高强MXene/PPy@BC复合薄膜的制备及其电磁屏蔽性能

唐婕; 李翔

高强MXene/PPy@BC复合薄膜的制备及其电磁屏蔽性能

唐婕,
李翔^,

上海理工大学　材料与化学学院, 上海杨浦 200093

基金项目: 国家自然科学基金(52072245)

详细信息

通讯作者:
李翔，教授，博士，磁性功能材料方向；　E-mail: xiangli@usst.edu.cn

计量
- 文章访问数: 172
- HTML全文浏览量: 120
- 被引次数: 0
出版历程
- 收稿日期: 2024-01-25
- 修回日期: 2024-02-25
- 录用日期: 2024-03-07
- 网络出版日期: 2024-04-13

Preparation of high-strength MXene/PPy@BC composite films and their electromagnetic shielding properties

TANG Jie,
LI Xiang^,

University of Shanghai for Science and Technology, School of Materials and Chemistry, Yangpu, Shanghai, 200093

Funds: National Natural Science Foundation of China (No.52072245)

摘要

摘要: 随着通信技术和移动电子设备的不断发展，电磁干扰问题日益突显，因此研发高性能的电磁屏蔽材料成为当前重要的研究方向。本文采用简单的真空过滤方法，成功制备了高导电性能的MXene/聚吡咯(PPy)@细菌纤维素(BC)薄膜(MPB)，深入研究了MXene和PPy@BC不同比例对复合薄膜导电性能、力学性能和电磁屏蔽性能的影响规律。研究表明:当MXene和PPy@BC比例为3∶1时，电导率和X波段电磁屏蔽效能(EMI SE)均达到最大值，分别1209 S/cm和63.89 dB；此外，由于PPy@BC和MXene之间存在丰富的氢键相互作用，使得复合薄膜的最大抗拉强度可达到24.73 MPa，较纯MXene薄膜提升了近10倍。MPB薄膜优异的综合性能展示了其在下一代智能和可穿戴电子产品的EMI屏蔽方面的巨大潜力。
- MXene /
- 聚吡咯 /
- 细菌纤维素 /
- 电磁屏蔽 /
- 力学性能 /
- 复合薄膜
Abstract: With the continuous development of communication technology and mobile electronic devices, electromagnetic interference problem is increasingly prominent, so the development of high performance electromagnetic shielding materials has become an important research direction. In this paper, a high conductivity MXene/polypyrrole (PPy)@bacterial cellulose (BC) film (MPB) with high conductivity was successfully prepared by a simple vacuum filtration method. The influence of different proportions of MXene and PPy@BC on the conductivity, mechanical properties and electromagnetic shielding performance of the composite film was deeply studied. The results show that when the ratio of MXene and PPy@BC is 3∶1, the conductivity and X-band electromagnetic shielding efficiency (EMI SE) reach the maximum, 1209 S/cm and 63.89 dB, respectively. In addition, due to the rich hydrogen bond interaction between PPy@BC and MXene, the maximum tensile strength of the composite film can reach 24.73 MPa, which is nearly 10 times higher than that of pure MXene film. The excellent comprehensive performance of MPB film shows its great potential in the EMI shielding of the next generation of intelligent and wearable electronic products.
- MXene /
- polypyrrole /
- bacterial cellulose /
- electromagnetic shielding /
- mechanical property /
- composite film

HTML全文

图 1 MXene/聚吡咯(PPy)@细菌纤维素(BC) (MPB)薄膜的制备流程图

Figure 1. Flow chart for the preparation of MXene/polypyrrole (PPy)@bacterial cellulose (BC) (MPB) films

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图 2 (a)纯BC的TEM照片;(b)纯BC的SEM照片;(c)PPy@BC的TEM照片;(d)Ti₃C₂T_x多层的SEM照片;(e)MPB的TEM照片;(f)MPB的SEM照片

Figure 2. (a) TEM image of pure BC; (b) SEM image of pure BC; (c) TEM image of PPy@BC; (d) SEM image of Ti₃C₂T_x multilayer; (e) TEM image of MPB; (f) SEM image of MPB

