植物衍生多孔碳材料在超级电容器中的研究进展

王园园; 董省身; 夏莹京; 宋华

植物衍生多孔碳材料在超级电容器中的研究进展

东北石油大学　化学化工学院, 黑龙江大庆 163318

基金项目: 国家自然科学基金 (22278068)；东北石油大学人才引进科研启动费资助(1305021821)

详细信息

通讯作者:
王园园，博士研究生，副教授，硕士生导师，研究方向为超级电容器电极材料的研究　E-mail: wangyuanyuan2016@126.com

中图分类号: TQ15；TB332
计量
- 文章访问数: 34
- HTML全文浏览量: 21
- 被引次数: 0
出版历程
- 收稿日期: 2024-07-18
- 修回日期: 2024-08-19
- 录用日期: 2024-08-31
- 网络出版日期: 2024-09-18

Research progress of plant-derived porous carbon materials in supercapacitors

College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

Funds: National Natural Science Foundation of China (22278068); Northeast Petroleum University talent introduction research project (1305021821)

摘要

摘要: 超级电容器是一种功率密度高、充放电速率快、使用寿命长、应用范围广的储能装置。影响其性能的主要因素是电极材料，故导电性好、原料易得、成本低、环境友好的电极材料的开发是当今超级电容器的研究重点。植物衍生多孔碳材料因其满足上述要求而受到广泛关注。本文按照前驱体的来源对植物衍生多孔碳材料进行了分类，介绍了近年来国内外植物衍生多孔碳材料用于超级电容器电极材料的研究成果，讨论了植物衍生多孔碳电极材料在超级电容器领域中所面临的挑战，并对植物衍生多孔碳材料的发展前景进行了展望。
- 植物衍生 /
- 碳材料 /
- 超级电容器 /
- 电极材料 /
- 研究进展
Abstract: Supercapacitors represent an energy storage device renowned for its high-power density, rapid charging/discharging rates, long service life, and versatility across diverse applications. The primary factor influencing their performance lies in the electrode materials. Consequently, the development of electrode materials that are conductive, readily available, cost-effective, and environmentally friendly has emerged as a pivotal research focus in the field of supercapacitors. Plant-based porous carbon materials have garnered significant attention due to their adherence to these criteria. This paper categorizes plant-based porous carbons based on their precursor sources, reviews recent research achievements worldwide on their application as electrode materials in supercapacitors, discusses the challenges faced by plant-based porous carbon electrode materials in this domain, and offers an outlook on their promising future.
- plant-derived /
- carbon materials /
- supercapacitors /
- electrode materials /
- research progress

HTML全文

图 1 各种植物前驱体用作超级电容器的电极材料

Figure 1. A variety of plants precursors used as electrode materials for supercapacitors

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图 2 NPCNs的制备方法及电化学性能^[20]

Figure 2. Preparation method and electrochemical properties of NPCNs ^[20]

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图 3 Co₃O₄/C复合材料的制备方法及电化学性能^[21]

Figure 3. Preparation method and electrochemical properties of Co₃O₄/C composites^[21]

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图 4 NiCo₂S₄/WHAC的制备方法及电化学性能^[27]

Figure 4. Preparation method and electrochemical properties of NiCo₂S₄/WHAC ^[27]

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图 5 PS-AC^[53]与KOH-AC^[54]的制备及电化学性能

Figure 5. Preparation and electrochemical properties of PS-AC^[53] and KOH-AC^[54]

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图 6 NixCo₃-xSy/CA的制备方法及电化学性能^[71]

Figure 6. Preparation method and electrochemical properties of NixCo₃-xSy/CA ^[71]

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图 7 AHPC^[81]与NPCNs^[83]的制备与电化学性能

Figure 7. Preparation and electrochemical properties of AHPC ^[81] and NPCNs ^[83]

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表 1 部分植物衍生碳材料的电化学性能

Table 1. Electrochemical properties of some plant-derived carbon materials

Material	Activator	Specific Capacitance/(F·g⁻¹)	Electrolyte	Energy density/ (Wh·kg⁻¹)	Power density/ (W·kg⁻¹)	Cycling stability	Reference
Shaddock endotheliums	KOH	550 (0.2 A·g⁻¹)	1 mol·L⁻¹ BMIMBF₄/AN	46.88	300	93.7% 10000 cycles	97
Cashew nut husk	KOH	305.2 (1 A·g⁻¹)	6 mol·L⁻¹ KOH	11.2	400	97.1% 4000 cycles	98
Zanthoxylum Leaves	ZnCl₂	196 (0.5 A·g⁻¹)	0.5 mol·L⁻¹ Na₂SO₄	18.68	225	92% 20000 cycles	99
Pine pollen	MgCO₃	416.9 (1 A·g⁻¹)	6 mol·L⁻¹ KOH	34.9	181	97.4% 10000 cycles	100
Willow catkin	KOH	298 (0.5 A·g⁻¹)	6 mol·L⁻¹ KOH	21.0	180	99.7% 10000 cycles	101
Loofah sponge	KOH	309.6 (1 A·g⁻¹)	6 mol·L⁻¹ KOH	16.1	160	81.3% 10000 cycles	102
Bamboo fungi	[ZnCO₃]₂· [Zn(OH)₂]₃	367 (0.5 A·g⁻¹)	6 mol·L⁻¹ KOH	24.6	400	95.7% 10000 cycles	103
Banana	CO₂	178.9 (1 A·g⁻¹)	6 mol·L⁻¹ KOH	3.23	50	67% 10000 cycles	104
Eucalyptus bark	KOH	483.5 (0.5 A·g⁻¹)	1 mol·L⁻¹ Na₂SO₄	21.7	168.9	83.1% 10000 cycles	105
Lacquer wood	H₃PO₄	354 (0.2 A·g⁻¹)	1 mol·L⁻¹ H₂SO₄	/	/	95.3% 10000 cycles	106
Notes：BMIMBF₄/AN is 1-butyl-3-methylimidazolium tetrafluoroborate/acetonitrile

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