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不同生物质来源的多孔碳复合碳电极在钙钛矿太阳能电池中的应用

刘海潮 谢亚红 魏鹏 耿聪 王昊斌 郑申申

刘海潮, 谢亚红, 魏鹏, 等. 不同生物质来源的多孔碳复合碳电极在钙钛矿太阳能电池中的应用[J]. 复合材料学报, 2022, 39(5): 1956-1966. doi: 10.13801/j.cnki.fhclxb.20211209.001
引用本文: 刘海潮, 谢亚红, 魏鹏, 等. 不同生物质来源的多孔碳复合碳电极在钙钛矿太阳能电池中的应用[J]. 复合材料学报, 2022, 39(5): 1956-1966. doi: 10.13801/j.cnki.fhclxb.20211209.001
LIU Haichao, XIE Yahong, WEI Peng, et al. Application of porous carbon composite carbon electrodes from different biomass sources in perovskite solar cells[J]. Acta Materiae Compositae Sinica, 2022, 39(5): 1956-1966. doi: 10.13801/j.cnki.fhclxb.20211209.001
Citation: LIU Haichao, XIE Yahong, WEI Peng, et al. Application of porous carbon composite carbon electrodes from different biomass sources in perovskite solar cells[J]. Acta Materiae Compositae Sinica, 2022, 39(5): 1956-1966. doi: 10.13801/j.cnki.fhclxb.20211209.001

不同生物质来源的多孔碳复合碳电极在钙钛矿太阳能电池中的应用

doi: 10.13801/j.cnki.fhclxb.20211209.001
基金项目: 大连理工大学精细化工国家重点实验室开放项目(KF2004);新疆维吾尔自治区大学科研计划自然科学项目(XJEDU2020I006);新疆维吾尔自治区重点实验室开放项目(2019D04006)
详细信息
    作者简介:

    谢亚红,新疆大学教授,博士研究生导师,新疆优秀青年科技人才。博士毕业于日本东北大学,中国科学院新疆理化技术研究所博士后,大连理工大学、加拿大滑铁卢大学访问学者。中国可再生能源学会光化学专业委员会委员。 主要研究领域:光电功能材料,光催化材料,新型太阳能电池的开发与低温制备,油田精细化学品。研究包括微/纳米催化/光催化功能材料的合成及其催化性能研究,新型硅基材料、碳材料的合成及其性能研究,染料敏化太阳能电池、钙钛矿薄膜太阳能电池,无机半导体薄膜太阳能关键材料的开发与研究。主持和结题包括国家自然科学基金、自治区自然科学基金、国家博士后基金、自治区重点实验室开放课题在内的课题10多项。在Chem. Mater., Chem. Eng.J., ChemComm, J. Power Sources, Carbon等国际期刊上以第一作者和通讯作者发表学术论文50余篇,获得新疆大学第五届青年科研奖,新疆大学自然科学一等奖(排名第一),新疆维吾尔自治区自然科学二等奖(排名第一)

    通讯作者:

    谢亚红,博士,教授,硕士生/博士生导师,研究方向为光电转化与储存材料的设计合成与综合利用 E-mail: xyh0707@163.com

  • 中图分类号: TM914.4

Application of porous carbon composite carbon electrodes from different biomass sources in perovskite solar cells

  • 摘要: 通过将生物质在惰性气体保护下高温热解/活化制备多孔碳材料,具有成本低,工艺简单等优点,并且是一种废物利用,减少环境污染的有效途径。将三种不同生物质通过高温热解/活化制备了多孔碳材料,将其与市售导电碳浆复合制成碳浆料后应用于钙钛矿太阳能电池(PSCs)背电极,研究了不同生物质多孔碳材料的形貌、结构和比表面积等对器件光电性能的影响。结果表明,基于不同生物质多孔碳材料的PSCs的光电性能取决于生物质多孔碳材料的形貌、结晶度、比表面积和形态以及钙钛矿/碳电极的界面接触。基于生物质多孔碳的复合碳电极结合研磨工艺制备的碳基PSCs,由于具有良好的界面性能获得最高10.18%的光电转换效率(PCE)(未复合生物质碳的PSCs的PCE为6.39%),室温下保存60天后,仍保留了初始PCE的96%。

     

  • 图  1  700℃热解/活化后CSC、COC和SDC的SEM图像

    Figure  1.  SEM images of CSC, COC and SDC after 700℃ pyrolysis/activation

    图  2  CSC、COC和SDC的XRD图谱(a)、Raman图谱(b)、氮气吸脱附等温线(c)和孔径分布曲线(d)

    Figure  2.  XRD spectra (a), Raman spectra (b), nitrogen adsorption and desorption isotherms (c) and pore size distribution curves (d) of CSC, COC and SDC