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图 3 MPB薄膜的EDS能谱图

Figure 3. EDS mapping images of MPB film

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图 4 MXene，PPy@BC和MPB的XRD图

Figure 4. XRD patterns of MXene, PPy@BC and MPB

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图 5 (a)纯MXene和MPB薄膜的XPS全谱图;(b)PPy@BC的N 1 s高分辨XPS谱图

Figure 5. (a) XPS full spectra of pure MXene and MPB films; (b) N 1 s high-resolution XPS spectra of PPy@BC

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图 6 (a) MPB薄膜的拉伸应力-应变曲线; (b) MPB薄膜的抗拉强度

Figure 6. (a) Tensile stress-strain curve of MPB film; (b) Tensile strength of MPB film

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图 7 MPB薄膜的电阻率变化

Figure 7. Resistivity variation of MPB film

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图 8 MPB 薄膜集成电路点亮 LED 灯的数码照片

Figure 8. Digital photo of MPB film IC lighting up an LED lamp

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图 9 不同 MXene和PPy@BC比例的MPB复合薄膜电磁屏蔽效能(EMI SE)(a)，反射损耗(SE_R)，吸收损耗(SE_A)和总电磁屏蔽效能(SE_T)(b)，R-A-T系数(c)

Figure 9. Electromagnetic shielding effectiveness (EMI SE) (a), reflection loss (SE_R), absorption loss (SE_A) and total electromagnetic shielding effectiveness (SE_T) (b), and R-A-T coefficients (c) of MPB composite films with different MXene and PPy@BC ratios

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图 10 其他EMI屏蔽膜的电磁屏蔽性能比较

Figure 10. Comparison of electromagnetic shielding performance of other EMI shielding films

