Diels-Alder型热修复木质素/三元乙丙橡胶的制备及性能

Preparation and properties of Diels-Alder reactive thermal-heating lignin/EPDM rubber

  • 摘要: 为改善橡胶材料废弃后的环境污染问题,以糠醛改性木质素(F-Lig)为填料,采用固相共混法制备了Diels-Alder型热修复三元乙丙橡胶(CEF-Lig)。通过可逆交联网络的断裂和重建赋予了CEF-Lig复合材料高温熔融加工、低温交联成型的特性,并探究了F-Lig含量对CEF-Lig材料的微观结构、力学性能和热修复性能的影响。结果表明:成功制备出具有热修复可回收特性的CEF-Lig复合材料;随F-Lig含量增加,拉伸强度呈现先增加后下降的趋势,CEF-Lig7的拉伸强度达到最大值4.6 MPa,为不含F-Lig对照组(CEPDM)的4.6倍;F-Lig的加入提高了CEF-Lig材料的热分解温度,CEF-Lig9最大分解速率对应的温度(Tmax)相比CEPDM提升8.8 ℃;CEF-Lig材料具有良好的热修复能力,力学强度的一次修复效率均在70%以上,二次修复效率均在60%以上。此外,采用固相共混法工艺,有效避免了溶剂污染,提高了生产效率,为其他可逆交联聚合物的制备提供参考。

     

    Abstract: In order to improve the environmental pollution of rubber materials after disposal, Diels-Alder reactive thermal-heating EPDM rubber (CEF-Lig) was prepared using furfural-modified lignin (F-Lig) as a filler in the solid phase blending method. The high-temperature melt processing and low-temperature cross-linking molding of CEF-Lig composites were endowed by the fracture and reconstruction of reversible cross-linking networks, and the effects of F-Lig content on the microstructure, mechanical properties, and thermal repair properties of CEF-Lig materials were explored. The results demonstrate that the CEF-Lig composites with thermally repairable recyclable properties are successfully prepared. With the increase of F-Lig content, the tensile strength shows the trend of increasing and then decreasing, and the tensile strength of CEF-Lig7 reaches the maximum value of 4.6 MPa, which is 4.6 times of that of the control group (CEPDM) without F-Lig. The F-Lig increases the thermal decomposition temperature of the CEF-Lig, and the temperature corresponding to the maximum decomposition rate (Tmax) of CEF-Lig9 was increased by 8.8 ℃ compared to CEPDM. The CEF-Lig has a good thermal repair ability, the mechanical strength of the primary repair efficiency are more than 70%, and the secondary repair efficiency are more than 60%. In addition, the solid phase blending method is adopted to effectively avoid solvent contamination and improve the production efficiency, which provides a reference for the preparation of other reversible cross-linked polymers.

     

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