Research progress of graphene oxide composite coatings in metal corrosion protection
-
摘要: 氧化石墨烯(GO)作为石墨烯的衍生物具有优异的综合性能，在金属的防腐蚀领域中表现出了巨大的应用潜力。GO不仅具有石墨烯的二维层状结构，还含有羟基、羰基、羧基和环氧基团等官能团可作为活性位点与其他物质进行共价/非共价性功能化改性，因此氧化石墨烯常被用作填料来增强涂层的综合性能。本文以氧化石墨烯复合涂层为中心，简要的介绍了其理化性质，从当前世界金属腐蚀的情况和腐蚀类型为切入点，针对一些常用的腐蚀防护方法进行了讨论。综述了近年来国内外关于氧化石墨烯与有机物和无机物的复合涂层在金属腐蚀与防护领域的研究进展并对复合涂层的防腐机制进行了简述；最后，总结了目前研究工作中存在的关键科学难题与挑战，对涂层的研究方向与应用前景进行了展望。Abstract: As a derivative of graphene, graphene oxide (GO) has excellent comprehensive performance, showing great application potential in metal corrosion and protection. Graphene oxide has not only a two-dimensional layered structure but also contains hydroxyl, carbonyl, carboxyl, epoxy groups and other functional groups that can be used as active sites with other substances for covalent/non-covalent functionalization modification, so graphene oxide is often used as a filler to enhance the comprehensive performance of coatings. This paper reviews the recent research progress on graphene oxide composite coating in metal corrosion and protection. The first part summarizes the morphology of metal corrosion and the corrosion protection methods, explains the primary forms of metal corrosion, and discusses the current main metal corrosion protection methods. The second part introduces the physicochemical properties of graphene and its derivatives. In this paper, graphene oxide (GO) is the main focus. It has tremendous application potential in metal corrosion protective coatings due to its sheet structure, excellent dispersion, and abundant oxygen-containing functional groups on the surface, which are the active point of the reaction and easy modification. The third part introduces the current GO composite coating, which compares the corrosion resistance of traditional coatings, GO organic/inorganic unit composite coatings and GO multi-composite coatings. It was found that the performance of GO multi-component composite coating is far better than that of GO organic/inorganic unit composite coating and traditional coating. This is due to the excellent dispersion of GO, which enables it to fill the pores that occur during the curing and film-forming process of organic polymer materials and improve the corrosion resistance of the coating. The photogenic cathodic protection mechanism and current situation of GO anti-corrosion coating are introduced, and due to the green environmental protection and excellent anti-corrosion effect, it is regarded as the future development trend of GO composite coating. The fourth part summarizes the key scientific issues and challenges of GO composite anti-corrosion coating in the current research. It looks forward to the research direction and application prospect of GO composite anti-corrosion coating.
-
图 5 GO/Mn-Zn2SiO4材料的腐蚀防护机制图[43](光生阴极效应(a)、无机锰离子磁感应效应(b)、二维GO屏蔽效应(c)、阴极二次保护效应(d))
Figure 5. Corrosion protection mechanism of GO/Mn-Zn2SiO4 material [43]. (Photogenerated cathode effect (a), inorganic manganese ion magnetic induction effect (b), two-dimensional GO shielding effect (c), cathode secondary protection effect (d))
表 1 GO作为涂层填料相对于其他常见无机填料的优缺点
Table 1. Advantages and disadvantages of GO as a coating filler over other common inorganic fillers
Type Character Advantages Disadvantages GO 1. High specific surface area, good mechanical properties, excellent barrier and shielding properties;
2. Excellent response reactivity, thermal and chemical stabilities;
3. Oxygen-containing functional group can serve as active sites for reactions; hydrophilic groups on the surface are more easily modified by polymers or alkali metal oxides;
4. "Maze effect" can increase the diffusion path of the corrosion factor in the coating, and has a high resistance to permeability.1. Easy to agglomerate, dispersibility and stability are reduced after agglomeration;
2. Electrical conductivity, prone to galvanic coupling corrosion at locations of coating defects.Nano-ZnO 1. High melting point;
2. Good oxidation and corrosion resistance.1. High surface activity, easy to agglomerate and lose the special effect of nanoparticles after agglomeration;
2. Hydrophilic and oleophobic, poor dispersibility and stability in organic media;
3. Weak bonding with the substrate, poor interfacial compatibility, easy to produce voids, micro-cracks and other interfacial defects.Nano-Al2O3 1. High strength, thermal conductivity and wear resistance;
2. Excellent electrical insulation;
3. Stable physical and chemical properties.1. Poor compatibility with the substrate, poor dispersion, easy to agglomerate；
2. Functionalisation of the surface may lead to a reduction in filler size, resulting in defects on the surface;
3. Different shapes and sizes also have an effect on the corrosion resistance of the coating.Micro/Nano-SiO2 1. High hardness, high mechanical strength;
