B<sub>4</sub>C-SiC复合陶瓷力学性能的研究进展

张巍

B₄C-SiC复合陶瓷力学性能的研究进展

张巍^,

中国科学院金属研究所沈阳材料科学国家研究中心, 沈阳 110016

基金项目: 辽宁省自然科学基金(2022-MS-013)，中国科学院金属研究所自主部署项目(E255L401)，沈阳材料科学国家研究中心青年人才项目(E21SL412)

详细信息

通讯作者:
张巍，博士，副研究员，硕士生导师，研究方向为无机非金属材料结构和物性　E-mail: cnzhangwei2008@126.com

中图分类号: TB321; TB332
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- 被引次数: 0
出版历程
- 收稿日期: 2024-03-22
- 修回日期: 2024-04-16
- 录用日期: 2024-04-23
- 网络出版日期: 2024-06-05

Advance in investigation on mechanical properties of B₄C-SiC composite ceramics

ZHANG Wei^,

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Funds: Natural Science Foundation of Liaoning Province of China (2022-MS-013), Starting Grants of Institute of Metal Research, Chinese Academy of Science (E255L401), Shenyang National Laboratory for Materials Science (E21SL412)

摘要

摘要: B₄C-SiC复合陶瓷结合了碳化硼(B₄C)和碳化硅(SiC)的性能，具有良好的物理和力学性能。与单相B₄C陶瓷相比，B₄C-SiC复合陶瓷具有更高的断裂韧性；与单相SiC陶瓷相比，B₄C-SiC复合陶瓷具有更大的硬度。B₄C-SiC复合陶瓷有望替代单相B₄C陶瓷和单相SiC陶瓷广泛应用于工程领域。B₄C-SiC复合陶瓷的力学性能与B₄C-SiC复合粉体的颗粒分散均匀性有关。同时，B₄C-SiC复合陶瓷的力学性能还受微观结构和相组成的影响。为了降低B₄C-SiC复合陶瓷的烧结温度，常在原料中添加烧结助剂，常用的烧结助剂主要有：碳、氧化物、硼化物、碳化物、金属单质、非金属单质(除碳外)。不同烧结助剂促进B₄C-SiC复合陶瓷烧结的机制各不相同；同时，这些烧结助剂通过影响B₄C-SiC复合陶瓷的微观结构进而影响其力学性能。本文根据B₄C-SiC复合陶瓷力学性能的研究结果，从B₄C-SiC复合粉体、微观结构、相组成和烧结助剂等方面详细阐述了B₄C-SiC复合陶瓷力学性能的影响因素，以期为B₄C-SiC复合陶瓷的设计和研究提供依据。
- B₄C-SiC /
- 复合陶瓷 /
- 力学性能 /
- 微观结构 /
- 烧结助剂
Abstract: B₄C-SiC composite ceramics combine the properties of boron carbide (B₄C) and silicon carbide (SiC) and have good physical and mechanical properties. Compared with monolithic B₄C ceramics, B₄C-SiC composite ceramics have improved fracture toughness. Compared with monolithic SiC ceramics, B₄C-SiC composite ceramics possess increased hardness. B₄C-SiC composite ceramics are expected to replace monolithic B₄C ceramics and monolithic SiC ceramics to be widely used in engineering fields. The mechanical properties of B₄C-SiC composite ceramics are related to the particle dispersion uniformity of B₄C-SiC composite powders. Meanwhile, the mechanical properties of B₄C-SiC composite ceramics are also influenced by their microstructure and phase composition. In order to reduce the sintering temperature of B₄C-SiC composite ceramics, sintering additives are often added to the raw materials. The commonly used sintering additives include carbon, oxides, borides, carbides, metallic elements, and non-metallic elements (excluding carbon). The mechanisms by which different sintering additives promote the sintering of B₄C-SiC composite ceramics vary. At the same time, these sintering additives affect the microstructure of B₄C-SiC composite ceramics, which in turn affects their mechanical properties. Based on the research results of mechanical properties of B₄C-SiC composite ceramics in recent years, the influencing factors of mechanical properties of B₄C-SiC composite ceramics are summarized in this review from the aspects of B₄C-SiC composite powders, microstructure, phase composition, and sintering additives, so as to provide a basis for the design and investigation of B₄C-SiC composite ceramics.
- boron carbide-silicon carbide /
- composite ceramics /
- mechanical property /
- microstructure /
- sintering additive

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图 1 B₄C-SiC复合陶瓷的应用

Figure 1. Applications of B₄C-SiC composite ceramics

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图 2 B₄C-50wt%SiC复合陶瓷的微观结构：(a)以湿磨后的B₄C-SiC复合粉体为原料，(b)以干磨后的B₄C-SiC复合粉体为原料^[42]

Figure 2. Microstructure of B₄C-50wt%SiC composite ceramics produced from: (a) B₄C-SiC composite powders after wet ball milling and (b) B₄C-SiC composite powders after dry mixing^[42]

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图 3 B₄C-SiC复合陶瓷的力学性能：(a)以湿磨后的B₄C-SiC复合粉体为原料，(b)以干磨后的B₄C-SiC复合粉体为原料^[42]

Figure 3. Mechanical properties of B₄C-SiC composite ceramics produced from: (a) B₄C-SiC composite powders after wet ball milling and (b) B₄C-SiC composite powders after dry mixing^[42]

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图 4 B₄C-50wt%SiC复合陶瓷断面的微观结构：(a)以高能球磨的B₄C-SiC复合粉体为原料，(b)以普通球磨的B₄C-SiC复合粉体为原料^[47]

