Fabrication and characterization of shape-stabilized phase change materials of ZIF-8/P(tetradecyl acrylate-<i>co</i>-hexadecyl acrylate) and prussian blue/ (tetradecyl acrylate-<i>co</i>-hexadecyl acrylate)

CHEN Sai; TAO Lijuan; LI Wei; ZHAO Yongnan; ZHANG Xingxiang

doi:10.13801/j.cnki.fhclxb.20210113.001

Volume 38 Issue 11

Nov. 2021

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CHEN Sai, TAO Lijuan, LI Wei, et al. Fabrication and characterization of shape-stabilized phase change materials of ZIF-8/P(tetradecyl acrylate-co-hexadecyl acrylate) and prussian blue/ (tetradecyl acrylate-co-hexadecyl acrylate)[J]. Acta Materiae Compositae Sinica, 2021, 38(11): 3896-3903. doi: 10.13801/j.cnki.fhclxb.20210113.001

Citation:

CHEN Sai, TAO Lijuan, LI Wei, et al. Fabrication and characterization of shape-stabilized phase change materials of ZIF-8/P(tetradecyl acrylate-co-hexadecyl acrylate) and prussian blue/ (tetradecyl acrylate-co-hexadecyl acrylate)[J]. Acta Materiae Compositae Sinica, 2021, 38(11): 3896-3903. doi: 10.13801/j.cnki.fhclxb.20210113.001

Citation:

CHEN Sai, TAO Lijuan, LI Wei, et al. Fabrication and characterization of shape-stabilized phase change materials of ZIF-8/P(tetradecyl acrylate-co-hexadecyl acrylate) and prussian blue/ (tetradecyl acrylate-co-hexadecyl acrylate)[J]. Acta Materiae Compositae Sinica, 2021, 38(11): 3896-3903. doi: 10.13801/j.cnki.fhclxb.20210113.001

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Fabrication and characterization of shape-stabilized phase change materials of ZIF-8/P(tetradecyl acrylate-co-hexadecyl acrylate) and prussian blue/ (tetradecyl acrylate-co-hexadecyl acrylate)

doi: 10.13801/j.cnki.fhclxb.20210113.001

CHEN Sai^1
,,
TAO Lijuan^1
,,
LI Wei^{1, 2
,},
ZHAO Yongnan^{1, 2
,},
ZHANG Xingxiang^{1, 2
,
,}

1.
School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
2.
Tianjin Municipal Key Lab of Advanced Fiber and Energy Storage Technology, Tianjin 300387, China

Received Date: 2020-11-16
Accepted Date: 2021-01-05

Available Online: 2021-01-14

Publish Date: 2021-11-01

Abstract

Abstract

A novel strategy based on Metal-organic frameworks nanoparticles (MOFs NPs)-stabilized suspension polymerization has been achieved for the fabrication of multifunctional ZIF-8/P(TDA-co-HDA) and PB/P(TDA-co-HDA) composites. By using this technique, functional nanoparticles can be immobilized on the surface of polymer. In this paper, ZIF-8 and PB nanoparticles (NPs) were used as stabilizer for the suspension polymerization in water and ZIF-8/P(TDA-co-HDA) and PB/P(TDA-co-HDA) composites are successfully synthesized. ZIF-8/P(TDA-co-HDA) and PB/P(TDA-co-HDA) absorbed heat at 37.5℃, 39.1℃ and released it at 8.4℃, 10.1℃ with a heat storage capacity of 63 J/g, 68 J/g, respectively. The material retains its shape without any leakage at 60℃, which is much higher than that of the melting temperature of P(TDA-co-HDA). The ZIF-8/P(TDA-co-HDA) and PB/P(TDA-co-HDA) composites exhibit good crystallization behaviors and excellent thermal reliabilities after 1000 thermal cycles. The thermal properties of the ZIF-8/P(TDA-co-HDA) and PB/P(TDA-co-HDA) composites were also investigated. The novel shape-stabilized PCMs fabricated in this study have potential uses in thermal energy storage applications.
- metal-organic frameworks material,
- phase change material,
- shape-stabilized,
- poly(alkylacrylate),
- energy storage material
Long Abstrsct
Innovation Points

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References(22)

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