Development of IL/MOF ternary mixed matrix membrane for CO2 separation
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摘要: 气体膜分离技术,作为实现碳中和的一种关键气体分离方法,在二氧化碳捕集领域取得了显著进展,混合基质膜(Mixed matrix membrane, MMM)结合了聚合物膜和多孔填料的优点,使其成为传统聚合物膜的有效替代品。然而,界面不相容性问题限制了MMM的气体分离性能。在膜分离技术中,通过引入第三种组分(通常是功能化添加剂)来制备的三元MMM,能够有效克服二元MMM在结构上存在的问题,并对膜的分离性能产生积极的影响。本综述聚焦于探讨离子液体(Ionic Liquid, IL)与金属有机框架(Metal-Organic Framework, MOF)作为高效填料共同用于三元相MMM的制备过程,深入分析了IL与MOF整合入MMM后所产生的协同效应,尤其是它们对提升膜材料机械稳定性和气体吸附性能方面的显著贡献。文中详细介绍了MMM中气体分离的传输机制,总结了IL/MOF复合材料的结构和制备工艺,并对三元相MMM的CO2分离性能进行详尽的综述与分析。基于这些分离性能数据,进一步讨论了三元相MMM所面临的挑战,为未来膜分离技术的发展提供了新的思路和方向。Abstract: Gas separation membrane technology, as a key gas separation method to achieve carbon neutrality, has made significant progress in the field of carbon dioxide capture, Mixed matrix membrane (MMM) combines the advantages of polymer membranes and porous fillers, making it an effective alternative to conventional polymer membranes. However, interface incompatibility issues limit MMM's gas separation performance. In Membrane separation technology, MMM prepared by introducing a third component (usually a functional additive) can effectively overcome the structural problems of binary phase MMM and have a positive impact on the separation performance of the membrane. This review focuses on the preparation process of ternary phase MMM using Ionic Liquid (IL) and Metal-Organic Framework (MOF) as high efficiency fillers, and further analyzes the synergistic effect of integrating IL and MOF into MMM. In particular, they contribute significantly to improving the mechanical stability and gas adsorption properties of membrane materials. In this paper, the transport mechanism of gas separation in MMM is introduced in detail, the structure and preparation process of IL/MOF composites are summarized, and the CO2 separation performance of ternary phase MMM is reviewed and analyzed in detail. Based on these separation performance data, the challenges faced by ternary phase MMM are further discussed, which provides new ideas and directions for the development of membrane separation technology in the future.
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Key words:
- CO2 capture /
- Membrane separation /
- Mixed matrix membrane /
- Ionic liquid /
- Metal-Organic Framework
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图 2 溶解-扩散过程示意图(a) 与膜接触的上游气体溶解到膜表面;(b) 由于浓度梯度,气体分子通过膜扩散;(c)气体分子通过膜以线性浓度梯度达到扩散平衡。
Figure 2. Dissolved - diffusion process diagram (a) contact with the membrane of upstream gas dissolves in the membrane surface; (b) Diffusion of gas molecules through membranes due to concentration gradients; (c) The diffusion equilibrium of gas molecules through the membrane is achieved in a linear concentration gradient.
图 5 离子液体(IL)/MOF复合材料合成中使用的不同的合成后浸渍[34]方法的示意图:(a)湿法浸渍法[35],(b)毛细管作用法[36],(c)瓶中船法[37],(d)采用湿法浸渍合成 ABIL-OH@HKUST-1[35],(e)采用毛细管作用法合成的EMI-TFSA的结构[41],(f)合成限制在Cr-MIL-101纳米笼中的BAIL的示意图[42]。
Figure 5. Schematic diagram of different post-synthetic impregnation methods used in Ionic Liquid (IL)/MOF composites synthesis[34] : (a) wet impregnation method [35], (b) capillary action method [36], (c) ship in a bottle method [37], (d) wet impregnation method for ABIL-OH@HKUST-1[35], (e) Structure of EMI-TFSA prepared by capillary action [41], (f) Schematic diagram of synthesized BAIL confined to Cr-MIL-101 nanoccages [42].
图 8 CO2与Robeson上限(2008年)相比,不同含量的PSf和几种固定10 wt%填料的MMM在303.15 K时的纯气体渗透结果:(a) CO2/CH4及(b) CO2/N2理想的选择性[64]。
Figure 8. CO2 vs. Robeson upper limit (2008) Pure gas permeation results at 303.15 K for PSf with different contents and MMM of several fixed 10 wt% fillers: (a) Ideal selectivity of CO2/CH4 and (b) CO2/N2[64].
