Compression molding process and performance of hollow glass microsphere/epoxy resin solid buoyancy materials

WU Shaohui; MA Rongfeng; WU Pingwei; DAI Jinhui

doi:10.13801/j.cnki.fhclxb.20200106.001

Volume 37 Issue 10

Oct. 2020

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WU Shaohui, MA Rongfeng, WU Pingwei, et al. Compression molding process and performance of hollow glass microsphere/epoxy resin solid buoyancy materials[J]. Acta Materiae Compositae Sinica, 2020, 37(10): 2401-2408. doi: 10.13801/j.cnki.fhclxb.20200106.001

Citation:

WU Shaohui, MA Rongfeng, WU Pingwei, et al. Compression molding process and performance of hollow glass microsphere/epoxy resin solid buoyancy materials[J]. Acta Materiae Compositae Sinica, 2020, 37(10): 2401-2408. doi: 10.13801/j.cnki.fhclxb.20200106.001

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Compression molding process and performance of hollow glass microsphere/epoxy resin solid buoyancy materials

doi: 10.13801/j.cnki.fhclxb.20200106.001

WU Shaohui^1
,,
MA Rongfeng^2
,,
WU Pingwei^1
,,
DAI Jinhui^{1
,
,}

1.
School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
2.
Taishan Fiberglass Inc., Taian 271000, China

Received Date: 2019-11-13
Accepted Date: 2019-12-29

Available Online: 2020-01-06

Publish Date: 2020-10-15

Abstract

Abstract

A vacuum-assisted compression molding and free curing method suitable for the preparation of epoxy resin-based solid buoyancy materials was proposed by learning from the ceramic material molding process, which realized the separation of molding and solidification during the preparation of solid buoyancy materials and provided a new method for the preparation of high performance solid buoyancy materials. The epoxy resin (E-4221) was used as the matrix, and the hollow glass microsphere (HGMS) was used as the filling material. The HGMS/E-4221 solid buoyancy material with high HGMS volume fraction was prepared by compression molding and free curing method. The effects of volume fraction of HGMS and molding pressure on the density, compressive strength and water absorption of HGMS/E-4221 solid buoyancy materials were studied. The results show that the vacuum-assisted compression molding and free curing method is suitable for the preparation of HGMS/E-4221 solid buoyancy materials with HGMS volume fraction of 65%-67%. The obtained HGMS/E-4221 solid buoyancy material has a den-sity of 0.621-0.655 g/cm³ and a suitable depth of 8 000-10 000 m.
- solid buoyancy material,
- epoxy resin,
- hollow glass microsphere,
- compression molding,
- composite foam material
Long Abstrsct
Innovation Points

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References(24)

