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WANG Shenwan, ZHONG Shuang, ZHENG Lili, et al. Preparation of calcite/biochar composite by co-pyrolysis and its adsorption properties and mechanism for Pb(II)[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4282-4293. DOI: 10.13801/j.cnki.fhclxb.20210309.002
Citation: WANG Shenwan, ZHONG Shuang, ZHENG Lili, et al. Preparation of calcite/biochar composite by co-pyrolysis and its adsorption properties and mechanism for Pb(II)[J]. Acta Materiae Compositae Sinica, 2021, 38(12): 4282-4293. DOI: 10.13801/j.cnki.fhclxb.20210309.002
shu

Preparation of calcite/biochar composite by co-pyrolysis and its adsorption properties and mechanism for Pb(II)

  • 1.

    Haikou Experimental Station, Chinese Academy of Tropical Agricultural Sciences, Haikou 571101, China

  • 2.

    College of Food Science and Engineering, Hainan University, Haikou 570228, China

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  • Received Date: December 13, 2020
  • Accepted Date: February 24, 2021
  • Available Online: March 09, 2021
    Abstract
  • In order to obtain a biochar material which adsorbs PB (II) in wastewater efficiently, calcite/biochar (CAL/BC) composite was prepared by co-pyrolysis at 500℃, 600℃ and 700℃, using coconut shell (CS) and calcite (CAL) as raw materials. The surface morphology and structure of CAL/BC composites were characterized by SEM, ICP-MS, BET, XRD and FTIR. The results show that CAL and CS combine tightly under the three pyrolysis tempera-tures, and CAL/BC has a large specific surface area and a large number of functional groups. The maximum adsorption capacities of PB (II) on CAL/BC composite (CAL∶ CS=1∶ 2, mass ratio) prepared at 500℃, 600℃, and 700℃ are 95.24 mg·g−1, 99.01 mg·g−1, and 185.19 mg·g−1. The optimum adsorption condition is pH=5.5 and the amount of adsorbent is 1.5 g·L−1. The adsorption process conforms to the second-order kinetic model and Langmuir isotherm model. The mechanisms of adsorption of Pb(II) on CAL/BC composites are precipitation, ion exchange, cation-π action, pore filling and electrostatic gravitation. In addition, the removal rate of Pb(II) by CAL/BC composite remains high level after 4 adsorption-desorption cycles. Therefore, the CAL/BC composite prepared by co-pyrolysis has a excellent application prospect in the treatment of Pb(II) in wastewater.
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