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埃洛石纳米管负载芳樟醇及其防霉抗菌性能

张原菘 甘雯馨 曾钦志 赵伟刚 陈奶荣 饶久平

张原菘, 甘雯馨, 曾钦志, 等. 埃洛石纳米管负载芳樟醇及其防霉抗菌性能[J]. 复合材料学报, 2024, 42(0): 1-12.
引用本文: 张原菘, 甘雯馨, 曾钦志, 等. 埃洛石纳米管负载芳樟醇及其防霉抗菌性能[J]. 复合材料学报, 2024, 42(0): 1-12.
ZHANG Yuansong, GAN Wenxin, ZENG Qinzhi, et al. Antibacterial and Antifungal Properties of halloysite nanotubes by loaded Linalool[J]. Acta Materiae Compositae Sinica.
Citation: ZHANG Yuansong, GAN Wenxin, ZENG Qinzhi, et al. Antibacterial and Antifungal Properties of halloysite nanotubes by loaded Linalool[J]. Acta Materiae Compositae Sinica.

埃洛石纳米管负载芳樟醇及其防霉抗菌性能

基金项目: 国家自然科学基金 (32371795);中央引导地方科技发展资金项目(2023L3044);福建农林大学科技创新专项基金项目(KFB23138)
详细信息
    通讯作者:

    饶久平,博士,教授,博士生导师,研究方向为生物质复合材料 E-mail: rjustin@fafu.edu.cn

  • 中图分类号: TB332

Antibacterial and Antifungal Properties of halloysite nanotubes by loaded Linalool

Funds: National Natural Science Foundation of China (No.32371795); Center Leading Local Science and Technology Development Special Project (No.2023L3044); Fujian Agriculture and Forestry University Science and Technology Innovation Special Fund Project (No.KFB23138)
  • 摘要: 芳樟醇具有良好的抗菌和抗氧化性,但易挥发且热稳定性差。埃洛石纳米管(HNTs)存在特殊中空孔道结构并具有保护和释放活性物质的功能,常作为纳米载体。因此,开展HNTs负载芳樟醇(LNL)的研究并进行抗菌试验。采用真空负压法将LNL负载到3 mol/L盐酸酸化后的埃洛石纳米管(AC-HNTs)管腔内部,制备出芳樟醇-酸化埃洛石纳米管(L-AC-HNTs)新型防霉抗菌剂。以竹制品中常见的大肠杆菌(Escherichia coli)、金黄色葡萄球菌(Staphylococcus aureus)、黑曲霉菌(Aspergillus niger)、桔青霉菌(Penicillium oryzae)为目标菌种,考察不同添加量L-AC-HNTs的抑菌效果,测试其热稳定性和缓释性并进行表征分析。结果表明,添加1.5%(W/V)的L-AC-HNTs对以上几种细菌和霉菌的抑菌效果最佳,抑菌率均达到了100%。L-AC-HNTs的热分解速率峰值温度达到279.9 ℃,比纯LNL提高了81.5 ℃,AC-HNTs在50 ℃下挥发72 h后对LNL的保留率仍为94.6%,仅损失了3.4%,而纯LNL保留率为8%,酸化刻蚀后LNL负载量从5.0%最高提升至15.6%。L-AC-HNTs具有广谱抑菌性和热稳定性,为其在竹制品中的应用提供参考。

     

  • 图  1  芳樟醇-酸化埃洛石纳米管(L-AC-HNTs)防霉抗菌剂制备流程

    Figure  1.  linalool acidified halloysite nanotubes (L-AC-HNTs) antibacterial and antifungal agent preparation process

    图  2  HNTs负载芳樟醇(LNL)标准曲线

    Figure  2.  Standard curve of HNTs loaded with linalool (LNL)

    图  3  不同添加量L-AC-HNTs 对(a)Aspergillus Niger;(b) Penicillium citrinsis;(c)Colibacillus;(d)Staphylococcus Aureus的防霉抗菌效果

    Figure  3.  Antibacterial and antifungal effects of different levels of L-AC-HNTs on (a) Aspergillus Niger; (b) Penicillium citrinsis; (c) Escherichia coli; (d) Staphylococcus Aureus

    图  4  HNTs、L-AC-HNTs、LNL的(a)热重曲线;(b)微商热重曲线图;(c)LNL负载前后保留率

    Figure  4.  (a) Thermogravimetric profiles of HNTs, L-AC-HNTs, LNL; (b) Microcommercial thermogravimetric profiles; (c) Retention before and after LNL loading

    图  5  (a)LNL红外光谱图;(b)HNTs、AC-HNTs、L-AC-HNTs红外光谱图

    Figure  5.  (a) Infrared spectra of LNL; (b) Infrared spectra of HNTs、AC-HNTs、L-AC-HNTs

    图  6  (a) HNTs;(b) AC-HNTs;(c) L-AC-HNTs的扫描电镜(能量色散X射线光谱)

    Figure  6.  SEM (EDX) images of (a) HNTs; (b) AC-HNTs; (c) L-AC-HNTs

    图  7  (a) HNTs;(b) AC-HNTs;(c) L-AC-HNTs的高倍率透射电镜(能量色散X射线光谱)

    Figure  7.  TEM(EDX) images of (a) HNTs; (b) AC-HNTs; (c) L-AC-HNTs

    图  8  LNL、HNTs、AC-HNTs、L-AC-HNTs的X-射线衍射图

    Figure  8.  XRD patterns of LNL、HNTs、AC-HNTs、L-AC-HNTs

    图  9  (a) HNTs、AC-HNTs、L-AC-HNTs的XPS全谱;(b) Al2p的XPS光谱;(c) Si2p的XPS光谱

    Figure  9.  (a) XPS full spectrum of HNTs, AC-HNTs, L-AC-HNTs; (b) XPS spectrum of Al2p; (c) XPS spectrum of Si2p

    图  10  (a) HNTs、AC-HNTs、L-AC-HNTs的氮气等温吸附-脱附曲线;(b)酸化前后HNTs对不同添加量LNL负载量

    Figure  10.  (a) Nitrogen isothermal adsorption-desorption curves of HNTs、AC-HNTs、L-AC-HNTs; (b) Loadings of HNTs to different additions of LNL before and after acidification

    表  1  HNTs,AC-HNTs和L-AC-HNTs中Si、Al和C元素含量

    Table  1.   Content of Si、Al and C elements in HNTs, AC-HNTs and L-AC-HNTs

    Samples Si Atomic/% Al Atomic /% C Atomic /%
    HNTs 14.20% 12.39% 14.83%
    AC-HNTs 14.18% 12.26% 13.19%
    L-AC-HNTs 12.84% 11.2% 24.59%
    下载: 导出CSV

    表  2  HNTs,AC-HNTs和L-AC-HNTs的比表面积和孔径结构数据

    Table  2.   SBET and porosity data of HNTs, AC-HNTs and L-AC-HNTs

    SamplesSBET/(m2·g−1)Vpore/(cm3·g−1)
    HNTs13.53890.04
    AC-HNTs37.28930.09
    L-AC-HNTs28.81000.08
    Notes:SBET is the specific surface area,Vpore is the total pore volume.
    下载: 导出CSV
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  • 收稿日期:  2024-05-20
  • 修回日期:  2024-06-24
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