表 1 通过不同合成方法合成IL/MOF复合材料的相关研究
Table 1. Studies on the synthesis of IL/MOF composites by different synthesis methods
IL MOF IL/MOF
Method of preparationReference [HMIM]Br ZIF-8 Solvothermal synthesis [32] [BMIM]Br MOF-5 Solvothermal synthesis [33] [rmi]X Mn-MOF Solvothermal synthesis [43] [EMIM][HBDC], [EMIM]2[BDC] UiO-66 Solvothermal synthesis [44] [AMI]Br Co-MOF Solvothermal synthesis [45] [BMI]Cl Zn-MOF Solvothermal synthesis [46] [BMIM]Otf ZIF-8 Solvothermal synthesis [47] [EMIM][Tf2N] HKUST-1 Wet dipping method [47] [HEMIM] [DCA] ZIF-8 Wet dipping method [48] C8H15ClN2 MIL-101 (Cr) Wet dipping method [49] [SO3H-(CH2)3-HIM][HSO4] MIL-100(Fe) Wet dipping method [50] [BMIM]Cl MIL-101 Wet dipping method [51] [mim(CH2)3COOH]Cl Uio-66 Wet dipping method [52] [OMIM] Br MIL-100 (Fe) Wet dipping method [53] [BMIM][Tf2N]、[Emim][Tf2N]、[BMIM][BF4] ZIF-67 Wet dipping method [54] [DPP-NC(3)bim] [PMO] MIL-101 (Al) Ship in a bottle method [37] MBIAIL MIL-101 (Cr) Ship in a bottle method [55] BMIMOAc MIL-101-NH2 Ship in a bottle method [40] BAIL MIL-101 Ship in a bottle method [42] N(n-Bu)3Br、P(n-Bu)3Br MIL-101 Ship in a bottle method [56] AmPyI ZIF-90 Ship in a bottle method [57] EMIMCl Uio-67(Zr) Capillary action method [36] EIMS MIL-101 Capillary action method [58] EMI-TFSI ZIF-8 Capillary action method [41] EIMS-HTFSI MIL-101(Cr) Capillary action method [58] EMI-TFSI ZIF-8 Capillary action method [26] [EMIM][DCN]、[EMIM][TCB] MIL-100
(Al)Capillary action method [59] Notes: [HMIM]Br is 1-Hexyl-3-methylimidazolium bromide ;
[BMIM]Br is 1-Butyl-3-methylimidazolium bromide;
[rmi]X is rmi = 1-alkyl-3-methylimidazolium; r = ethyl or propyl, X = Cl, Br, or I(As a template agent); [EMIM][HBDC] is 1-Ethyl-3-methylimidazolium hydrogen bis(2-ethylhexyl) phosphate; [EMIM]2[BDC] is 1-Ethyl-3-methylimidazolium bis(2-ethylhexyl) phosphate;
[AMI]Br is 1-Allyl-3-methylimidazolium chloride;
[BMI]Cl is 1-Butyl-3-methylimidazolium chloride;
[BMIM]Otf is 1-Butyl-3-methylimidazolium trifluoromethansulfonate;
[HEMIM] [DCA] is 1-Hexyl-3-methylimidazolium dicyanamide;
C8H15ClN2 is 1-Butyl-3-methylimidazolium chloride;
[SO3H-(CH2)3-HIM][HSO4] is 3-Sulfonic acid propylimidazolium hydrogen sulfate;
[BMIM]Cl is 1-Butyl-3-methylimidazolium chloride;
[mim(CH2)3COOH]Cl is 1-Methyl-3-(3-carboxypropyl)imidazolium chloride;
[OMIM] Br is 1-Octyl-3-methylimidazolium bromide;
[BMIM][Tf2N] is 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide;
[Emim][Tf2N] is 1-Ethylimidazolium bis(trifluoromethylsulfonyl)imide ;
[BMIM][BF4] is 1-Butyl-3-methylimidazolium tetrafluoroborate;
[DPP-NC(3)bim] [PMO] is Di(3,3'-dipyridyl)methane di(3-cyanomethyl)imidazolium phosphate;
MBIAIL is Methylbenzimidazolium ionic liquid;
BMIMOAc is 1-Butyl-3-methylimidazolium acetate;
BAIL is Amine-based ionic liquid; N(n-Bu)3Br is Tributylamine bromide;
P(n-Bu)3Br is Tributylphosphine bromide;
AmPyI is 1-Aminopyridinium iodide;
EMIMCl is 1-Ethyl-3-methylimidazolium chloride;
EIMS is 1-Ethyl-3-methylimidazolium ethyl sulfate;
EMI-TFSI is 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide;
EIMS-HTFSI is 1-Ethyl-3-methylimidazolium bis(heptafluorobutylsulfonyl)imide;
EMI-TFSI is 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide;
[EMIM][DCN] is 1-Ethyl-3-methylimidazolium dicyanamide;
[EMIM][TCB] is 1-Ethyl-3-methylimidazolium trichlorobenzene.表 2 不同IL/MOF复合材料的制备方法和MOF纳米负载的聚合物基MMM的CO2捕获能力渗透性的比较,膜的CO2/CH4和CO2/N2选择性。
Table 2. Preparation methods of different IL/MOF composites and comparison of CO2 capture capacity of MOF NPS-supported polymer based MMM permeability, CO2/CH4 and CO2/N2 selectivity of the membranes.