    图  3  (a) 钙钛矿太阳能电池的截面SEM图像; (b) 钙钛矿太阳能电池的结构示意图

    Figure  3.  (a) Cross-sectional SEM image of PSCs; (b) Schematic diagram of the structure of PSCs

    图  4  SDC、COC、CSC和CPC器件的J-V曲线(a)、阻抗谱图和等效电路图(b)

    Figure  4.  J-V curves (a) and impedance spectrogram and equivalent circuit diagrams (b) of SDC, COC, CSC and CPC devices

    图  5  (a) SDC、COC、CSC和CPC器件在经过20 s光照后的延迟开路光电压降(OCVD);(b) OCVD曲线对应的依据电子空穴复合机制得到的电子寿命τ'n和开路电压Voc的关系图

    Figure  5.  (a) Delayed open circuit photovoltage drop (OCVD) of SDC, COC, CSC and CPC device after 20 seconds illumination; (b) Relationship between the electron lifetime τ'n and the open circuit voltage Voc obtained by the electron hole recombination mechanism corresponding to the OCVD curve

    图  6  用光电参数显示的SDC、COC、CSC和CPC器件的箱形图

    Figure  6.  Statistical box diagrams of SDC, COC, CSC and CPC device

    图  7  SDC、COC、CSC和CPC器件的正反扫曲线

    Figure  7.  Reverse and forward scan curves of SDC, COC, CSC and CPC device

    图  8  SDC (a)、COC (b)、CSC (c)和CPC (d)基C-PSCs在最大功率点的稳态光电流测试

    Figure  8.  Steady-state photocurrent output of SDC (a), COC (b), CSC (c) and CPC (d)-based C-PSCs

    图  9  SDC (a)、COC (b)、CSC (c)和CPC (d)基C-PSCs器件在空气条件下60天的稳定性测试

    Figure  9.  SDC (a), COC (b), CSC (c) and CPC (d)-based C-PSCs stability test under air conditions for 60 days

    表  1  CSC、COC和SDC生物质碳样品BET参数

    Table  1.   BET parameters of CSC, COC and SDC bio-carbon samples

    SampleSSA
    /(m2·g−1)
    Vtotal
    /(cm3·g−1)
    Vmicro
    /(cm3·g−1)
    Vmeso
    /(cm3·g−1)
    D
    /nm
    CSC10670.3740.3140.0601.74
    COC12200.3960.3120.0841.79
    SDC14040.5920.4340.1581.92
    Notes: SSA—Specific surface area; Vtotal—Total pore volume; Vmicro—Micropore volume; Vmeso—Mesopore volume; D—Average pore diameter.
    下载: 导出CSV

    表  2  SDC、COC、CSC和CPC器件的最佳光电性能和平均光电参数

    Table  2.   Optimal and average optoelectronic parameters of SDC, COC, CSC and CPC device

    SampleVoc/VJsc/(mA·cm−2)FFPCE/%
    SDCBest0.8722.860.5110.18
    Average0.87±0.0220.91±0.670.48±0.039.17±0.58
    COCBest0.8721.310.499.03
    Average0.81±0.0620.17±1.260.44±0.047.46±0.99
    CSCBest0.8322.400.417.62
    Average0.80±0.0520.97±1.840.41±0.026.78±0.52
    CPCBest0.7720.310.416.39
    Average0.75±0.0417.10±1.490.43±0.025.48±0.59
    Notes: Voc—Voltage of open circuit; Jsc—Current of short circuit; FF—Fill factor; PCE—Photoelectric conversion efficiency.
    下载: 导出CSV

    表  3  SDC、COC、CSC和CPC器件的阻抗参数

    Table  3.   Optical impedance parameters of SDC, COC, CSC and CPC devices

    SampleRsRtrRrec
    SDC20.1369.9392.96
    COC15.870.7629.75
    CSC18.787.1347.89
    CPC16.543.1266.71
    Notes: Rs—Sheet resistance; Rtr—Transfer resistance; Rrec—Recombination resistance.
    下载: 导出CSV

    表  4  SDC、COC、CSC和CPC器件的正反扫光电性能数据和迟滞因子

    Table  4.   Reverse and forward scanning photoelectric performance data and hysteresis factor of SDC, COC, CSC and CPC device

    SampleVoc/VJsc/(mA·cm−2)FFPCE/%HF/%
    SDC-R0.8721.490.5410.058
    SDC-F0.8521.880.509.25
    COC-R0.8719.860.528.9214
    COC-F0.8518.760.497.71
    CSC-R0.8121.200.427.1823
    CSC-F0.7322.760.335.53
    CPC-R0.7518.910.436.1032
    CPC-F0.6618.600.344.15
    Note: HF—Hysteresis factor.
    下载: 导出CSV
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出版历程
  • 收稿日期:  2021-09-06
  • 修回日期:  2021-11-16
  • 录用日期:  2021-12-13
  • 网络出版日期:  2021-12-13
  • 刊出日期:  2022-03-23

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