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图 11 MPB薄膜的电磁屏蔽机制图

Figure 11. Electromagnetic shielding mechanism diagrams of MPB films

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[1]	张淑琴, 张彭. 电磁辐射的危害与防护[J]. 工业安全与环保, 2008, 34(3): 30-32. doi: 10.3969/j.issn.1001-425X.2008.03.014 ZHANG Shuqin, ZHANG Peng. Hazards and protection of electromagnetic radiation[J]. Industrial Safety and Environmental Protection, 2008, 34(3): 30-32(in Chinese). doi: 10.3969/j.issn.1001-425X.2008.03.014
[2]	SHAHZAD F, ALHABEB M, HATTER C B, et al. Electromagnetic interference shielding with 2D transition metal carbides (MXenes)[J]. Science, 2016, 353(6304): 1137-1140. doi: 10.1126/science.aag2421
[3]	王静, 罗蕙敏, 刘元军, 等. 电磁吸收与屏蔽材料[J]. 染整技术, 2020, 42(2): 9. WANG Jing, LUO Huimin, LIU Yuanjun, et al. Electromagnetic absorption and shielding materials[J]. Dyeing and Finishing Technology, 2020, 42(2): 9(in Chinese).
[4]	文峰, 符佳伟, 王新远, 等. 多壁碳纳米管导电纸/碳纤维复合材料的制各及电磁屏蔽性能研究[J]. 化工新型材料, 2020, 48(9): 68-71. WEN Feng, FU Jiawei, WANG Xinyuan, et al. Research on the fabrication of multi-walled carbon nanotube conductive paper/carbon fiber composites and electromagnetic shielding performance[J]. New Chemical Materials, 2020, 48(9): 68-71(in Chinese).
[5]	YAO Y, JIN S, WANG M, et al. MXene hybrid polyvinyl alcohol flexible composite films for electromagnetic interference shielding[J]. Applied Surface Science:A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials, 2022, (Mar.15): 578.
[6]	ZHANG Y Z, WANG Y, JIANG Q, et al. MXene printing and patterned coating for device applications[J]. Advanced materials, 2020, 32(21): 1908486. doi: 10.1002/adma.201908486
[7]	PANG J, MENDES R G, BACHMATIUK A, et al. Applications of 2D MXenes in energy conversion and storage systems[J]. Chemical Society Reviews, 2019, 48(1): 72-133. doi: 10.1039/C8CS00324F
[8]	FU Z, WANG N, LEGUT D, et al. Rational design of flexible two-dimensional MXenes with multiple functionalities[J]. Chemical reviews, 2019, 119(23): 11980-12031. doi: 10.1021/acs.chemrev.9b00348
[9]	NAGUIB M, KURTOGLU M, PRESSER V, et al. Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂[J]. Advanced materials, 2011, 23(37): 4248-4253. doi: 10.1002/adma.201102306
[10]	LIU F, Li Y, HAO S, et al. Well-aligned MXene/chitosan films with humidity response for high-performance electromagnetic interference shielding[J]. Carbohydrate polymers, 2020, 243: 116467. doi: 10.1016/j.carbpol.2020.116467
[11]	MA Z, KANG S, MA J, et al. Ultraflexible and mechanically strong double-layered aramid nanofiber–Ti₃C₂T_x MXene/silver nanowire nanocomposite papers for high-performance electromagnetic interference shielding[J]. Acs Nano, 2020, 14(7): 8368-8382. doi: 10.1021/acsnano.0c02401
[12]	CHENG W, FU J, HU H, et al. Interlayer structure engineering of MXene-based capacitor-type electrode for hybrid micro-supercapacitor toward battery-level energy density[J]. Advanced Science, 2021, 8(16): 2100775. doi: 10.1002/advs.202100775
[13]	JIAO S, ZHOU A, WU M, et al. Kirigami patterning of MXene/bacterial cellulose composite paper for all-solid-state stretchable micro-supercapacitor arrays[J]. Advanced Science, 2019, 6(12): 1900529. doi: 10.1002/advs.201900529
[14]	XU X, CHEN Y, HE P, et al. Wearable CNT/Ti₃C₂T_x MXene/PDMS composite strain sensor with enhanced stability for real-time human healthcare monitoring[J]. Nano Research, 2021, 14(8): 2875-2883. doi: 10.1007/s12274-021-3536-3
[15]	LI X P, LI Y, LI X, et al. Highly sensitive, reliable and flexible piezoresistive pressure sensors featuring polyurethane sponge coated with MXene sheets[J]. Journal of colloid and interface science, 2019, 542: 54-62. doi: 10.1016/j.jcis.2019.01.123
[16]	ZHAO Y, DENG C, YAN B, et al. One-Step Method for Fabricating Janus Aramid Nanofiber/MXene Nanocomposite Films with Improved Joule Heating and Thermal Camouflage Properties[J]. ACS Applied Materials & Interfaces, 2023, 15(47): 55150-55162.
[17]	LIU R, MIAO M, LI Y, et al. Ultrathin biomimetic polymeric Ti₃C₂T_x MXene composite films for electromagnetic interference shielding[J]. ACS applied materials & interfaces, 2018, 10(51): 44787-44795.
[18]	施鸥玲, 谭妍妍, 武晓等. 具有高导电性的PVDF/MWCNTs-AgNWs@MXene双层三维网络的电磁屏蔽复合薄膜[J/OL]. 复合材料学报, 2024, 1-14. SHI Ouling, TAN Yanyan, WU Xiao, et al. Electromagnetic shielding composite films with highly conductive PVDF/MWCNTs-AgNWs@MXene bilayer three-dimensional network[J/OL]. Journal of Composite Materials, 2024, 1-14. (in Chinese)
