Preparation and electrochemical performance of Au-Pt nanoparticles/graphene-cellulose microfiber composite electrodes

HUANG Cuiping; LI Shanshan; QI Tianle; ZHONG Tingting; CHEN Liying; ZHANG Zhiqing; SHEN Guanghui

doi:10.13801/j.cnki.fhclxb.20200928.005

Volume 38 Issue 7

Jul. 2021

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HUANG Cuiping, LI Shanshan, QI Tianle, et al. Preparation and electrochemical performance of Au-Pt nanoparticles/graphene-cellulose microfiber composite electrodes[J]. Acta Materiae Compositae Sinica, 2021, 38(7): 2274-2283. doi: 10.13801/j.cnki.fhclxb.20200928.005

Citation:

HUANG Cuiping, LI Shanshan, QI Tianle, et al. Preparation and electrochemical performance of Au-Pt nanoparticles/graphene-cellulose microfiber composite electrodes[J]. Acta Materiae Compositae Sinica, 2021, 38(7): 2274-2283. doi: 10.13801/j.cnki.fhclxb.20200928.005

Citation:

HUANG Cuiping, LI Shanshan, QI Tianle, et al. Preparation and electrochemical performance of Au-Pt nanoparticles/graphene-cellulose microfiber composite electrodes[J]. Acta Materiae Compositae Sinica, 2021, 38(7): 2274-2283. doi: 10.13801/j.cnki.fhclxb.20200928.005

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Preparation and electrochemical performance of Au-Pt nanoparticles/graphene-cellulose microfiber composite electrodes

doi: 10.13801/j.cnki.fhclxb.20200928.005

School of Food Science, Sichuan Agricultural University, Ya’an 625014, China

Received Date: 2020-08-20
Accepted Date: 2020-09-21

Available Online: 2020-09-29

Publish Date: 2021-07-15

Abstract

Abstract

The graphene and metal nano-materials are excellent conductive nanomaterials. In order to construct an electrochemical sensing interface with high-efficiency active surface area, glassy carbon electrode was used as a conductive substrate, and Au-Pt nano particles/reduced graphene oxide-cellulose microfiber (Au-Pt NPs/RGO-CMF) composites were successfully prepared by drip coating combined with one-step electrodeposition. The SEM, atomic force microscopy (AFM), EDS and Raman spectroscopy analysis show that Au-Pt nanoparticles are uniformly distributed on the thin layer of RGO-CMF, and at the same time, graphene oxide (GO) reduce to RGO. Using potassium ferricyanide as a redox probe to study the electrochemical properties of the interface, under optimized experimental conditions (cyclic voltammetry electrodeposition: Potential is −1.2-0 V, period is 20, electrolyte pH value is 6, drops coated GO-CMF volume is 8 μL), the high-efficiency active surface area of Au-Pt NPs/RGO-CMF composites (3.54 cm²) is much better than that of bare glassy carbon electrode (1.52 cm²). It shows that the constructed interface has high electrocatalytic activity, which provides theoretical support for the further application of the sensor.
- graphene oxide,
- cellulose microfiber,
- Au-Pt nanoparticles,
- composites,
- electrochemical properties
Long Abstrsct
Innovation Points

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References(29)

References

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