Figure 4. Microstructure of fracture surfaces of B₄C-50wt%SiC composite ceramics produced from: (a) B₄C-SiC composite powders prepared by high-energy ball milling and (b) B₄C-SiC composite powders prepared by ball milling^[47]

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图 5 固相烧结B₄C-SiC复合陶瓷的相界特征、裂纹扩展及断面：(a)洁净且清晰的相界^[50]，(b)穿晶扩展^[47]，(c)断面处粗糙的SiC晶粒^[54]

Figure 5. Phase boundary characteristics, crack propagation, and fracture surface of solid-state sintered B₄C-SiC composite ceramics: (a) clean and clear phase boundary^[50], (b) transgranular propagation mode^[47], and (c) fracture surface exhibiting rougher SiC grains^[54]

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图 6 不同B₄C与SiC质量比的B₄C-SiC复合陶瓷的抛光表面形貌：(a) 80∶20，(b) 60∶40，(c) 40∶60，(d) 20∶80^[59]

Figure 6. Morphologies of polished surface of B₄C-SiC composite ceramics with different mass ratios of B₄C to SiC: (a) 80∶20, (b) 60∶40, (c) 40∶60, (d) 20∶80^[59]

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图 7 含有5wt%氧化石墨烯烧结助剂的B₄C-SiC复合陶瓷表面的裂纹扩展：(a)石墨烯桥联，(b)石墨烯拔出^[74]

Figure 7. Crack propagation on surface of B₄C-SiC composite ceramics with sintering additive of 5wt% graphene oxide: (a) graphene oxide bridging and (b) graphene oxide pull-out^[74]

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图 8 含有5wt%CeO₂烧结助剂的B₄C-SiC复合陶瓷表面的裂纹扩展：(a)裂纹偏转，(b)裂纹桥联^[78]

Figure 8. Crack propagation on surface of B₄C-SiC composite ceramics with sintering additive of 5wt%CeO₂: (a) crack deflection and (b) crack bridging^[78]

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图 9 B₄C-40wt%SiC复合陶瓷表面的裂纹扩展：(a)未添加TiB₂，(b)添加5wt%TiB₂^[94]

Figure 9. Crack propagation on surface of B₄C-40wt%SiC composite ceramics: (a) without addition of TiB₂ and (b) with addition of 5wt%TiB₂^[94]

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表 1 含有不同碳烧结助剂的B₄C-SiC复合陶瓷的力学性能

Table 1. Mechanical properties of B₄C-SiC composite ceramics with different carbon sintering additives

Ceramics	Sintering additive	Content of sintering additive/wt%	Sintering method	Relative density/%	Vickers hardness/ GPa (9.8 N)	Bending strength/ MPa	Fracture toughness/ (MPa·m^1/2)	Elastic modulus/ GPa	Ref.
B₄C-9wt%SiC	Carbon black	2	Hot-press	99.6	-	403	5.26 (SENB)	-	[70]
B₄C-15wt%SiC	No	No	Spark plasma	96.6	30.3	-	6.00 (IF)	-	[32]
B₄C-15wt%SiC	Graphite	2	Spark plasma	98.8	25.7	-	5.50 (IF)	-	[32]
B₄C-15wt%SiC	Graphene oxide	5	Spark plasma	99.2	34.2	545	5.72 (IF)	444	[74]
Notes: The bending strength is measured according to three-point bending test method. ‘SENB’ and ‘IF’ represent that the fracture toughness is measured according to single edge notched beam method and indentation-fracture method, respectively.

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表 2 含有不同氧化物烧结助剂的B₄C-SiC复合陶瓷的力学性能

Table 2. Mechanical properties of B₄C-SiC composite ceramics with different oxide sintering additives

Ceramics	Sintering additive	Content of sintering additive	Sintering method	Relative density/%	Vickers hardness/ GPa	Bending strength/ MPa	Fracture toughness/ (MPa·m^1/2)	Ref.
B₄C-10wt%SiC	Al₂O₃	3wt%	Spark plasma	99.5	35.1 (3 N)	-	5.9 (IF)	[76]
B₄C-10wt%SiC	Al₂O₃	6wt%	Spark plasma	99.1	33.7 (3 N)	-	6.5 (IF)	[76]
B₄C-15vol%SiC	No	No	Spark plasma	97.8	31.1 (9.8 N)	-	-	[77]
B₄C-15vol%SiC	Y₂O₃	5wt%	Spark plasma	98.2	33.0 (9.8 N)	-	-	[77]
B₄C-15wt%SiC	No	No	Pressureless	85.8	19.8 (9.8 N)	194	2.40 (SENB)	[78]
	CeO₂	1wt%		91.2	26.0 (9.8 N)	270	3.25 (SENB)
	CeO₂	5wt%		96.4	32.2 (9.8 N)	380	4.32 (SENB)
	CeO₂	9wt%		93.4	27.0 (9.8 N)	330	4.00 (SENB)
B₄C-9wt%SiC	No	No	Pressureless	82.8	-	307	3.72 (SENB)	[81]
B₄C-9wt%SiC	Al₂O₃-Y₂O₃	15wt%	Pressureless	98.8	-	496	4.57 (SENB)	[81]
B₄C-10wt%SiC	Al₂O₃:Y₂O₃(5:3, molar ratio)	10vol%	Pressureless	91.5	29.5 (9.8 N)	-	-	[83]
B₄C-10wt%SiC	AlN:Y₂O₃(3:2, molar ratio)	10vol%	Pressureless	93.4	30.3 (9.8 N)	-	-	[83]

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表 3 含有不同硼化物或碳化物烧结助剂的B₄C-SiC复合陶瓷的力学性能

