纳米纤维素基功能性复合电极材料的研究进展

张冬妍; 杜珂珂; 吴晓峰; 张双保

doi:10.13801/j.cnki.fhclxb.20230228.001

纳米纤维素基功能性复合电极材料的研究进展

doi: 10.13801/j.cnki.fhclxb.20230228.001

张冬妍^{1, 2},
杜珂珂^{1, 2},
吴晓峰^{1, 2},
张双保^{1, 2, ,}

1.
北京林业大学　木质材料科学与应用教育部重点实验室，北京 100083
2.
北京林业大学　木材科学与工程北京市重点实验室，北京 100083

基金项目: 国家自然科学基金(32171707)；北京市自然科学基金(6202024)

详细信息

通讯作者:
张双保，博士，教授，博士生导师，研究方向为木质复合材料与胶黏剂　E-mail: shuangbaozhang@163.com

中图分类号: TK6；TB332
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出版历程
- 收稿日期: 2022-12-09
- 修回日期: 2023-02-10
- 录用日期: 2023-02-16
- 网络出版日期: 2023-03-01
- 刊出日期: 2023-08-15

Research progress of functional composite electrode materials based on nanocellulose

ZHANG Dongyan^{1, 2},
DU Keke^{1, 2},
WU Xiaofeng^{1, 2},
ZHANG Shuangbao^{1, 2
, ,}

1.
Key Laboratory of Wood Material Science and Application, Ministry of Education, Beijing Forestry University, Beijing 100083, China
2.
Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, China

Funds: National Natural Science Foundation of China (32171707); Beijing Natural Science Foundation of China (6202024)

摘要

摘要: 日益增长的能源需求与不断加剧的环境危机使高性能储能装置成为近些年来的研究热点。根据功率和能量密度，储能设备可分为电化学电容器、二次电池和燃料电池等，其中电极材料在制备绿色环保和高性能储能器中起着重要作用。纳米纤维素来源丰富、环境友好、制备方法多样、高比表面积、优异的力学性能和良好的生物相容性等优点使得其在储能材料的制备及其性能提高方面具有巨大的应用潜力和发展前景。本文针对纳米纤维素的分类、制备方法、改性及纳米纤维素基复合材料进行了总结，重点介绍了纳米纤维素与电活性物质混合及基于纳米纤维素制备的水凝胶、气凝胶、纸/膜复合材料和作为碳前驱体在电极材料的应用和研究进展。
- 纳米纤维素 /
- 电极材料 /
- 储能装置 /
- 可持续发展 /
- 电化学性能
Abstract: The ongoing surge in demand for energy and the increasing environmental crisis makes the high-performance energy storage device become a research hotspot in recent years. Based on the power and energy density, energy storage devices can be divided into electrochemical capacitors, secondary batteries, and fuel cells, etc. Electrode materials play an important role in the preparation of energy storage with green environment protection and high performance. Nanocellulose has great application potential and development prospect in the preparation and performance improvement of energy storage materials due to their natural abundance, environmental sustainability, high specific surface area, excellent mechanical properties and biocompatibility. In this paper, the classification, preparation, modification of nanocellulose and nanocellulose composites were summarized, the application and research progress of the mixing of nanocellulose with electroactive substances and the preparation of hydrogel, aerogel, paper/film composites based on nanocellulose and as carbon precursors in electrode materials were mainly introduced.
- nanocellulose /
- electrode material /
- energy storage /
- sustainable development /
- electrochemical pro-perties

HTML全文

图 1 纳米纤维素制备过程^[1]： (a)纳米纤维素纤维(CNF)和纳米纤维素晶(CNC)制备；(b)细菌纤维素(BC)制备

Figure 1. Nanocellulose preparation process^[1]: (a) Preparation of cellulose nanofiber (CNF) and cellulose nanocrystals (CNC); (b) Preparation of bacterial nanocellulose (BC)

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图 2 用作储能电极的3种不同材料^[12]

PPy—Polypyrrole; PEDOT—Poly(3, 4-ethylenedioxythiophene); PTh—Polythiophene; PPP—Poly(p-phenylene); CNT—Carbon nanotubes; GO—Graphene oxide

Figure 2. Schematic diagram of three different types of materials used as supercapacitor electrodes^[12]

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图 3 纳米纤维素在储能系统的应用

CNC—Cellulose nanocrystals; CNF—Cellulose nanofiber; BC—Bacterial nanocellulose; QAFCGO—Quaternary ammonium-functionalized nanocellulose/graphene oxide; SCs—Supercapacitors

Figure 3. Application of nanocellulose in energy storage system

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图 4 脱木素木材沉积聚吡咯(PPy) (DWP)、2, 2, 6, 6-四甲基哌啶氧化法(TEMPO)氧化DWP周期分别为1~3 h (TDWP-1、TDWP-2、TDWP-3)电极的电化学性能^[23]：(a) 10 mV/s扫描速率下的CV曲线；(b)扫描速率为30 mA/cm⁻²时的电容保持率

Figure 4. Electrochemical performance of delignified wood deposits polypyrrole (PPy) (DWP), the period of 2, 2, 6, 6-tetramethylpiperidine oxidation (TEMPO) oxidizing DWP is 1-3 h (TDWP-1, TDWP-2, TDWP-3) electrodes^[23]: (a) CV curves at 10 mV/s scan rate; (b) Capacitance retention rate at scan rate of 30 mA/cm⁻²

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图 5 高导电性碳纳米管纸^[25]：(a)在商业纸上直接印刷碳纳米管；(b)不同半径弯曲导电纸后的薄层电阻变化

R/R₀—Ratio of resistance after bending to resistance before bending

Figure 5. Highly conductive carbon nanotube paper^[25]: (a) Direct printing of carbon nanotubes on commercial paper; (b) Sheet resistance changes after bending the conductive paper at different radii

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图 6 纳米纤维素晶(CNC)/GeO₂气凝胶制备过程^[29]

DMF—N, N-dimethylformamide

Figure 6. Aerogel preparation process of cellulose nanocrystals (CNC)/GeO₂^[29]

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图 7 纳米纤维素在薄膜应用^[31]：(a)独立电极制造工艺示意图；((b), (c))碳纳米管(CNT)-CNC800的截面形貌

EC—Ethylene carbonate; DEC—Diethyl carbonate

Figure 7. Nanocellulose in thin film applications^[31]: (a) Schematic illustration of the free-standing electrode fabrication process; ((b), (c)) Cross-section morphologies of carbon nanotube (CNT)-CNC800

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