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改性环氧树脂防腐复合涂层的研究进展

童庆玲 杨建军 吴庆云 吴明元 张建安 刘久逸

童庆玲, 杨建军, 吴庆云, 等. 改性环氧树脂防腐复合涂层的研究进展[J]. 复合材料学报, 2024, 42(0): 1-13.
引用本文: 童庆玲, 杨建军, 吴庆云, 等. 改性环氧树脂防腐复合涂层的研究进展[J]. 复合材料学报, 2024, 42(0): 1-13.
TONG Qingling, YANG Jianjun, WU Qingyun, et al. Research progress of modified epoxy resin anticorrosive composite coatings[J]. Acta Materiae Compositae Sinica.
Citation: TONG Qingling, YANG Jianjun, WU Qingyun, et al. Research progress of modified epoxy resin anticorrosive composite coatings[J]. Acta Materiae Compositae Sinica.

改性环氧树脂防腐复合涂层的研究进展

基金项目: 国家自然科学基金(51973001);安徽省科技计划重点项目(1704a0902018)
详细信息
    通讯作者:

    杨建军,研究生,教授,博士生导师,研究方向为水基高分子纳米杂化材料的合成及应用 E-mail: andayjj@163

  • 中图分类号: TG174.4;TB332

Research progress of modified epoxy resin anticorrosive composite coatings

Funds: National Natural Science Foundation of China (No.51973001); Anhui Province Science and Technology Program key Project (No.1704a0902018)
  • 摘要: 在防腐领域,环氧树脂防腐复合涂层是防止金属腐蚀的优良材料。环氧树脂涂层在金属和腐蚀性离子之间形成了屏障,但环氧树脂在固化期间,由于机械破裂和微孔的形成,防腐效果并不持久。本文介绍了纳米粒子改性环氧树脂防腐涂层、微/纳米容器改性环氧树脂防腐涂层、生物基材料改性环氧树脂防腐涂层这3种提高环氧树脂防腐性能的策略,综述了环氧树脂防腐复合涂层改性的研究进展,并展望了环氧树脂防腐复合涂层未来的发展方向,未来应该开发出兼具智能自预警与自修复、多功能化、成本效益的绿色环氧防腐复合涂层。

     

  • 图  1  划痕涂层暴露在盐雾中30天的变化情况[17]

    Figure  1.  Visual situation of scratched coatings exposed to salt spray for 30 days (A colour version of this figure can be viewed online)[17]

    图  2  (a) 二元和三元纳米复合材料水接触角结果[25];(b) MoS2的结构图[26]

    Figure  2.  (a) WCA results of synthesized binary and ternary nanocomposites[25]; (b) the structure of MoS2[26]

    图  3  通过传统方法和表面活性剂辅助方法制备Cu-TCPP MOFs的示意图[32]

    Figure  3.  Schematic representation of the preparation for Cu-TCPP MOFs via traditional and surfactant-assisted mehotds[32]

    图  4  ZIF-8与环氧树脂基体反应机制示意图[34]

    Figure  4.  Schematic mechanisms of the reaction between ZIF-8 and epoxy matrices[34]

    图  5  Ti3 C2 MXene@PANI复合材料合成示意图[36]

    Figure  5.  Schematic illustration of synthesis of Ti3 C2 MXene@PANI composites[36]

    图  6  在3.5 wt% NaCl (pH = 6.8)溶液中浸泡35 d后,碳钢基体上不含(a-e)和含3% AMT@MSN-PAA (f-j)人工划痕环氧涂层的光学图像[47]

    Figure  6.  Optical images of the artificial scratch epoxy coatings without (a–e) and with 3% AMT@MSN-PAA (f–j) on carbon steel substrate after immersed in 3.5 wt% NaCl solution with pH = 6.8 for 35 d[47]

    图  7  涂层划伤2 h (a1, b1, c1)和24 h (a2, b2, c2)用SKP测量的电位分布图(a-Ep/ TpPa-1 wt%,b- Ep/MSNs-1 wt%,c- Ep/MSNs-CS/TpPa-1 wt%,复合涂层a,b未负载BTA,复合涂层c负载BTA)[48]

    Figure  7.  Potential profiles measured by SKP at 2 h (a1, b1, c1) and 24 h (a2, b2, c2) after scratching (a-Ep/ TpPa-1 wt%,b- Ep/MSNs-1 wt%,c- Ep/MSNs-CS/TpPa-1 wt%,composite coating a, b is not loaded with BTA, and composite coating c is loaded with BTA)[48]

    图  8  (a) HNT-CS@BTA纳米容器和(b)复合涂层的制备示意图[53]

    Figure  8.  The schematic diagram of the preparation of (a) HNT-CS@BTA nanocontainers and (b) composite coatings[53]

    图  9  示意图表示:(a) HHNTs的合成和(b,c) HNT的负载和连续层间的静电吸引[54]

    Figure  9.  Schematic representation: (a) synthesis of HHNTs and (b,c) loading of HNTs and the electrostatic attraction between the consecutive layers of HHNTs[54]

    图  10  MSNs-BTA@ZIF-LDHs纳米容器的合成路线[55]

    Figure  10.  The synthesis route of MSNs-BTA@ZIF-LDHs nanocontainers[55]

    图  11  样品在3.5 wt.% NaCl溶液中浸泡不同时间(a) 0 d, (b) 3 d, (c) 7 d, (d) 10 d, (e) 14 d, (f) 21 d的荧光显微图[61]

    Figure  11.  Fluorescence micrographs of the samples after immersion in 3.5 wt.% NaCl solution for different times: (a) 0 d, (b) 3 d, (c) 7 d, (d) 10 d, (e) 14 d and (f) 21 d[61]

    图  12  WE-PB复合涂层的制备示意图[65]

    Figure  12.  The schematic of preparation of WE-PB composite coating[65]

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  • 收稿日期:  2023-11-08
  • 修回日期:  2024-01-30
  • 录用日期:  2024-02-08
  • 网络出版日期:  2024-03-18

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