Table 3. Mechanical properties of B₄C-SiC composite ceramics with different boride or carbide sintering additives

Ceramics	Sintering additive	Content of sintering additive	Sintering method	Relative density/%	Vickers hardness/ GPa (9.8 N)	Bending strength/ MPa	Fracture toughness/ (MPa·m^1/2)	Elastic modulus/ GPa	Ref.
B₄C-40wt%SiC	No	No	Spark plasma	99.5	29.5	-	2.39 (IF)	436	[94]
	TiB₂	10wt%		99.0	28.5	-	3.07 (IF)	427
	TiB₂	20wt%		98.4	23.4	-	2.96 (IF)	415
B₄C-10vol%SiC	TiB₂	30vol%	Hot-press	99.2	32.8	858	8.21 (SENB)	-	[95]
B₄C-10vol%SiC	ZrB₂	30vol%	Hot-press	99.7	-	612	-	-	[96]
B₄C-20wt%SiC	TiC	3wt%	Pressureless	89.7	-	176	4.57 (SENB)	-	[98]
	TiC	12wt%		94.5	-	239	4.91 (SENB)	-
	TiC	15wt%		92.1	-	230	4.75 (SENB)	-

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表 4 含有不同金属或非金属单质烧结助剂的B₄C-SiC复合陶瓷的力学性能

Table 4. Mechanical properties of B₄C-SiC composite ceramics with different metallic or non-metallic elemental sintering additives

Ceramics	Sintering additive	Content of sintering additive/wt%	Sintering method	Relative density/%	Vickers hardness/ GPa (9.8 N)	Bending strength/ MPa	Fracture toughness/ (MPa·m^1/2)	Ref.
B₄C-50wt%SiC	No	No	Pressureless	97.5	-	290	-	[99]
B₄C-50wt%SiC	Ti	3	Pressureless	97.6	-	204	-	[99]
B₄C-15wt%SiC	No	No	Hot-press	95.4	24.0	265	4.96	[101]
	Si	4		95.8	26.4	260	5.06
	Si	15		98.3	31.0	350	5.40
B₄C-60wt%SiC	No	No	Pressureless	89.0	20.0	-	-	[103]
	Si	2		88.0	14.0	-	-
	Si	5		89.0	16.2	-	-
	Si	10		92.0	18.1	-	-
	Si	20		90.0	15.0	-	-
B₄C-60wt%SiC	No	No	Spark plasma	94.0	28.0	-	-	[103]
	Si	2		94.6	22.0	-	-
	Si	5		96.3	24.4	-	-
	Si	10		98.0	27.8	-	-
	Si	20		97.0	24.0	-	-

