Phase separation and rheological behavior of a new biphenyl  poly(aryl-ether-ketone)-bismaleimide composite resin

HU Xiaolan; YAN Jianlong; YU Ronglu; ZHOU Yujing; LI Weidong; LIU Gang; YI Xiaosu

doi:10.13801/j.cnki.fhclxb.20201015.004

Volume 38 Issue 8

Aug. 2021

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Article Navigation > Acta Materiae Compositae Sinica > 2021 > 38(8): 2568-2577

HU Xiaolan, YAN Jianlong, YU Ronglu, et al. Phase separation and rheological behavior of a new biphenyl poly(aryl-ether-ketone)-bismaleimide composite resin[J]. Acta Materiae Compositae Sinica, 2021, 38(8): 2568-2577. doi: 10.13801/j.cnki.fhclxb.20201015.004

Citation:

HU Xiaolan, YAN Jianlong, YU Ronglu, et al. Phase separation and rheological behavior of a new biphenyl poly(aryl-ether-ketone)-bismaleimide composite resin[J]. Acta Materiae Compositae Sinica, 2021, 38(8): 2568-2577. doi: 10.13801/j.cnki.fhclxb.20201015.004

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Phase separation and rheological behavior of a new biphenyl poly(aryl-ether-ketone)-bismaleimide composite resin

doi: 10.13801/j.cnki.fhclxb.20201015.004

HU Xiaolan^{1
,
,},
YAN Jianlong^1
,,
YU Ronglu^1
,,
ZHOU Yujing^4
,,
LI Weidong²,
LIU Gang^3
,,
YI Xiaosu²

1.
College of Materials, Xiamen University, Xiamen 361005, China
2.
National Key Laboratory of Advanced Composites, AVIC Composite Technology Center, AVIC Composite Corporation LTD., Beijing 101300, China
3.
Center for Advanced Low-dimension Materials, Donghua University, Shanghai 201620, China
4.
State Key Laboratory of Advanced Forming Technology & Equipment, Beijing Jike Guochuang Lightweight Science Research Institute CO. LTD., Beijing 100083, China

Received Date: 2020-08-13
Accepted Date: 2020-10-04

Available Online: 2020-10-15

Publish Date: 2021-08-15

Abstract

Abstract

Ex-situ toughening technology is a good solution to improve the toughness of intrinsically brittle thermosetting resin matrix fiber composites. In order to better combine the ex-situ toughening technology with resin transfer molding (RTM) process to prepare high performance bismaleimide (BMI) resin matrix composites, in this paper, based on a new thermoplastic biphenyl polyether ketone (PAEK-B) resin, the phase separation behavior of the PAEK-B in BMI resin and carbon fiber composites, and the rheological properties of PAEK-B/BMI composite resin were studied. The results show that the phase separation behavior of PAEK-B occurs in the injection window temperature of BMI resin for a certain time, and the phase separation structure is maintained in the carbon fiber (CF)/PAEK-B/BMI composites prepared by RTM process. The solution of PAEK-B in the BMI resin is affected by the injection temperature of BMI resin. The initial viscosity of the BMI resin decreases with the increase of injection temperature, but the inflection point time of the PAEK-B/BMI composite resin decreases; The PAEK-B/BMI composite resin accords with the Winter-Chambon criterion. The tanδ of the composite resin has no dependence on the frequency, and the gel activation energy of the composite resin increases with the increase of PAEK-B content.
- ex-situ toughening technology,
- bismaleimide resin,
- phase separation,
- morphology,
- rheological behavior,
- resin transfer molding (RTM)
Long Abstrsct
Innovation Points

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References(24)

