The structural stability of Al
2TiO
5ss/3Al
2O
3·2SiO
2ss composite based on middle-low grade bauxite calcined at 1 600℃ and held subsequently at 1 200℃ for 12 h was studied by XRD, SEM and energy dispersive spectroscope (EDS). The results show that after middle-low grade bauxite being calcined at 1 600℃, its crystal phase composition consists of 3Al
2O
3·2SiO
2ss, Al
2TiO
5ss and a little cristobalite, in which Fe
3+/Ti
4+ cations exsit in crystalline phases (3Al
2O
3·2SiO
2ss and Al
2TiO
5ss) and amorphous phase (silicate) in different forms. Al
2TiO
5ss is separated and huddled by 3Al
2O
3·2SiO
2ss containing Fe
3+/Ti
4+ cations, restraining its decomposition; in addition, both 3Al
2O
3·2SiO
2ss and Al
2TiO
5ss build compact skeleton structure of Al
2TiO
5ss/3Al
2O
3·2SiO
2ss synthesis system based on middle-low grade bauxite due to their near element composition, which avoids appearance of silicate phases with low melting point and further endows good structural stability.