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[1]	ZARE A, HE M R, STRAKER M, et al. Mechanical characterization of boron carbide single crystals[J]. Journal of the American Ceramic Society, 2022, 105(5): 3030-3042. doi: 10.1111/jace.18065
[2]	ZHANG W, YAMASHITA S, KITA H. Self lubrication of pressureless sintered SiC ceramics[J]. Journal of Materials Research and Technology, 2020, 9(6): 12880-12888. doi: 10.1016/j.jmrt.2020.09.022
[3]	THÉVENOT F. Boron carbide- a comprehensive review[J]. Journal of the European Ceramic Society, 1990, 6(4): 205-225. doi: 10.1016/0955-2219(90)90048-K
[4]	ZHANG W. Tribology of SiC ceramics under lubrication: Features, developments, and perspectives[J]. Current Opinion in Solid State & Materials Science, 2022, 26(4): 101000.
[5]	ZHANG W, YAMASHITA S, KITA H. Effects of load on tribological properties of B₄C and B₄C-SiC ceramics sliding against SiC balls[J]. Journal of Asian Ceramic Societies, 2020, 8(3): 586-596. doi: 10.1080/21870764.2020.1769819
[6]	KHODAEI M, YAGHOBIZADEH O, ALHOSSEINI S H N, et al. The effect of oxide, carbide, nitride and boride additives on properties of pressureless sintered SiC: A review[J]. Journal of the European Ceramic Society, 2019, 39(7): 2215-2231. doi: 10.1016/j.jeurceramsoc.2019.02.042
[7]	SURI A K, SUBRAMANIAN C, SONBER J K, et al. Synthesis and consolidation of boron carbide: a review[J]. International Materials Reviews, 2010, 55(1): 4-40. doi: 10.1179/095066009X12506721665211
[8]	ZHANG W, CHEN X Y, YAMASHITA S, et al. Frictional characteristics of carbide ceramics in water[J]. Journal of Tribology, 2022, 144(1): 011702. doi: 10.1115/1.4050732
[9]	ZHANG W. A review of tribological properties for boron carbide ceramics[J]. Progress in Materials Science, 2021, 116: 100718. doi: 10.1016/j.pmatsci.2020.100718
[10]	ZHANG W, YAMASHITA S, KITA H. Progress in tribological research of SiC ceramics in unlubricated sliding-A review[J]. Materials & Design, 2020, 190: 108528.
[11]	LEE W E, GILBERT M, MURPHY S T, et al. Opportunities for advanced ceramics and composites in the nuclear sector[J]. Journal of the American Ceramic Society, 2013, 96(7): 2005-2030. doi: 10.1111/jace.12406
[12]	SAUERSCHNIG P, WATTS J L, VANEY J B, et al. Thermoelectric properties of phase pure boron carbide prepared by a solution-based method[J]. Advances in Applied Ceramics, 2020, 119(2): 97-106. doi: 10.1080/17436753.2019.1705017
[13]	ZHANG W, CHEN X Y, YAMASHITA S, et al. B₄C–SiC ceramics with interfacial nanorelief morphologies and low underwater friction and wear[J]. ACS Applied Nano Materials, 2021, 4(3): 3159-3166. doi: 10.1021/acsanm.1c00375
[14]	ZHANG W, DAI W Y, CHIYODA N. Research on thermal shock resistance of mullite-bauxite-silicon carbide castable refractory[J]. Chinese Journal of Geochemistry, 2012, 31(2): 204-208. doi: 10.1007/s11631-012-0569-z
[15]	ZHANG J, ZHANG Y, WANG Y F, et al. Long-term oxidation performance of SiC_f/SiC composites at 1200 ℃ in air atmosphere manufactured by PIP and hybrid CVI/PIP techniques[J]. Ceramics International, 2024, 50(7): 10259-10267. doi: 10.1016/j.ceramint.2023.12.337
[16]	ZHANG W, YAMASHITA S, KUMAZAWA T, et al. Tribological properties of B₄C ceramics prepared by pressureless sintering and annealed at different temperatures[J]. Tribology Transactions, 2020, 63(4): 672-682. doi: 10.1080/10402004.2020.1734705
[17]	ZHANG W, YAMASHITA S, KUMAZAWA T, et al. Influence of surface roughness parameters and surface morphology on friction performance of ceramics[J]. Journal of the Ceramic Society of Japan, 2019, 127(11): 837-842. doi: 10.2109/jcersj2.19124
[18]	张巍, 张杰. 碳化硼陶瓷自润滑的研究现状[J]. 中国表面工程, 2024, 37(3): 15-26. ZHANG Wei, ZHANG Jie. State of the art on self-lubrication of boron carbide ceramics[J]. China Surface Engineering, 2024, 37(3): 15-26(in Chinese).
[19]	崔凤单, 马天, 李伟萍, 等. SiC和B₄C防弹插板抗多发弹打击损伤特性研究[J]. 无机材料学报, 2017, 32(9): 967-972. doi: 10.15541/jim20160667 CUI Fengdan, MA Tian, LI Weiping, et al. Damage characteristics of SiC and B₄C ballistic insert plates subjected to multi-hit[J]. Journal of Inorganic Materials, 2017, 32(9): 967-972(in Chinese). doi: 10.15541/jim20160667
[20]	ZHANG W, YAMASHITA S, KITA H. Progress in pressureless sintering of boron carbide ceramics-A review[J]. Advances in Applied Ceramics, 2019, 118(4): 222-239. doi: 10.1080/17436753.2019.1574285
[21]	李树杰, 陈孝飞, 刘文慧, 等. 采用聚硅氧烷(HPSO-VPSO)和Al-Si粉连接无压烧结SiC陶瓷[J]. 复合材料学报, 2011, 28(1): 88-93. LI Shujie, CHEN Xiaofei, LIU Wenhui, et al. Joining of pressureless sintered SiC using polysiloxane (HPSO-VPSO) with additive Al-Si powders[J]. Acta Materiae Compositae Sinica, 2011, 28(1): 88-93(in Chinese).
