb.20210531.004
shu

Synthesis and emulsifying performance of polyester sodium olefin sulfonate polymer as a CO2-switchable surfactant

  • Hunan Provincial Key Defense Laboratory of High Temperature Wear-resisting Materials and Preparation Technology, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

More Information
  • Received Date: April 24, 2021
  • Accepted Date: May 24, 2021
  • Available Online: May 31, 2021
    Abstract
  • Polymer surfactants are widely used in scientific research and industrial fields such as food, agriculture and spanning. In order to reduce the side effect caused by the residual of the inactive polymer after most of the practical application process, designing and developing switchable polymer surfactants is of great significance and application value. A CO2-switchable surfactant Poly(N, N-Diethylaminoethyl methacrylate-sodium vinylsulfonate) (P(DEAEMA-SVS)) has been synthesized by free radical polymerization. The structure and molecular weight distribution of P(DEAEMA-SVS) were characterized by 1H-NMR and GPC spectra. The stability of P(DEAEMA-SVS) emulsion was studied by the surface tension and interfacial tension. The polymer P(DEAEMA-SVS) with the size of about 113 nm and the narrow particle size distribution form via N, N-Diethylaminoethyl methacrylate (DEAEMA) and sodium vinylsulfonate (SVS) of 1∶1 mole ratio as reaction monomers, which decrease the surface tension of water to 37.279 mN/m and the interfacial tension of water/paraffin wax to 5.492 mN/m. It is indicated that P(DEAEMA-SVS) polymer is an effective CO2-switchable O/W surfactant to stabilize emulsion as a only emulsifier. The surface activity and CO2 response of the polymer were evaluated by mixing the aqueous solution (1wt%) with paraffin wax. Bubbling CO2 for 30 min to the milky emulsion, it turns into clear and bubbling N2 for 30 min at 60℃, and converts to its original state, showing excellent cyclic performance of de-emulsification and re-emulsification process. The research results of emulsification mechanism show that the side-electron mobility and photogenerated electron-hole pairs separation. Chained tertiary amino groups of P(DEAEMA-SVS) polymer protonize and turn into hydrophilic quatemary ammonium salt to destroy the oil/water balance of the emulsion with bubbling CO2, while quatemary ammonium salt deprotonizes and returns into hydrophobic tertiary aminogroups with bubbling N2 at 60℃.
    • Summary
    • Innovation Points
    • FullText(HTML)
    • References (27)
  • [1]
    JIE D, WANG Y, JIAN Z, et al. Multiple stimuli-responsive polymeric micelles for controlled release[J]. Soft Matter,2012,9(2):370-373.
    [2]
    ZHANG Q. Preparation of N2/CO2 triggered reversibly coagulatable and redispersible latexes by emulsion polymerization of styrene with a reactive switchable surfactant[J]. Langmuir,2012,28(14):5940-5946. DOI: 10.1021/la300051w
    [3]
    QIAO W, ZHENG Z, SHI Q. Synthesis and properties of a series of CO2 switchable surfactants with imidazoline group[J]. Journal of Surfactants & Detergents,2012,15(5):533-539.
    [4]
    ZHANG Y M, ZHANG Y D, WANG C, et al. CO2-responsive microemulsion: Reversible switching from an apparent single phase to near-complete phase separation[J]. Green Chemistry,2015,18(2):392-396.
    [5]
    JESSOP, P G, SU X, CUNNINGHAM MF. Switchable surfactants at the polystyrene-water interface: Effect of molecular structure[J]. Green Materials,2014,2(2):69-74. DOI: 10.1680/gmat.13.00015
    [6]
    HAN D, XIA T, BOISSIERE O, et al. General strategy for making CO2-switchable polymers[J]. Acs Macro Letters,2012,1(1):57-61. DOI: 10.1021/mz2000175
    [7]
    LIU Y. Switchable surfactants[J]. Science,2006,313(5789):958-960. DOI: 10.1126/science.1128142
    [8]
    ZHANG Y, YIN H, FENG Y. CO2-responsive anionic wormlike micelles based on natural erucic acid[J]. Green Materials,2014,2(2):95-103. DOI: 10.1680/gmat.13.00016
    [9]