References

[1]	陈祥宝, 张宝艳, 邢丽英. 先进树脂基复合材料技术发展及应用现状[J]. 中国材料进展, 2009, 28(6):2-12. CHEN Xiangbao, ZHANG Baoyan, XING Liying. Application and development of advanced polymer matrix composites[J]. Materials China,2009,28(6):2-12(in Chinese).
[2]	CHEN B, LI Y, GUAN Q, et al. Preparation and mechanism of shape memory bismaleimide resins with high transition temperature, high toughness and good processability[J]. Journal of Materials Science,2018,53(3):10798-10811.
[3]	IREDALE R J, WARD C, HAMERTON I. Modern advances in bismaleimide resin technology: A 21st century perspective on the chemistry of addition polyimides[J]. Progress in Polymer Science,2017,69:1-21. doi: 10.1016/j.progpolymsci.2016.12.002
[4]	王超, 黄玉东, 张斌. 液体端羧基丁腈橡胶改性双马来酰亚胺结构胶粘剂(Ⅰ)双马来酰亚胺树脂及胶粘剂的合成[J]. 高分子材料科学与工程, 2003, 19(2):86-88. doi: 10.3321/j.issn:1000-7555.2003.02.021 WANG Chao, HUANG Yudong, ZHANG Bin. CTBN modified BMI construction adhesive (Ⅰ) synthesis of BMI and the adhesive[J]. Polymer Materials Science & Engineering,2003,19(2):86-88(in Chinese). doi: 10.3321/j.issn:1000-7555.2003.02.021
[5]	杨海冬, 曲春艳, 王德志, 等. 乙烯基橡胶增韧双马来酰亚胺树脂的研究[J]. 化学与黏合, 2014, 36(1):20-23. YANG Haidong, QU Chunyan, WANG Dezhi, et al. Study on toughening bismaleimide resin by vinyl rubber[J]. Chemistry and Adhesion,2014,36(1):20-23(in Chinese).
[6]	LIAO Y T, LIN C R, LIU W L. High-performance thermoplastic toughened BMI matrix system. II. Interface study[J]. Journal of Applied Polymer Science,2010,40(11-12):2239-2242.
[7]	SUN Shujun, GUO Miaocai, YI Xiaosu. Phase separation morphology and mode II interlaminar fracture toughness of bismaleimide laminates toughened by thermoplastics with triphenylphosphine oxidegroup[J]. Science China-Technological Sciences,2017,60(3):444-451. doi: 10.1007/s11431-016-0719-4
[8]	LIU X, YU Y, LI S. Viscoelastic phase separation in polyethersulfone modified bismaleimide resin[J]. European Polymer Journal,2006,42(4):835-842. doi: 10.1016/j.eurpolymj.2005.10.004
[9]	丁妍羽, 贾玉玺, 姚形龙, 等. 聚醚砜-环氧树脂共混体系相分离过程的数值模拟[J]. 复合材料学报, 2018, 35(1):81-88. DING Yanyu, JIA Yuxi, YAO Xinglong,et al. Numerical simulation of phase separation processes of polyethersulfone-epoxy resin blend systems[J]. Acta Materiae Compositae Sinica,2018,35(1):81-88(in Chinese).
[10]	GU J W, LIANG C B, DANG J, et al. Ideal dielectric thermally conductive bismaleimide nanocomposites filled with polyhedral oligomeric silsesquioxane functionalized nanosized boron nitride[J]. RSC Advances,2018,6(42):35809-35814.
[11]	CHENG Q F, BAO J W, PARK J, et al. High mechanical performance composite conductor: Multi-walled carbon nanotube sheet/bismaleimide nanocomposites[J]. Advanced Functional Materials,2009,19(20):3219-3225. doi: 10.1002/adfm.200900663
[12]	肖杰, 顾轶卓, 李敏, 等. 多壁碳纳米管改性环氧树脂胶黏剂实验研究[J]. 复合材料学报, 2011, 28(3):20-26. XIAO Jie, GU Yizhuo, LI Min, et al. Experiment study on epoxy resin adhesive modified by multi-walled carbon nanotubes[J]. Acta Materiae Compositae Sinica,2011,28(3):20-26(in Chinese).
[13]	益小苏, 安学锋, 唐邦铭, 等. 一种提高层状复合材料韧性的方法: 中国, ZL01 100981.0[P]. 2001-03-26. YI Xiaosu, AN Xuefeng, TANG bangming, et al. A method to improve the toughness of laminated composites: China, No. ZL01 100981.0[P]. 2001-03-26(in Chinese).
[14]	益小苏, 安学锋, 唐邦铭, 等. 一种增韧的复合材料层合板及其制备方法: 中国, FP1060809P[P]. 2010-08-04. YI Xiaosu, AN Xuefeng, TANG bangming, et al. A toughened composite laminate and its preparation method: China, FP1060809P[P]. 2010-08-04(in Chinese).
[15]	益小苏, 许亚洪, 程群峰, 等. 层间韧化的碳纤维复合材料层压板的力学性能[J]. 材料研究学报, 2008, 22(4):337-346. doi: 10.3321/j.issn:1005-3093.2008.04.001 YI Xiaosu, XU Yahong, CHENG Qunfeng, et al. Mechanical properties of interlaminar toughened carbon fiber compo-site laminates[J]. Chinese Journal of Materials Research,2008,22(4):337-346(in Chinese). doi: 10.3321/j.issn:1005-3093.2008.04.001
[16]	程群峰. 双马来酰亚胺树脂基复合材料的离位增韧研究[D]. 杭州: 浙江大学, 2007. CHENG Qunfeng. Studies on toughening composites based on BMI resin by Ex-Situ concept[D]. Hangzhou: Zhejiang University, 2007(in Chinese).
[17]	RATNA D, SIMON G P. Thermomechanical properties and morphology of blends of a hydroxy-functionalized hyperbranched polymer and epoxy resin[J]. Polymer,2001,42(21):8833-8839. doi: 10.1016/S0032-3861(01)00341-X
[18]	QIN H H, MATHER P T, BAEK J B, et al. Modification of bisphenol-A based bismaleimide resin (BPABMI) with an allyl-terminated hyperbranched polyimide (AT-PAEKI)[J]. Polymer,2006,47(8):2813-2821. doi: 10.1016/j.polymer.2006.02.062
[19]	CHENG Qunfeng, FANG Zhengping, XU Yahong, et al. Morphological and spatial effects on toughness and impact damage resistance of PAEK-toughened BMI and graphite fiber composite laminates[J]. Chinese Journal of Aeronautics,2009,22:87-96. doi: 10.1016/S1000-9361(08)60073-4
[20]	INOUE T. Reaction-induced phase-decomposition in polymer blends[J]. Progress in Polymer Science,1995,20:119-153. doi: 10.1016/0079-6700(94)00032-W
[21]	CHAMBON F , PETROVIC Z S , MACKNIGHT W J, et al. Rheology of model polyurethanes at the gel point[J]. Macromolecules,1986,19(8):2146-2149. doi: 10.1122/1.549853
[22]	HU X, FAN J. Rheological study of crosslinking and gelation in bismaleimide/cyanate ester interpenetrating polymer network[J]. Journal of Applied Polymer Science,2001,80(13):2437-2445. doi: 10.1002/app.1350
[23]	张明. 航空RTM树脂的固化行为与相结构-性能关系研究[D]. 北京: 北京航空材料研究所, 2010. ZHANG Ming. Study on the relationship between curing behavior and phase structure property of aviation RTM Resin[D]. Beijing: Institute of Aeronautical Materia, 2010(in Chinese).
[24]	MENG J R, HU X, FREDDY Y C, et al. Effect of layered nano-organosilicate on the gel point rheology of bismaleimide/diallylbisphenol A resin[J]. Polymer,2005,46(8):2766-2776. doi: 10.1016/j.polymer.2004.11.087