[22]	YAMADA S, HIRAO K, YAMAUCHI Y, et al. B₄C−CrB₂ composites with improved mechanical properties[J]. Journal of the European Ceramic Society, 2003, 23(3): 561-565. doi: 10.1016/S0955-2219(02)00094-8
[23]	GUPTA S, SHARMA S K, KUMAR B V M, et al. Tribological characteristics of SiC ceramics sintered with a small amount of yttria[J]. Ceramics International, 2015, 41(10): 14780-14789. doi: 10.1016/j.ceramint.2015.07.210
[24]	SECRIST D R. Phase equilibria in the system boron carbide-silicon carbide[J]. Journal of the American Ceramic Society, 1964, 47(3): 127-130. doi: 10.1111/j.1151-2916.1964.tb14369.x
[25]	HONG J D, SPEAR K E, STUBICAN V S. Directional solidification of SiC-B₄C eutectic: growth and some properties[J]. Materials Research Bulletin, 1979, 14(6): 775-783. doi: 10.1016/0025-5408(79)90137-5
[26]	ZORZI J E, PEROTTONI C A, JORNADA J A H. Hardness and wear resistance of B₄C ceramics prepared with several additives[J]. Materials Letters, 2005, 59(23): 2932-2935. doi: 10.1016/j.matlet.2005.04.047
[27]	BIND J M, BIGGERS J V. Hot-pressing of silicon carbide with 1 % boron carbide addition[J]. Journal of the American Ceramic Society, 1975, 58(7-8): 304-306. doi: 10.1111/j.1151-2916.1975.tb11482.x
[28]	LI C R, LI S, AN D, et al. Microstructure and mechanical properties of spark plasma sintered SiC ceramics aided by B₄C[J]. Ceramics International, 2020, 46(8): 10142-10146. doi: 10.1016/j.ceramint.2020.01.005
[29]	张巍, 张杰. B₄C-Al₂O₃复合陶瓷增韧机理研究[J]. 材料研究学报, 2024. ZHANG Wei, ZHANG Jie. Study on the toughening mechanism of B₄C-Al₂O₃ composite ceramics[J]. Chinese Journal of Materials Research, 2024(in Chinese).
[30]	LYU X X, ZHAO Z Y, SUN H L, et al. Influence of Y₂O₃ contents on sintering and mechanical properties of B₄C-Al₂O₃ multiphase ceramic composites[J]. Journal of Materials Research and Technology, 2020, 9(5): 11687-11701. doi: 10.1016/j.jmrt.2020.08.072
[31]	BAHARVANDI H R, HADIAN A M, ABDIZADEH A, et al. Investigation on addition of ZrO₂-3 mol% Y₂O₃ powder on sintering behavior and mechanical properties of B₄C[J]. Journal of Materials Science, 2006, 41(16): 5269-5272. doi: 10.1007/s10853-006-0355-6
[32]	MOSHTAGHIOUN B M, ORTIZ A L, GARCÍA D G, et al. Toughening of super-hard ultra-fine grained B₄C densified by spark-plasma sintering via SiC addition[J]. Journal of the European Ceramic Society, 2013, 33(8): 1395-1401. doi: 10.1016/j.jeurceramsoc.2013.01.018
[33]	MAGNANI G, BELTRAMI G, MINOCCARI G L, et al. Pressureless sintering and properties of αSiC-B₄C composite[J]. Journal of the European Ceramic Society, 2001, 21(5): 633-638. doi: 10.1016/S0955-2219(00)00244-2
[34]	ZHANG W, CHEN X Y, YAMASHITA S, et al. Effect of water temperature on tribological performance of B₄C-SiC ceramics under water lubrication[J]. Tribology Letters, 2021, 69(2): 34. doi: 10.1007/s11249-021-01406-0
[35]	ZHANG W, YAMASHITA S, KITA H. A study of B₄C-SiC composite for self-lubrication[J]. Journal of the American Ceramic Society, 2021, 104(5): 2325-2336. doi: 10.1111/jace.17584
[36]	ZHANG W. A novel ceramic with low friction and wear toward tribological applications: Boron carbide-silicon carbide[J]. Advances in Colloid and Interface Science, 2022, 301: 102604. doi: 10.1016/j.cis.2022.102604
[37]	宋小伟. 振荡压力烧结B₄C-SiC_w复合陶瓷制备与性能研究[D]. 郑州: 郑州航空工业管理学院, 2023. SONG Xiaowei. Preparation and properties of B₄C-SiC_w composite ceramics sintered by hot oscillating pressure[D]. Zhengzhou: Zhengzhou University of Aeronautics, 2023(in Chinese).
[38]	陈家鑫, 曾启航, 王峰, 等. B₄C增强SiC基复合陶瓷力学性能和抗氧化性能[J]. 硅酸盐学报, 2023, 51(3): 730-737. CHEN Jiaxin, ZENG Qihang, WANG Feng, et al. Mechanical and oxidation resistance of SiC based composite ceramics reinforced with B₄C[J]. Journal of the Chinese Ceramic Society, 2023, 51(3): 730-737(in Chinese).
[39]	ZHANG W, YAMASHITA S, KUMAZAWA T, et al. Effect of nanorelief structure formed in situ on tribological properties of ceramics in dry sliding[J]. Ceramics International, 2019, 45(11): 13818-13824. doi: 10.1016/j.ceramint.2019.04.078
[40]	ZHANG W, YAMASHITA S, KUMAZAWA T, et al. Study on friction behavior of SiC-B₄C composite ceramics after annealing[J]. Industrial Lubrication and Tribology, 2020, 72(5): 673-679.
[41]	ZHANG W. An overview of the synthesis of silicon carbide-boron carbide composite powders[J]. Nanotechnology Reviews, 2023, 12: 20220571. doi: 10.1515/ntrev-2022-0571
[42]	YAŞAR Z A, HABER R A. Evaluating the role of uniformity on the properties of B₄C–SiC composites[J]. Ceramics International, 2021, 47(4): 4838-4844. doi: 10.1016/j.ceramint.2020.10.055
[43]	ZHANG W, YAMASHITA S, KITA H. Effect of counterbody on tribological properties of B₄C–SiC composite ceramics[J]. Wear, 2020, 458-459: 203418. doi: 10.1016/j.wear.2020.203418