References

[1]	MICHEL J. In the trenches topside remembrances by the chief of the boat, DSV trieste[J]. Marine Technology Society Journal,2009,43(5):20-22. doi: 10.4031/MTSJ.43.5.8
[2]	YANO Y, TAKAGAWA S. Study on buoyancy material by engineering ceramics[J]. Report of Japan Marine Science and Technology Center,2004,49:81-87.
[3]	GALL M L, CHOQUEUSE D, GAC P Y L, et al. Novel mechanical characterization method for deep sea buoyancy material under hydrostatic[J]. Polymer Testing,2014,39(10):36-44.
[4]	WESTON S, OLSSON M, MEREWETHER R, et al. Flotation in ocean trenches using hollow ceramic spheres[J]. Marine Technology Society Journal,2009,43(5):110-114. doi: 10.4031/MTSJ.43.5.24
[5]	何成贵, 张培志, 郭方全, 等. 全海深浮力材料发展综述[J]. 机械工程材料, 2017, 41(9):14-18. doi: 10.11973/jxgccl201709002 HE Chenggui, ZHANG Peizhi, GUO Wanquang, et al. Development review of full ocean depth buoyancy material[J]. Materials for Mechanical Engineering,2017,41(9):14-18(in Chinese). doi: 10.11973/jxgccl201709002
[6]	李乐, 于良民, 李昌诚, 等. 固体浮力材料及其性能研究现状[J]. 材料导报, 2012, 26(17):66-69. doi: 10.3969/j.issn.1005-023X.2012.17.014 LI Le, YU Liangmin, LI Changcheng, et al. Solid buoyancy material and research status on its properties[J]. Materials Review,2012,26(17):66-69(in Chinese). doi: 10.3969/j.issn.1005-023X.2012.17.014
[7]	黄炳坤. 固体浮力材料制备及性能研究[D]. 大连: 大连理工大学, 2015. HUANG Bingkui. Research on the preparation and performance of solid buoyancy material[D]. Dalian: Dalian University of Technology, 2015(in Chinese).
[8]	汪永良. 三相组合泡沫材料[J]. 化学工程师, 1988(5):7-9. WANG Yongliang. Three-phase composite foam material[J]. Chemical Engineer,1988(5):7-9(in Chinese).
[9]	宋邦增. 固体浮力材料研制[J]. 材料开发与应用, 1986(3):9-15. SONG Bangzeng. Development of solid buoyancy materials[J]. Development and Application of Materials,1986(3):9-15(in Chinese).
[10]	刘峰, 李向阳. 中国载人深潜蛟龙号研发历程[M]. 北京: 海洋出版社, 2016. LIU Feng, LI Xiangyang. Development of Chinese submersible Jiaolong's footmarks[M]. Beijing: China Ocean Press, 2016(in Chinese).
[11]	AN Zhenguo, ZHANG Jingjie. Glass-iron oxide, glass-iron and glass-iron-carbon composite hollow particles with tunable electromagnetic properties[J]. Journal of Materials Chemistry C,2016,4(34):7979-7988. doi: 10.1039/C6TC02669A
[12]	AN Zhenguo, ZHANG Jingjie, et al. Silicon rubber/hollow glass microsphere composites: Influence of broken, hollow glass microsphere on mechanical and thermal insulation property[J]. Composites Science & Technology,2013,79(5):64-69.
[13]	HU Yan, WANG Yuanhua, AN Zhenguo, et al. The super-hydrophobic IR-reflectivity TiO₂ coated hollow glass microspheres synthesized by soft-chemistry method[J]. Journal of Physics & Chemistry of Solids,2016,98:43-49.
[14]	李芝华, 陈明, 李珍, 等. 界面活化处理对固体浮力材料力学性能的影响[J]. 高分子材料科学与工程, 2016, 32(11):70-74. LI Zhihua, CHEN Ming, LI Zhen, et al. Influences of surface treatment on mechanical property of epoxy resin solid buoyancy materials[J]. Polymer Materials Science & Engineering,2016,32(11):70-74(in Chinese).
[15]	陈晨阳, 李仙会, 马颖琦, 等. 环氧树脂基固体浮力材料的吸水性及压缩性[J]. 理化检验(物理分册), 2018, 54(6):390-394. CHEN Chenyang, LI Xianhui, MA Yingqi, et al. Water absorption and compressibility of solid buoyancy materials based on epoxy resins[J]. Physical Testing and Chemical Analysis(Part A: Physical Testing),2018,54(6):390-394(in Chinese).
[16]	周金磊, 戴金辉, 吴平伟, 等. 环氧树脂基固体浮力材料的制备及性能研究[J]. 材料开发与应用, 2013, 28(2):59-65. ZHOU Jinlei, DAI Jinhui, WU Pingwei, et al. Research on preparation and properties of solid buoyancy materials based on epoxy resins[J]. Development and Application of Materials,2013,28(2):59-65(in Chinese).
[17]	马新蕾, 戴金辉, 周金磊, 等. 空心微珠对树脂基复合材料成型及性能的影响[J]. 材料科学, 2013, 3(1):30-34. doi: 10.12677/MS.2013.31006 MA Xinlei, DAI Jinhui, ZHOU Jinlei, et al. Effect of content of hollow glass microsphere on forming and properties of resin-based composite material[J]. Material Sciences,2013,3(1):30-34(in Chinese). doi: 10.12677/MS.2013.31006
[18]	中国国家标准化管理委员会. 树脂浇铸体压缩性能试验方法: GB/T 2569—1995[S]. 北京: 中国标准出版社, 1996. Standardization Administration of the People’s Republic of China. Test method for compressive properties of resin casting body: GB/T 2569—1995[S]. Beijing: China Standards Press, 1996(in Chinese).
[19]	刘艳, 刘文智, 马春霞. 深水固体浮力材料的制备及性能研究[J]. 舰船科学技术, 2017, 39(5):87-90. LIU Yan, LIU Wenzhi, MA Chunxia. Research on preparation and properties of deep water solid buoyancy materials[J]. Ship Science and Technology,2017,39(5):87-90(in Chinese).
[20]	李涛, 魏明坤, 王逢爽. 成型因素对Al₂O₃-ZrO₂陶瓷材料性能的影响[J]. 武汉理工大学学报, 2010, 32(18):20-23. doi: 10.3963/j.issn.1671-4431.2010.18.006 LI Tao, WEI Mingkun, WANG Fengshuang. Effect of forming factors for the property of Al₂O₃-ZrO₂ ceramic[J]. Journal of Wuhan University of Technology,2010,32(18):20-23(in Chinese). doi: 10.3963/j.issn.1671-4431.2010.18.006
[21]	刘圆圆, 戴金辉, 吴平伟. 模压成型高微珠含量复合泡沫材料的制备及性能研究[J]. 材料开发与应用, 2015, 30(3):72-77. LIU Yuanyuan, DAI Jinhui, WU Pingwei. Preparation and properties of high microspheres levels of syntactic foam by molded forming[J]. Development and Application of Materials,2015,30(3):72-77(in Chinese).
[22]	任素娥, 陶鑫, 耿海涛, 等. 空心微球/环氧树脂材料制备及性能研究[J]. 稀有金属材料与工程, 2015, 44(S1):299-302. REN Sue, TAO Xin, GENG Haitao, et al. Preparation and properties of hollow microspheres/epoxy resin materials[J]. Rare Metal Materials and Engineering,2015,44(S1):299-302(in Chinese).
[23]	王平, 严开祺, 潘顺龙, 等. 深水固体浮力材料研究进展[J]. 工程研究-跨学科视野中的工程, 2016, 8(2):223-229. WANG Ping, YAN Kaiqi, PAN Shunlong, et al. Research progress of deep water solid buoyancy materials[J]. Engineering Research-Engineering from an Interdisciplinary Perspective,2016,8(2):223-229(in Chinese).
[24]	梁小杰, 梁忠旭, 周媛, 等. 全海深浮力材料性能分析[J]. 热固性树脂, 2016, 31(5):38-41. LIANG Xiaojie, LIANG Zhongxu, ZHOU Yuan, et al. Performance analysis of deep sea buoyancy materials[J]. Thermosetting Resin,2016,31(5):38-41(in Chinese).