Research progress of plant-derived porous carbon materials in supercapacitors
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摘要: 超级电容器是一种功率密度高、充放电速率快、使用寿命长、应用范围广的储能装置。影响其性能的主要因素是电极材料,故导电性好、原料易得、成本低、环境友好的电极材料的开发是当今超级电容器的研究重点。植物衍生多孔碳材料因其满足上述要求而受到广泛关注。本文按照前驱体的来源对植物衍生多孔碳材料进行了分类,介绍了近年来国内外植物衍生多孔碳材料用于超级电容器电极材料的研究成果,讨论了植物衍生多孔碳电极材料在超级电容器领域中所面临的挑战,并对植物衍生多孔碳材料的发展前景进行了展望。Abstract: Supercapacitors represent an energy storage device renowned for its high-power density, rapid charging/discharging rates, long service life, and versatility across diverse applications. The primary factor influencing their performance lies in the electrode materials. Consequently, the development of electrode materials that are conductive, readily available, cost-effective, and environmentally friendly has emerged as a pivotal research focus in the field of supercapacitors. Plant-based porous carbon materials have garnered significant attention due to their adherence to these criteria. This paper categorizes plant-based porous carbons based on their precursor sources, reviews recent research achievements worldwide on their application as electrode materials in supercapacitors, discusses the challenges faced by plant-based porous carbon electrode materials in this domain, and offers an outlook on their promising future.
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Key words:
- plant-derived /
- carbon materials /
- supercapacitors /
- electrode materials /
- research progress
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表 1 部分植物衍生碳材料的电化学性能
Table 1. Electrochemical properties of some plant-derived carbon materials
Material Activator Specific
Capacitance/(F·g−1)Electrolyte Energy density/
(Wh·kg−1)Power density/
(W·kg−1)Cycling
stabilityReference Shaddock endotheliums KOH 550
(0.2 A·g−1)1 mol·L−1
BMIMBF4/AN46.88 300 93.7% 10000 cycles97 Cashew nut husk KOH 305.2
(1 A·g−1)6 mol·L−1
KOH11.2 400 97.1% 4000 cycles98 Zanthoxylum Leaves ZnCl2 196
(0.5 A·g−1)0.5 mol·L−1
Na2SO418.68 225 92% 20000 cycles99 Pine pollen MgCO3 416.9
(1 A·g−1)6 mol·L−1
KOH34.9 181 97.4% 10000 cycles100 Willow catkin KOH 298
(0.5 A·g−1)6 mol·L−1
KOH21.0 180 99.7% 10000 cycles101 Loofah sponge KOH 309.6
(1 A·g−1)6 mol·L−1
KOH16.1 160 81.3% 10000 cycles102 Bamboo fungi [ZnCO3]2·
[Zn(OH)2]3367
(0.5 A·g−1)6 mol·L−1
KOH24.6 400 95.7% 10000 cycles103 Banana CO2 178.9
(1 A·g−1)6 mol·L−1
KOH3.23 50 67% 10000 cycles104 Eucalyptus bark KOH 483.5
(0.5 A·g−1)1 mol·L−1
Na2SO421.7 168.9 83.1% 10000 cycles105 Lacquer wood H3PO4 354
(0.2 A·g−1)1 mol·L−1
H2SO4/ / 95.3% 10000 cycles106 Notes:BMIMBF4/AN is 1-butyl-3-methylimidazolium tetrafluoroborate/acetonitrile -
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