[44]	ZHANG W, CHEN X Y, YAMASHITA S, et al. Tribological behaviour of B₄C-SiC composite ceramics under water lubrication: influence of counterpart[J]. Materials Science and Technology, 2021, 37(9): 863-876. doi: 10.1080/02670836.2021.1961365
[45]	SO S M, CHOI W H, KIM K H, et al. Mechanical properties of B₄C–SiC composites fabricated by hot-press sintering[J]. Ceramics International, 2020, 46(7): 9575-9581. doi: 10.1016/j.ceramint.2019.12.222
[46]	MATOVIĆ B, MALETAŠKIĆ J, PRIKHNA T, et al. Characterization of B₄C-SiC ceramic composites prepared by ultra-high pressure sintering[J]. Journal of the European Ceramic Society, 2021, 41(9): 4755-4760. doi: 10.1016/j.jeurceramsoc.2021.03.047
[47]	ZHANG Z X, DU X W, WANG W M, et al. Preparation of B₄C–SiC composite ceramics through hot pressing assisted by mechanical alloying[J]. International Journal of Refractory Metals and Hard Materials, 2013, 41: 270-275. doi: 10.1016/j.ijrmhm.2013.04.012
[48]	ZHANG Z X, DU X W, WANG W M, et al. Preparation and sintering of high active and ultrafine B₄C-SiC composite powders[J]. Journal of Inorganic Materials, 2014, 29(2): 185-190. doi: 10.3724/SP.J.1077.2014.13226
[49]	ZHANG W. Recent progress in B₄C–SiC composite ceramics: processing, microstructure, and mechanical properties[J]. Materials Advances, 2023, 4(15): 3140-3191. doi: 10.1039/D3MA00143A
[50]	ZHANG W, YAMASHITA S, KUMAZAWA T, et al. A study on formation mechanisms of relief structure formed in situ on the surface of ceramics[J]. Ceramics International, 2019, 45(17): 23143-23148. doi: 10.1016/j.ceramint.2019.08.008
[51]	ZHU Y, LUO D J, LI Z J, et al. Effect of sintering temperature on the mechanical properties and microstructures of pressureless-sintered B₄C/SiC ceramic composite with carbon additive[J]. Journal of Alloys and Compounds, 2020, 820: 153153. doi: 10.1016/j.jallcom.2019.153153
[52]	KALANDARAGH Y A, NAMINI A S, AHMADI Z, et al. Reinforcing effects of SiC whiskers and carbon nanoparticles in spark plasma sintered ZrB₂ matrix composites[J]. Ceramics International, 2018, 44(16): 19932-19938. doi: 10.1016/j.ceramint.2018.07.258
[53]	HWANG C, YANG Q, XIANG S, et al. Fabrication of dense B₄C-preceramic polymer derived SiC composite[J]. Journal of the European Ceramic Society, 2019, 39(4): 718-725. doi: 10.1016/j.jeurceramsoc.2018.12.029
[54]	吴宇超, 曹剑武, 高晓菊, 等. 温度对SPS烧结B₄C-SiC复相陶瓷力学性能的影响[J]. 兵器材料科学与工程, 2019, 42(2): 21-24. WU Yuchao, CAO Jianwu, GAO Xiaoju, et al. Effect of temperature on mechanical properties of B₄C-SiC prepared by SPS sintering[J]. Ordnance Material Science and Engineering, 2019, 42(2): 21-24(in Chinese).
[55]	MORADKHANI A, BAHARVANDI H. Mechanical properties and fracture behavior of B₄C-nano/micro SiC composites produced by pressureless sintering[J]. International Journal of Refractory Metals & Hard Materials, 2018, 70: 107-115.
[56]	YE K C, WANG Z J. Residual stress effects on toughening of ultrafine-grained B₄C-SiC ceramics[J]. Materials Today Communications, 2023, 36: 106649. doi: 10.1016/j.mtcomm.2023.106649
[57]	张志晓, 杜贤武, 邢伟宏, 等. SiC含量对机械合金化-热压制备B₄C-SiC复合陶瓷的影响[J]. 无机材料学报, 2014, 29(7): 695-700. ZHANG Zhixiao, DU Xianwu, XING Weihong, et al. Effect of SiC content on B₄C-SiC composites fabricated by mechanical alloying-hot pressing[J]. Journal of Inorganic Materials, 2014, 29(7): 695-700(in Chinese).
[58]	CHO J Y, AN T, JI S, et al. The effects of B₄C addition on the microstructure and mechanical properties of SiC prepared using powders recovered from kerf loss sludge[J]. Ceramics International, 2017, 43(17): 15332-15338. doi: 10.1016/j.ceramint.2017.08.072
[59]	ZHANG W, YAMASHITA S, KITA H. Tribological properties of SiC-B₄C ceramics under dry sliding condition[J]. Journal of the European Ceramic Society, 2020, 40(8): 2855-2861. doi: 10.1016/j.jeurceramsoc.2020.02.062
[60]	VANDEPERRE L J, TEO J H. Pressureless sintering of SiC-B₄C composites[J]. Advances in Ceramic Armor IX, 2014, 101-108.
[61]	MCCLELLAN K J, CHU F, ROPER J M, et al. Room temperature single crystal elastic constants of boron carbide[J]. Journal of Materials Science, 2001, 36(14): 3403-3407. doi: 10.1023/A:1017947625784
[62]	张巍, 张金, 段春雷, 等. Al₂O₃抗热震陶瓷的研究进展[J]. 沈阳工业大学学报, 2020, 42(6): 624-647. doi: 10.7688/j.issn.1000-1646.2020.06.05 ZHANG Wei, ZHANG Jin, DUAN Chunlei, et al. Research progress in Al₂O₃ thermal shock resistant ceramics[J]. Journal of Shenyang University of Technology, 2020, 42(6): 624-647(in Chinese). doi: 10.7688/j.issn.1000-1646.2020.06.05
[63]	KEÇELI Z, ÖGÜNÇ H, BOYRAZ T, et al. Effects of B₄C addition on the micro-structural and thermal properties of hot pressed SiC ceramic matrix composites[J]. Journal of Achievements in Materials and Manufacturing Engineering, 2009, 37(2): 428-433.
