基于反蛋白石结构的功能性薄膜制备及应用研究进展

何文玉; 马万彬; 向娇娇; 张耘箫; 柴丽琴; 周岚; 刘国金

doi:10.13801/j.cnki.fhclxb.20220120.002

基于反蛋白石结构的功能性薄膜制备及应用研究进展

doi: 10.13801/j.cnki.fhclxb.20220120.002

何文玉^1,,
马万彬^1,,
向娇娇¹,
张耘箫¹,
柴丽琴²,
周岚²,
刘国金^{1, 2, ,}

1.
浙江理工大学　浙江省纤维材料和加工技术研究重点实验室，杭州 310018
2.
浙江理工大学　先进纺织材料与制备技术教育部重点实验室，杭州 310018

基金项目: 国家自然科学基金(52003242)；浙江省自然科学基金(LQ19E030022；LY20E030006)；国家重点研发计划“高端功能与智能材料”重点专项(2021YFB3801500)；2020年国家级大学生创新创业训练计划项目

详细信息

通讯作者:
刘国金，博士，副教授，研究方向是亲水性过滤膜的开发与应用　E-mail：guojin900618@163.com

中图分类号: TB34
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- 被引次数: 0
出版历程
- 收稿日期: 2021-11-26
- 修回日期: 2021-12-23
- 录用日期: 2022-01-11
- 网络出版日期: 2022-01-20
- 刊出日期: 2022-06-01

Research progress in preparation and application of functional films based on inverse opal structure

1.
Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou 310018, China
2.
Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China

摘要

摘要: 作为光子晶体的一种典型结构，基于反蛋白石(IO)结构构筑的功能性薄膜呈现典型的周期性排列，除具有微孔大小均一、孔隙率高、孔径易灵活调控等优势外，还具有一些特殊的光学性质。近年来，IO结构膜引起了检测、防伪、药物输送、过滤等领域的广泛关注。本文首先概述了IO型膜的结构特点和光学特性，然后重点介绍了IO结构膜的制备方法并将其概括为“三步法”和“两步法”，接着详细总结了IO型膜在结构生色、传感器、电致变色、光催化和医学载体五方面的应用进展，最后对其未来的研究方向和发展趋势作出了展望。本研究可为IO型功能性薄膜的推广和应用提供策略支撑。
- 功能性薄膜 /
- 光子晶体 /
- 反蛋白石 /
- 制备方法 /
- 应用进展
Abstract: As a representative structure of photonic crystals, films constructed with inverse opal (IO) structure exhibit a typical periodic arrangement. These films have some special optical properties in addition to the advantages of uniform micropores, high porosity and great flexibility of pore sizes. In recent years, films possessing an IO structure have attracted widespread attention from fields such as detection, anti-counterfeiting, drug delivery and filtration. In this article, the structural characteristics and optical properties of IO films were described, then the preparation methods of IO films were introduced and summarized into the three-step method and the two-step method. The applications of IO films in aspects of structural coloration, photocatalysis and medical carrier were depicted in details, and finally the prospects of films with IO structure in research direction and development trend in the future were given. The research work described in this article can provide strategic supports for the promotion and application of IO functional films.
- functional films /
- photonic crystals /
- inverse opal (IO) /
- preparation methods /
- application progress

HTML全文

图 1 相转化法制备所得的聚偏氟乙烯(PVDF)膜 (a)和反蛋白石结构PVDF膜 (b)

Figure 1. PVDF film by phase-inversion method (a) and inverse opal PVDF film (b)

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图 2 蛋白石与反蛋白石构型 (a)^[43]、三步法制备反蛋白石结构膜 (b)^[44]和两步法制备反蛋白石结构膜 (c)

Figure 2. Opal and inverse opal structures (a)^[43], preparation of inverse opal films by the three-step method (b)^[44], preparation of inverse opal films by the two-step method (c)

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图 3 重力沉积法组装蛋白石结构模板^[45]

Figure 3. Assembly of opal templates by gravitational deposition method^[45]

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图 4 垂直沉积法组装蛋白石结构模板^[45]

Figure 4. Assembly of opal templates by vertical deposition method^[45]

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图 5 旋涂法制备蛋白石结构模板^[46]

Figure 5. Preparation of opal templates by spin-coating^[46]

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图 6 旋涂-提拉法制备聚苯乙烯(PS)单层胶体晶体(MCC)模板^[47]

Figure 6. Preparation of polystyrene (PS) MCC template by combining a spin-coating and lifting-up method^[47]

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图 7 优化旋涂参数后制得的单层晶体模板^[46]

Figure 7. Monolayer crystal template by optimizing the parameters of spin-coating^[46]

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图 8 喷涂法制备SnO₂微球层示意图^[43]

Figure 8. Schematic diagram of the preparation of SnO₂ microspheres by spray-coating^[43]

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图 9 喷涂不同质量分数聚(苯乙烯-甲基丙烯酸)(P(St-MAA))预组装液所得的蛋白石光子晶体^[49]

Figure 9. Opal photonic crystal by spray-coating different mass fractions poly(styrene-methacrylate)(P(ST-MAA)) pre-assembly solution^[49]

