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基于高分子配体修饰改善卤系钙钛矿稳定性的研究进展

马彤彤 马建中 范倩倩 张文博 刘蜜

马彤彤, 马建中, 范倩倩, 等. 基于高分子配体修饰改善卤系钙钛矿稳定性的研究进展[J]. 复合材料学报, 2024, 42(0): 1-11.
引用本文: 马彤彤, 马建中, 范倩倩, 等. 基于高分子配体修饰改善卤系钙钛矿稳定性的研究进展[J]. 复合材料学报, 2024, 42(0): 1-11.
MA Tongtong, MA Jianzhong, FAN Qianqian, et al. Research progress on stability improvement by polymeric ligand modification for halide perovskite[J]. Acta Materiae Compositae Sinica.
Citation: MA Tongtong, MA Jianzhong, FAN Qianqian, et al. Research progress on stability improvement by polymeric ligand modification for halide perovskite[J]. Acta Materiae Compositae Sinica.

基于高分子配体修饰改善卤系钙钛矿稳定性的研究进展

基金项目: 国家自然科学基金(No. 22378251,No. 52103088);陕西省科协青年人才托举计划项目(No.20230469)
详细信息
    通讯作者:

    马建中,博士,教授,博士生导师,研究方向为有机/无机纳米复合材料的关键技术, E-mail: majz@sust.edu.cn

    范倩倩,博士,副教授,硕士生导师,研究方向为新型钙钛矿复合光催化材料, E-mail: qianqianfan@sust.edu.cn

  • 中图分类号: TB383; TB332

Research progress on stability improvement by polymeric ligand modification for halide perovskite

Funds: National Natural Science Foundation of China (No. 22378251, No. 52103088); Youth Talent Support Program of Shaanxi Association for Science and Technology (No.20230469)
  • 摘要: 卤系钙钛矿具有吸收系数大、载流子迁移率高、荧光量子产率高、载流子寿命长、光电转化系数高、带隙可调等优异的特性,在发光二极管、太阳能电池、探测传感器、防伪等多领域,具有良好的应用前景,但其稳定性较差,易受外界环境影响(如温度、湿度),引起其发生分解、晶体结构改变、相变等,导致其光学性能减弱,局限了它的应用。目前,卤系钙钛矿稳定性仍是一个重要的研究方向。本文首先介绍了卤系钙钛矿的结构,并分析了影响卤系钙钛矿稳定性的外部因素;然后,总结了高分子配体修饰改善卤系钙钛矿稳定性的研究进展;最后,就现阶段卤系钙钛矿纳米材料研究中存在的问题及未来研究方向进行了展望。

     

  • 图  1  卤系钙钛矿的结构。(a) ABX3卤系钙钛矿的单胞晶体结构,(b)三维和(c) 二维钙钛矿材料

    Figure  1.  Figure caption structure of halide perovskite. (a) Unicellular crystal structure of ABX3 halide perovskite. (b) 3 D and (c) 2 D perovskite materials.

    图  2  卤系钙钛矿在水存在下可能的分解途径

    Figure  2.  Possible decomposition pathways of halide perovskite in the presence of water.

    图  3  碘基钙钛矿中光诱导离子重组示意图

    Figure  3.  Schematic of light-induced ionic restructuring in iodine-based perovskites.

    图  4  卤系钙钛矿-淀粉结构示意图[54-55]

    Figure  4.  Perovskite-starch structures[54-55]

    图  5  (a) 骨明胶钝化钙钛矿纳米晶的示意图; (b) 骨明胶-钙钛矿纳米晶对Fe3+离子的检测机制图[19]

    Figure  5.  (a)Bone gelatin passivation perovskite nanocrystals; (b) Detection mechanism of bone gelatin and perovskite nanocrystals for Fe3+ ions[19]

    图  6  EC与钙钛矿之间氢键形成示意图[58]

    Figure  6.  Schematic diagram of hydrogen bond formation between EC and perovskite[58]

    图  7  CsPbBr3@PAA-b-PS PQDs的示意图[60]

    Figure  7.  A schematic of CsPbBr3 @PAA-b-PS PQDs[60]

    图  8  聚酰胺(PAA)的化学结构及合成过程

    Figure  8.  The chemical structure and synthesize procedure of polyamide (PAA)

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  • 收稿日期:  2024-04-02
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