[64]	CHEN W, HAO W H, ZHAO Z Q, et al. Mechanical properties and tribological characteristics of B₄C-SiC ceramic composite in artificial seawater[J]. Journal of Asian Ceramic Societies, 2021, 9(4): 1495-1505. doi: 10.1080/21870764.2021.1986202
[65]	TOMOHIRO Y, ATSUSHI N, KATSUAKI S, et al. Preparation and properties of B₄C-SiC composite[J]. Japan Society of Powder and Powder Metallurgy, 1990, 37(4): 571-574. doi: 10.2497/jjspm.37.571
[66]	XU C M, CAI Y B, FLODSTRÖM K, et al. Spark plasma sintering of B₄C ceramics: the effects of milling medium and TiB₂ addition[J]. International Journal of Refractory Metals and Hard Materials, 2012, 30(1): 139-144. doi: 10.1016/j.ijrmhm.2011.07.016
[67]	YAŞAR Z A, HABER R. Effect of acid etching time and concentration on oxygen content of powder on the microstructure and elastic properties of silicon carbide densified by SPS[J]. International Journal of Materials Science and Applications, 2020, 9(1): 7-13. doi: 10.11648/j.ijmsa.20200901.12
[68]	YAŞAR Z A, DELUCCA V A, HABER R A. Influence of oxygen content on the microstructure and mechanical properties of SPS SiC[J]. Ceramics International, 2018, 44(18): 23248-23253. doi: 10.1016/j.ceramint.2018.08.195
[69]	KAKIAGE M, TOMINAGA Y, YANASE I, et al. Synthesis of boron carbide powder in relation to composition and structural homogeneity of precursor using condensed boric acid-polyol product[J]. Powder Technology, 2012, 221: 257-263. doi: 10.1016/j.powtec.2012.01.010
[70]	李少峰. B₄C-SiC复合材料的制备及性能研究[J]. 佛山陶瓷, 2018, 28(5): 12-15. doi: 10.3969/j.issn.1006-8236.2018.05.004 LI Shaofeng. The research on preparation process and properties of B₄C-SiC composite materials[J]. Foshan Ceramics, 2018, 28(5): 12-15(in Chinese). doi: 10.3969/j.issn.1006-8236.2018.05.004
[71]	THÉVENOT F. Sintering of boron carbide and boron carbide-silicon carbide two-phase materials and their properties[J]. Journal of Nuclear Materials, 1988, 152(2-3): 154-162. doi: 10.1016/0022-3115(88)90321-2
[72]	GALÁN C A, ORTIZ A L, GUIBERTEAU F, et al. High-energy ball-milling of ZrB₂ in the presence of graphite[J]. Journal of the American Ceramic Society, 2010, 93(10): 3072-3075. doi: 10.1111/j.1551-2916.2010.04051.x
[73]	MOSHTAGHIOUN B M, GARCÍA D G, RODRÍGUEZ A D. High-temperature plastic deformation of spark plasma sintered boron carbide-based composites: The case study of B₄C-SiC with/without graphite (g)[J]. Journal of the European Ceramic Society, 2016, 36(5): 1127-1134. doi: 10.1016/j.jeurceramsoc.2015.12.016
[74]	HU L X, WANG A Y, TIAN T, et al. Effects of SiC on the microstructures and mechanical properties of B₄C–SiC–rGO composites prepared using spark plasma sintering[J]. Journal of the European Ceramic Society, 2022, 42(4): 1282-1291. doi: 10.1016/j.jeurceramsoc.2021.11.038
[75]	PYZIK A J, BEAMAN D R. Microstructure and properties of self-reinforced silicon nitride[J]. Journal of the American Ceramic Society, 2010, 76(11): 2737-2744.
[76]	JAMALE S, KUMAR B V M. Sintering and sliding wear studies of B₄C-SiC composites[J]. International Journal of Refractory Metals & Hard Materials, 2020, 87: 105124.
[77]	SAHIN F C, APAK B, AKIN I, et al. Spark plasma sintering of B₄C–SiC composites[J]. Solid State Sciences, 2012, 14(11-12): 1660-1663. doi: 10.1016/j.solidstatesciences.2012.05.037
[78]	ZHU Y, WANG F C, WANG Y W, et al. Mechanical properties and microstructure evolution of pressureless-sintered B₄C-SiC ceramic composite with CeO₂ additive[J]. Ceramics International, 2019, 45(12): 15108-15115. doi: 10.1016/j.ceramint.2019.04.251
[79]	YIN B Y, WANG L S. Study on physical properties of hot-pressing sintered B₄C ceramic[J]. Atomic Energy Science and Technology, 2004, 38(5): 429-431.
[80]	彭可武, 马贺利, 陈韧, 等. 原位生成CeB₆颗粒增韧B₄C/Al复合材料的研究[J]. 稀有金属, 2009, 33(6): 850-854. doi: 10.3969/j.issn.0258-7076.2009.06.017 PENG Kewu, MA Heli, CHEN Ren, et al. Toughening B₄C/Al ceramics by in-situ CeB₆ particles in B₄C[J]. Chinese Journal of Rare Metals, 2009, 33(6): 850-854(in Chinese). doi: 10.3969/j.issn.0258-7076.2009.06.017
[81]	李少峰. 液相烧结法制备B₄C-SiC复合陶瓷材料的研究[J]. 佛山陶瓷, 2019, 29(5): 10-13. doi: 10.3969/j.issn.1006-8236.2019.05.005 LI Shaofeng. The research on preparation of B₄C-SiC composite ceramic materials by liquid-phase sintering process[J]. Foshan Ceramics, 2019, 29(5): 10-13(in Chinese). doi: 10.3969/j.issn.1006-8236.2019.05.005
[82]	JAMALE S, KUMAR B V M. B₄C-SiC composites with tuneable mechanical properties: Role of Al₂O₃-Y₂O₃ sintering additives[J]. Journal of Alloys and Compounds, 2024, 976: 172954. doi: 10.1016/j.jallcom.2023.172954
[83]	ROCHA R M D, MELO F C L D. Pressureless sintering of B₄C-SiC composites for armor applications[J]. Ceramic Engineering & Science Proceedings, 2010, 30(5): 113-119.