[19]	HUO Y, GUO D, YANG J, et al. Multifunctional bacterial cellulose nanofibers/polypyrrole (PPy) composite films for joule heating and electromagnetic interference shielding[J]. ACS Applied Electronic Materials, 2022, 4(5): 2552-2560. doi: 10.1021/acsaelm.2c00316
[20]	SHI Y, XIANG Z, CAI L, et al. Multi-interface Assembled N-Doped MXene/HCFG/AgNW Films for Wearable Electromagnetic Shielding Devices with Multimodal Energy Conversion and Healthcare Monitoring Performances[J]. 2022, 16(5): 7816–7833.
[21]	张艳, 马忠雷, 李桢等. 轻质高强MXene/细菌纤维素复合气凝胶的制备及其电磁屏蔽性能[J]. 复合材料学报, 2023, 40(11): 6407-6415. ZHANG Yan, MA Zhonglei, LI Zhen et al. Preparation of lightweight and high-strength MXene/bacterial cellulose composite aerogels and their electromagnetic shielding properties[J]. Journal of Composite Materials, 2023, 40(11): 6407-6415(in Chinese).
[22]	SONG Q, ZHAN Z, CHEN B, et al. Biotemplate synthesis of polypyrrole@ bacterial cellulose/MXene nanocomposites with synergistically enhanced electrochemical performance[J]. Cellulose, 2020, 27: 7475-7488. doi: 10.1007/s10570-020-03310-7
[23]	WU H, ZHU C, LI X, et al. Layer-by-Layer Assembly of Multifunctional NR/MXene/CNTs Composite Films with Exceptional Electromagnetic Interference Shielding Performances and Excellent Mechanical Properties[J]. Macromolecular Rapid Communications, 2022, 43(18): 2200387. doi: 10.1002/marc.202200387
[24]	WANG J, ZHU X, XIONG P, et al. Flexible, robust and washable bacterial cellulose/silver nanowire conductive paper for high-performance electromagnetic interference shielding[J]. Journal of Materials Chemistry A, 2022, 10(2): 960-968. doi: 10.1039/D1TA07900J
[25]	ROSTAMI M, MAGHAMI S, VATANPOUR V, et al. The nanocomposites of N-doped graphene oxide decorated with La-doped Zn-Cu-Ni ferrite with lightweight and excellent absorption-dominant electromagnetic interference shielding performance[J]. Journal of Materials Science:Materials in Electronics, 2023, 34(10): 882. doi: 10.1007/s10854-023-10293-1
[26]	SONG W L, GUAN X T, FAN L Z, et al. Magnetic and conductive graphene papers toward thin layers of effective electromagnetic shielding[J]. Journal of Materials Chemistry A, 2015, 3(5): 2097-2107. doi: 10.1039/C4TA05939E
[27]	LIU F, LI Y, HAO S, et al. Well-aligned MXene/chitosan films with humidity response for high-performance electromagnetic interference shielding[J]. Carbohydrate Polymers:Scientific and Technological Aspects of Industrially Important Polysaccharides, 2020, 243: 116467.
[28]	XIN W, XI GQ, CAO WT, et al. Lightweight and flexible MXene/CNF/silver composite membranes with a brick-like structure and high-performance electromagnetic-interference shielding[J]. RSC Adv, 2019, 9(51): 29636-29644. doi: 10.1039/C9RA06399D
[29]	WU F, TIAN Z, HU P, et al. Lightweight and flexible PAN@ PPy/MXene films with outstanding electromagnetic interference shielding and Joule heating performance[J]. Nanoscale, 2022, 14(48): 18133-18142. doi: 10.1039/D2NR05318G
[30]	LI S, LI S, XU S, et al. Ultra-thin broadband terahertz absorption and electromagnetic shielding properties of MXene/rGO composite film[J]. Carbon, 2022, 194: 127-139. doi: 10.1016/j.carbon.2022.03.048
[31]	ZHANG Y, WANG L, ZHANG J, et al. Fabrication and investigation on the ultra-thin and flexible Ti₃C₂T_x/co-doped polyaniline electromagnetic interference shielding composite films[J]. Composites Science and Technology, 2019, 183: 107833. doi: 10.1016/j.compscitech.2019.107833
[32]	WANG S J, LI D S, JIANG L. Synergistic effects between MXenes and Ni chains in flexible and ultrathin electromagnetic interference shielding films[J]. Advanced Materials Interfaces, 2019, 6(19): 1900961. doi: 10.1002/admi.201900961
[33]	ZHANG K, GU X, DAI Q, et al. Flexible polyaniline-coated poplar fiber composite membranes with effective electromagnetic shielding performance[J]. Vacuum, 2019, 170: 108990. doi: 10.1016/j.vacuum.2019.108990
[34]	MA M, TAO W, LIAO X, et al. Cellulose nanofiber/MXene/FeCo composites with gradient structure for highly absorbed electromagnetic interference shielding[J]. Chemical Engineering Journal, 2023, 452: 139471. doi: 10.1016/j.cej.2022.139471
[35]	LIANG L, XU P, WANG Y, et al. Flexible polyvinylidene fluoride film with alternating oriented graphene/Ni nanochains for electromagnetic interference shielding and thermal management[J]. Chemical Engineering Journal, 2020, 395: 125209. doi: 10.1016/j.cej.2020.125209
[36]	IQBAL A, SAMBYAL P, KOO C M. 2D MXenes for electromagnetic shielding: a review[J]. Advanced Functional Materials, 2020, 30(47): 2000883. doi: 10.1002/adfm.202000883