    HAN D, BOISSIERE O, KUMAR S, et al. Two-way CO2-switchable triblock copolymer hydrogels[J]. Macromolecules,2012,45(18):7440-7445. DOI: 10.1021/ma3015189
    [10]
    BROWN P, BUTTS C P, EASTOE J. Stimuli-responsive surfactants[J]. Soft Matter,2013,9(8):2365-2374. DOI: 10.1039/c3sm27716j
    [11]
    LIU F, URBAN M W. Recent advances and challenges in designing stimuli-responsive polymers[J]. Progress in Polymer Science,2010,35(1-2):3-23. DOI: 10.1016/j.progpolymsci.2009.10.002
    [12]
    MORSE A J, DUPIN D, THOMPSON K L, et al. Novel pickering emulsifiers based on pH-responsive poly(tert-butylaminoethyl methacrylate) latexes[J]. Langmuir the Acs Journal of Surfaces & Colloids,2012,28(32):11733-11740.
    [13]
    SCOTT L M. Designing the head group of CO2-triggered switchable surfactants[J]. Rsc Advances,2012,2(11):4925-4931. DOI: 10.1039/c2ra01242a
    [14]
    BROWN P, WASBROUGH M J, GURKAN B E, et al. CO2-responsive microemulsions based on reactive ionic liquids[J]. Langmuir,2014,30(15):4267-72. DOI: 10.1021/la500675g
    [15]
    HU J, LIU S. Responsive polymers for detection and sensing applications: Current status and future developments[J]. Macromolecules,2010,43(20):8315-8330. DOI: 10.1021/ma1005815
    [16]
    DESTRIBATS M, PINAUD F, LAPEYRE V, et al. Pickering emulsions stabilized by soft microgels: Influence of the emulsification process on particle interfacial organization and emulsion properties[J]. Langmuir,2013,29(40):12367-12374. DOI: 10.1021/la402921b
    [17]
    DESTRIBATS M, EYHARTS M, LAPEYRE V, et al. Impact of pNIPAM microgel size on its ability to stabilize pickering emulsions[J]. Langmuir the Acs Journal of Surfaces & Colloids,2014,30(7):1768-1777.
    [18]
    JIANG J, JIANG J, LIU K, et al. Switchable pickering emulsions stabilized by silica nanoparticles hydrophobized in situ with a switchable surfactant[J]. Angewandte Chemie,2013,52(47):12373-12376. DOI: 10.1002/anie.201305947
    [19]
    MORSE A J, ARMES S P, THONPSON K C, et al. Novel pickering emulsifiers based on pH-responsive poly(2-(diethylamino)ethyl methacrylate) latexes[J]. Langmuir,2013,29(18):5466-5475. DOI: 10.1021/la400786a
    [20]
    ZHANG Q Y, WANG G Q, YAN W J, et al. Switchable block copolymer surfactants for preparation of reversibly coagulatable and redispersible poly(methyl methacrylate) latexes[J]. Macromolecules,2013,46(4):1261-1267. DOI: 10.1021/ma302505r
    [21]
    MORSE A J, ARMES S P, MILLS P, et al. Stopped-flow kinetics of pH-responsive polyamine latexes: How fast is the latex-to-microgel transition?[J]. Langmuir the ACS Journal of Surfaces& Colloids,2013,29(49):15209-15216.
    [22]
    WANG X, JIANG G H, LI X, et al. Synthesis of multi-responsive polymeric nanocarriers for controlled release of bioactive agents[J]. Polymer Chemistry,2013,4(17):4574-4577. DOI: 10.1039/c3py00746d
    [23]
    LU H S, GUAN X Q, DAI S S, et al. Application of CO2-triggered switchable surfactants to form emulsion with xinjiang heavy oil[J]. Journal of Dispersion Science and Technology,2014,35(5):655-662. DOI: 10.1080/01932691.2013.803254
    [24]
    LU H, GUAN X Q, WANG B G, et al. CO2-switchable oil/water emulsion for pipeline transport of heavy oil[J]. Journal of Surfactants and Detergents,2015,18(5):773-782. DOI: 10.1007/s11743-015-1712-8
    [25]
    RICHTERING W. Responsive emulsions stabilized by stimuli-sensitive microgels: Emulsions with special non-Pickering properties[J]. Langmuir the ACS Journal of Surfaces & Colloids,2014,28(50):17218-17226.
    [26]
    WANG J J, WANG H F, LI Y, et al. Formation and CO2/N2 switchable ability of a novel copolymer poly(N, N-diethylaminoethyl methacrylate-co-codium vinyl-sulfonate)[J]. Polymer Science, Series A,2018,60(5):1-6.
    [27]
    KUMAR S, TONG X, DORY Y, et al. A CO2-switchable polymer brush for reversible capture and release of proteins[J]. Chemical Communications,2013,49(1):90-92. DOI: 10.1039/C2CC36284H
    • Related Articles