[84]	ROCHA R M D, MELO F C L D. Sintering of B₄C-SiC composites with AlN-Y₂O₃ addition[J]. Materials Science Forum, 2012, 727-728: 850-855. doi: 10.4028/www.scientific.net/MSF.727-728.850
[85]	ZHOU Y, TANAKA H, OTANI S, et al. Low-temperature pressureless sintering of α-SiC with Al₄C₃-B₄C-C additions[J]. Journal of the American Ceramic Society, 1999, 82(8): 1959-1964. doi: 10.1111/j.1151-2916.1999.tb02026.x
[86]	ZHANG Y L, ZHANG Y M, LI C H, et al. Influence of reaction temperature on the densification behavior of the SiC/B₄C composites[J]. Applied Mechanics and Materials, 2015, 727-728: 11-14. doi: 10.4028/www.scientific.net/AMM.727-728.11
[87]	ZHANG Y L, ZHANG Y M, HU M, et al. Effect of B₄C content on densification behavior of SiC-B₄C ceramics[J]. Advanced Materials Research, 2014, 997: 454-456. doi: 10.4028/www.scientific.net/AMR.997.454
[88]	SCHWETZ K. Handbook of Ceramic Hard Materials[M]. Oxford: Alden Bookset, 2000.
[89]	RIDGWAY R R. Boron carbide: a new crystalline abrasive and wear-resisting product[J]. Transactions of the Electrochemical Society, 1934, 66(1): 117. doi: 10.1149/1.3498064
[90]	MUNRO R G. Material properties of titanium diboride[J]. Journal of Research of the National Institute of Standards and Technology, 2000, 105(5): 709-720. doi: 10.6028/jres.105.057
[91]	WU C, XIE S H, LI Y K. Microstructure evolution and phase transformation of TiB₂/SiC/B₄C composites synthesized from Ti-SiC-B₄C ternary system[J]. International Journal of Applied Ceramic Technology, 2017, 14(6): 1055-1061. doi: 10.1111/ijac.12740
[92]	ZHANG X R, ZHANG Z X, WANG W M, et al. Preparation of B₄C composites toughened by TiB₂-SiC agglomerates[J]. Journal of the European Ceramic Society, 2017, 37(2): 865-869. doi: 10.1016/j.jeurceramsoc.2016.09.003
[93]	ZHANG X R, ZHANG Z X, WANG W M, et al. Microstructure and mechanical properties of B₄C–TiB₂–SiC composites toughened by composite structural toughening phases[J]. Journal of the American Ceramic Society, 2017, 100(7): 3099-3107. doi: 10.1111/jace.14815
[94]	YAŞAR Z A, CELIK A M, HABER R A. Improving fracture toughness of B₄C–SiC composites by TiB₂ addition[J]. International Journal of Refractory Metals and Hard Materials, 2022, 108: 105930. doi: 10.1016/j.ijrmhm.2022.105930
[95]	HE Q L, WANG A Y, LIU C, et al. Microstructures and mechanical properties of B₄C-TiB₂-SiC composites fabricated by ball milling and hot pressing[J]. Journal of the European Ceramic Society, 2018, 38(7): 2832-2840. doi: 10.1016/j.jeurceramsoc.2018.02.020
[96]	QU Z L, HE R J, CHENG X M, et al. Fabrication and characterization of B₄C–ZrB₂–SiC ceramics with simultaneously improved high temperature strength and oxidation resistance up to 1600 ℃[J]. Ceramics International, 2016, 42(7): 8000-8004. doi: 10.1016/j.ceramint.2016.01.202
[97]	UPATOV M, VLEUGELS J, KOVAL Y, et al. Microstructure and mechanical properties of B₄C-NbB₂-SiC ternary eutectic composites by a crucible-free zone melting method[J]. Journal of the European Ceramic Society, 2021, 41(2): 1189-1196. doi: 10.1016/j.jeurceramsoc.2020.09.049
[98]	孟凡然, 王琨, 冯荣, 等. TiC对B₄C-SiC复合陶瓷材料性能的影响[J]. 佛山陶瓷, 2022, 32(3): 16-19. doi: 10.3969/j.issn.1006-8236.2022.03.005 MENG Fanran, WANG Kun, FENG Rong, et al. Effect of TiC on properties of B₄C-SiC composite ceramic materials[J]. Foshan Ceramics, 2022, 32(3): 16-19(in Chinese). doi: 10.3969/j.issn.1006-8236.2022.03.005
[99]	王书晗. B₄C/SiC和B₄C/TiB₂陶瓷复合材料的制备、组织及力学性能的研究[D]. 沈阳: 东北大学, 2019. WANG Shuhan. A study on preparation, microstructure and mechanical properties of B₄C/SiC and B₄C/TiB₂ ceramic composites[D]. Shenyang: Northeastern University, 2019(in Chinese).
[100]	王伟明, 王为得, 粟毅, 等. 以非氧化物为烧结助剂制备高导热氮化硅陶瓷的研究进展[J]. 无机材料学报, https://link.cnki.net/urlid/31.1363.TQ.20240202.1626.004. WANG Weiming, WANG Weide, SU Yi, et al. Research progress in high thermal conductivity silicon nitride ceramics prepared by non-oxide additives[J]. Journal of Inorganic Materials, https://link.cnki.net/urlid/31.1363.TQ.20240202.1626.004 (in Chinese).
[101]	DU X W, WANG Y, ZHANG Z X, et al. Effects of silicon addition on the microstructure and properties of B₄C–SiC composite prepared with polycarbosilane-coated B₄C powder[J]. Materials Science & Engineering A, 2015, 636: 133-137.
[102]	DU X W, ZHANG Z X, WANG W M, et al. Microstructure and properties of B₄C-SiC composites prepared by polycarbosilane-coating/B₄C powder route[J]. Journal of the European Ceramic Society, 2014, 34(5): 1123-1129. doi: 10.1016/j.jeurceramsoc.2013.10.039
[103]	SAHANI P, CHAIRA D. Nonlubricated sliding wear behavior study of SiC–B₄C–Si cermet against a diamond indenter[J]. Journal of Tribology, 2017, 139(5): 051601. doi: 10.1115/1.4035344