Progress of metal halide perovskite nanocrystal in the field of fluorescence sensing
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摘要: 金属卤化物钙钛矿纳米晶因具独特的物理和化学特性，如高光吸收系数、窄发射光谱、高光致发光量子产率以及可调的组分与尺寸等，在发光二极管、太阳能电池、光电探测器、催化、激光、荧光传感等光电技术领域展现出广泛的应用潜力，已成为材料科学领域的研究热点。本文基于金属卤化物钙钛矿纳米晶在荧光传感领域的应用，重点归纳了金属卤化物钙钛矿纳米晶的制备技术、荧光传感机理及在该领域的应用研究进展；同时讨论了其在荧光传感领域应用中面临的稳定性问题及解决方案；最后，总结和展望了具有更高光学性能和稳定性的金属卤化物钙钛矿材料的发展方向。本文旨在通过对其在荧光传感领域应用的综述分析总结，为促进研究人员开发高效稳定的钙钛矿材料提供借鉴。Abstract: Due to the unique physical and chemical properties such as high light absorption coefficient, narrow emission spectrum, high photoluminescence quantum yield, and adjustable composition and size, metal halide perovskite nanocrystal have demonstrated extensive application potential in optoelectronic technologies including light-emitting diodes, solar cells, photodetectors, catalysis, lasers, and fluorescence sensing, and have become a research hotspot in the field of materials science. Based on their application in fluorescence sensing, this paper focuses on summarizing the preparation techniques of metal halide perovskites nanocrystal, the fluorescence sensing mechanism, and the research progress in this field. Meanwhile, it discusses the stability issues faced in the application of metal halide perovskites nanocrystal in fluorescence sensing and their corresponding solutions. Finally, the development direction of metal halide perovskite materials with higher optical performance and stability is summarized and prospected. This paper aims to provide a reference for researchers to develop efficient and stable perovskite materials through a comprehensive review and analysis of their applications in fluorescence sensing.
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Key words:
- metal halide perovskite /
- fluorescence sensing /
- optical properties /
- stability /
- defect passivation
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图 7 (a) 方法感应机制；(b) 不同过氧化物浓度的油样荧光光谱(从右到左依次为过氧化氢浓度为0、0.3、0.5 g/100 g和CsPbBr3钙钛矿)(插图显示在365 nm紫外光下的图像)[22]
Figure 7. (a) Sensing mechanism of method; (b) Fluorescence spectra of oil sample with different peroxide numbers (From right to left, the peroxide number is 0, 0.3, 0.5 g/100 g, and CsPbBr3 MHP) (The inset shows the apparent color under 365 nm UV light) [22]
图 12 (a)钙钛矿稳定性问题示意图和(b)钙钛矿表面缺陷钝化策略
Figure 12. (a) Schematic diagram of perovskite stability issues and (b) Passivation strategy for perovskite surface defects
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