  • Related Articles

    [1]LI Ke, WANG Shaohua, ZHENG Shuning, FAN Jiajun, ZHU Juntao. Numerical simulation and theoretical analysis of flexural strengthening of RC beams with high-strength steel strand mesh/ECC[J]. Acta Materiae Compositae Sinica, 2024, 41(11): 6077-6091. DOI: 10.13801/j.cnki.fhclxb.20240306.001
    [2]LI Ke, CHEN Xiang, FAN Jiajun, NIU Zili, ZHANG Zhe. Experiment on RC beams strengthened with high-strength steel strand meshes and ECC under secondary load[J]. Acta Materiae Compositae Sinica, 2023, 40(8): 4670-4681. DOI: 10.13801/j.cnki.fhclxb.20221102.003
    [3]ZHU Juntao, LIU Yawen, WANG Juan, LI Ke. Experimental on bond properties of grooved interface between high-strength steel wire mesh reinforced ECC and concrete[J]. Acta Materiae Compositae Sinica, 2023, 40(5): 2913-2925. DOI: 10.13801/j.cnki.fhclxb.20220721.001
    [4]HUI Yingxin, WANG Wenwei, ZHU Zhongfeng. Cyclic compression behavior of FRP-ECC confined concrete cylinder[J]. Acta Materiae Compositae Sinica, 2022, 39(11): 5586-5598. DOI: 10.13801/j.cnki.fhclxb.20220516.004
    [5]LI Ke, ZHAO Jiali, LI Zhiqiang, ZHU Juntao. Experiment on non-damaged RC beams strengthened by high-strength steel wire strand meshes reinforced ECC in bending[J]. Acta Materiae Compositae Sinica, 2022, 39(7): 3428-3440. DOI: 10.13801/j.cnki.fhclxb.20210816.004
    [6]WANG Xinling, LI Yunpu, LIMIAO Haofu, FAN Jiajun. Compressive behavior of RC short columns strengthened with high-strength stainless steel wire strand mesh and ECC[J]. Acta Materiae Compositae Sinica, 2022, 39(5): 2308-2317. DOI: 10.13801/j.cnki.fhclxb.20210804.001
    [7]WANG Xinling, WEI Yaoxin, FAN Jianwei, ZHU Juntao. Experimental study on compressive performance of new composite material “concrete confined with high-strength steel stranded wire meshes/ECC”[J]. Acta Materiae Compositae Sinica, 2021, 38(11): 3904-3911. DOI: 10.13801/j.cnki.fhclxb.20201225.002
    [8]WANG Xinling, CHEN Yongjie, QIAN Wenwen, LI Ke, ZHU Juntao. Experiment on bending performance of engineered cementitious composites reinforced by high-strength stainless steel wire strand mesh[J]. Acta Materiae Compositae Sinica, 2021, 38(4): 1292-1301. DOI: 10.13801/j.cnki.fhclxb.20200805.001
    [9]WANG Xinling, YANG Guanghua, QIAN Wenwen, LI Ke, ZHU Juntao. Tensile stress-strain relationship of engineered cementitious composites reinforced by high-strength stainless steel wire mesh[J]. Acta Materiae Compositae Sinica, 2020, 37(12): 3220-3228. DOI: 10.13801/j.cnki.fhclxb.20200428.002
    [10]ZHU Juntao, ZHAO Yalou, LI Yi, WANG Xinling. Experiment on bonding and anchoring performance between high-strength stainless steel wire mesh and engineered cementitious composites[J]. Acta Materiae Compositae Sinica, 2020, 37(7): 1731-1742. DOI: 10.13801/j.cnki.fhclxb.20191010.001
    • Supplements (0)

  • Cited by

    Periodical cited type(10)

    1. 徐建蓉，梅启林，姜端洋，蔡永祺，刘备，丁国民. Ca~(2+)辅助增强CNT/PEEK界面结合及其导电复合材料制备与性能. 复合材料学报. 2025(01): 283-298 . 本站查看
    2. 赵宏婷，王鹤峰，罗居杰，贾宜委，何艳骄，树学峰. N, S共掺杂碳/PVDF纳米复合膜的电磁屏蔽效能及其力学性能. 复合材料学报. 2025(02): 845-853 . 本站查看
    3. 朱再斌，凌辉，杨小平，李刚，王超. 碳纳米管膜层间增强增刚碳纤维增强树脂基复合材料的压缩强度与导热性能. 复合材料学报. 2024(03): 1235-1248 . 本站查看
    4. 施水娟，卞达，李佳红，王恺璇，徐鹏程，赵鹏，赵永武，陈义. 不同注射温度和热处理对聚醚醚酮/碳纤维复合材料摩擦磨损性能的影响. 塑料科技. 2024(04): 23-27 .
    5. 周杰，何相明，耿闻，李闯，李伟. 碳纳米管改性热固性树脂的研究进展. 广州化工. 2024(14): 11-13 .
    6. 王文波，宋彦平，李年，王振洋. 激光诱导石墨烯的纳米银颗粒原位修饰及其导电性能调控. 复合材料学报. 2024(08): 4124-4133 . 本站查看
    7. 李纪康，刘雁雁，王维超，郑振荣. 纳米材料在防护纺织品中的应用研究. 天津纺织科技. 2023(03): 1-5 .
    8. 李亚洲 ，杨强 ，彭瑞龙 ，王富 ，李涤尘 . 聚醚醚酮及其复合材料激光粉末床熔融成形的研究现状与展望. 精密成形工程. 2023(11): 46-60 .
    9. 任天翔，滕晓波，黄兴，马金星，赵德方，占海华. 聚醚醚酮的改性及应用研究进展. 塑料科技. 2022(09): 123-128 .
    10. 杨琴，汪莹，刘逸众. 热塑性树脂聚醚醚酮(PEEK)改性研究进展. 长沙航空职业技术学院学报. 2022(04): 33-37 .

    Other cited types(8)

Catalog

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (1069) PDF downloads (66) Cited by(18)
    Related

    Copyright © 2009 《复合材料学报》编辑部

    Address: 37 Xueyuan Road, Haidian District, BeijingTel: 010-82316907, 82315973Email: fhclxb@buaa.edu.cn

    Supported by: Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return