MOF IL Polymer Preparation method Filler content/% CO2 permeability/
barrerCO2/CH4 select-ivity CO2/N2
selec-tivityReference ZIF-8 [BMIM][Tf2N] Pebax 1657 Blending method 16.8–18.3% IL in ZIF-8; 0–25% composite 104.9 34 83.9 [27] ZIF-8 [BMIM][Tf2N] PSf Blending method 6 307 26 53 [27] ZIF-8 [BMIM][Tf2N] Pebax Blending method 5 80 21 58 [27] ZIF-8 [BMIM][Tf2N] PSf Pre-modified by ship in bottle method Wide range 310 45.7 130 [30] ZIF-8 [BMIm]Otf PVIM/PI Pre-modified by ship in bottle method 570 37.5 39 [30] ZIF-8 [EMIM][DCA] PSf Blending method 10%/30% (composite—3–30% IL) 8.3 35.51 36.83 [64] ZIF-8 [EMIM][TCM] PSf 10.05 56.29 60.43 [64] ZIF-8 [EMIM][Tf2N] PSf 7.36 85.3 64.25 [64] ZIF-8 DnBMCl Pebax 1657 Blending method 40% IL in PX—0–32% filler 260 37 70 [65] ZIF-8 [EMIM][BF4] PIL
P[vbim][Tf2N]Wet impregnation 33% IL in PIL—0-25% filler 340 16.59 29.06 [66] ZIF-8 [EMIM][Tf2N] 693.6 12.1 19.65 [66] ZIF-8 [EMIM][B(CN)4] 1062.4 12.34 24.2 [66] ZIF-67 [BMIM][BF4] PIM-1
6 FDA-
durene
Wet impregnation
Wet impregnation
10 % ZIF-67/PIM-1
5% IL in composite 20% in MMM1300 17 27 [54] ZIF-67 TSIL 9971.3 7.6 [67] ZIF-67 [EMIM][Tf2N] 1200 25 25 [54] ZIF-67 [BMIM][Tf2N] 900 28 27.5 [54] ZIF-67 [BMIM][BF4] PI Pre-modified by ship in bottle method 20 1250 24 25 [54] HKUST-1/Cu3(BTC)2 [EMIM][BF4] Matrimid
5218Blending method 10 32.5 46.7 18.69 [68] HKUST-1/Cu3(BTC)2 [EMIM][OTF] Matrimid
5218Blending method 10 37.78 97 24.4 [68] HKUST-1 [EMIM][Tf2N] PI Pre-modified by ship in bottle method 10 1101.6 29.3 27.1 [69] NH2-MIL-101(Cr) [NH2bim][Tf2N] PIM-1 Solvothermal synthesis 5 2979 - 37 [70] UiO-66 IL-ClO4 PU Solvothermal synthesis 30 - 15.3 24.4 [71] UiO-66 IL-ClO4 PU Solvothermal synthesis 50 - 32.3 18.3 [71] Notes: Pebax 1657 is Poly (ether-block-amide) resin-1657 ;
PSf is Polysulfone;
Pebax is Poly(ether-block-amide);
PVIM is Poly(N-vinylimidazole) ;
PI is Polyimide;
PILis Poly(N-isopropylacrylamide);
P[vbim][Tf2N] is Poly(vinylimidazole) bis(trifluoromethanesulfonyl)imide;
PIM-1 is Prolyl Isomerase of Mammalian-1;
Matrimid5218 is Polyamide-imide;
PU is Polyurethane. -
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