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图 10 溶剂蒸发法制备丝素蛋白反蛋白石结构膜^[38]

Figure 10. Silk inverse opal structure films by solvent evaporation methods^[38]

PMMA—Polymethyl methacrylate

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图 11 不同热处理温度下的聚偏氟乙烯(PVDF)反蛋白石结构膜^[50]

Figure 11. Polyvinylidene fluoride (PVDF) inverse opal films under different temperature conditions^[50]

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图 12 碳纳米球蛋白石 (a)、以碳纳米球为模板制得的TiO₂反蛋白石结构膜 (b)、PS微球蛋白石 (c) 和以PS微球为模板制得的TiO₂反蛋白石结构膜 (d) 的SEM图像^[53]

Figure 12. SEM images of the samples carbon sphere opal (a), TiO₂ inverse opal films from carbon sphere (b), PS sphere opal (c) and TiO₂ inverse opal films from PS (d)^[53]

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图 13 新型填充法制备反蛋白结构膜聚乳酸-羟基乙酸共聚物(PLGA)反蛋白石结构膜 (a)^[61]；SU-8反蛋白石结构膜 (b)^[62]

Figure 13. A novel method for preparation of inverse opal films polylactic acid-glycolic acid copolymer (PLGA) inverse opal films (a)^[61]; SU-8 inverse opal films (b)^[62]

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图 14 蒸法诱导共组装法制备混合金属氧化物反蛋白石结构膜^[64]

Figure 14. Schematic illustration of the fabrication process for mixed metal oxide inverse opals films by evaporation indued assembly method^[64]

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图 15 不同TiO₂/SiO₂前驱体混合比例下的杂化反蛋白石结构膜的SEM图像^[64]

Figure 15. SEM images of mixed metal oxide inverse opals films with different molar ratios of titania to silica precursors^[64]

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图 16 三步法制备彩色PVDF反蛋白石结构膜^[67]

Figure 16. Schematic illustration of the routine to prepare the colored PVDF inverse opal films by three-step method^[67]

3DPC—3D photonic crystal; HMPA—Hexamethylphosphoramide; CB—Carbon black

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图 17 观测角度为5° (a) 和10° (b) 下贴有彩色PVDF膜的纸币照片^[67]

Figure 17. Photos of banknotes with colored PVDF film at observation angles were 5° (a) and 10° (b)^[67]

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图 18 观测角度分别为10°和40°下蓝、绿、红色反蛋白石结构膜的照片^[68]

Figure 18. Optical photographs of blue, green and red inverse opal films with the shooting angle of 10° and 40°^[68]

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图 19 有机-无机复合响应型水凝胶(SRPH)薄膜在不同有机溶剂下的光学照片^[69]

Figure 19. Optical photographs of organic-inorganic composite responsive hydrogel (SRPH) film discoloration in response to different organic solvents^[69]

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图 20 三步法制备ZnO/苯胺黑(AB)-PVDF复合反蛋白石结构膜 (a)；SiO₂光子晶体模板 (b)、填充AB-PVDF后的SiO₂光子晶体模板 (c)、0.5%AB-PVDF反蛋白石结构膜 (d) 和ZnO/0.5%AB-PVDF反蛋白石结构膜 (e) 的SEM图像^[76]

Figure 20. Preparation process illustration of the ZnO/aniline black (AB)-PVDF inverse opal film by three-step method (a); SEM images of the silica photonic crystal template(b), silica photonic crystal template after AB-PVDF infiltration(c), 0.5%AB-PVDF inverse opal film(d)and ZnO/0.5%AB-PVDF inverse opal film (e)^[76]

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图 21 TiO₂反蛋白石结构膜 (a) 和Ag/TiO₂反蛋白石结构膜 (b) 的SEM图像^[37]

Figure 21. SEM images of TiO₂ inverse opal film (a) and Ag/TiO₂ inverse opal film (b)^[37]

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图 22 PVDF平板膜 (a)、拉伸倍数分别为0 (b)、3 (c) 和6 (d) 倍的PVDF反蛋白石结构膜的SEM图像^[44]

Figure 22. SEM images of PVDF inverted opal membrane with PVDF flat membrane (a) and stretching ratio of 0 (b), 3 (c) and 6 (d), respectively^[44]

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图 23 神经干细胞在PVDF平板膜 (a)、拉伸倍率分别为0 (b)、3 (c)、6 (d) 倍的PVDF反蛋白石结构膜上的分化情况^[44]

Figure 23. Differentiation of neural stem cells on PVDF flat membrane (a), PVDF reverse opal membrane with 0 (b), 3 (c) and 6 (d) tensile ratios, respectively^[44]

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图 24 220 nm (a)、250 nm (b) 和300 nm (c)粒径模板所得PLGA反蛋白石结构膜在释放药物前后的反射率曲线^[79]

Figure 24. Reflectance curves of PLGA reverse opal structures obtained from 220 nm (a), 250 nm (b) and 300 nm (c) particle size templates before and after drug release^[79]

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