2. Excellent thermal and chemical stability;
3. Low density, small particle size, large specific surface area;
4. Colorless, odorless and pollution-friendly;
5. Good corrosion resistance.1. Fine particles and high hydrophilicity, easy to agglomerate;
2. The coating is prone to cracking during curing and reducing the corrosion resistance of the coating.
下载: 导出CSV
-
[1] BALANDIN A A, GHOSH S, BAO W Z, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Letters, 2008, 8(3): 902-907. doi: 10.1021/nl0731872 [2] GUO S J, DONG S J. Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications[J]. Chemical Society reviews, 2011, 40(5): 2644-2672. doi: 10.1039/c0cs00079e [3] LIANG X, LI X J, TANG Y, et al. Hyperbranched epoxy resin-grafted graphene oxide for efficient and all-purpose epoxy resin modification[J]. Journal of Colloid and Interface Science, 2022, 611: 105-117. doi: 10.1016/j.jcis.2021.12.068 [4] WANG J Q, ZHANG P, LIANG B, et al. Graphene oxide as an effective barrier on a porous nanofibrous membrane for water treatment[J]. ACS Applied Materials & Interfaces, 2016, (8): 6211-6218. [5] CHEN J H, LI W G, ZHAO Y T, et al. Application of graphene in anti-corrosive and anti-fouling coating[J]. Surface technology, 2019, 48(6): 89-97. [6] ZHANG Y J, SHAO Y W, LIU X L, et al. A study on corrosion protection of different polyaniline coatings for mild steel[J]. Progress in organic coatings, 2017, 111: 240-247. doi: 10.1016/j.porgcoat.2017.06.015 [7] CHENG L, LIU C, HAN D, et al. Effect of graphene on corrosion resistance of waterborne inorganic zinc-rich coatings[J]. Journal of Alloys and Compounds, 2019, 774: 255-264. doi: 10.1016/j.jallcom.2018.09.315 [8] LE H S, NGUYEN D L, JUKKA S. Enhanced mechanical and thermal properties of polyurethane functionalized Graphene oxide composites by in situ polymerization[J]. Plastics, Rubber and Composites, 2019, 48(10): 466-476. doi: 10.1080/14658011.2019.1664820 [9] SALAVAGIONE H J, MARTÍNEZ G, ELLIS G. Recent advances in the covalent modification of graphene with polymers[J]. Macromolecular Rapid Communications, 2011, 32(22): 1771-1789. doi: 10.1002/marc.201100527 [10] SUN Y B, YANG S B, CHEN Y, et al. Adsorption and desorption of U(VI) on functionalized graphene oxides: a combined experimental and theoretical study[J]. Environmental Science & Technology, 2015, 49(7): 4255-4262. [11] ASALDOUST S, RAMEZANZADEH B. Synthesis and characterization of a high-quality nanocontainer based on benzimidazole-zinc phosphate (ZP-BIM) tailored graphene oxides; A facile approach to fabricating a smart self-healing anti-corrosion system[J]. Journal of Colloid and Interface Science, 2020, 5(64): 230-244. [12] LI Y F, LIU J L, DENG J S, et al. Fabrication of graphene oxide reinforced plasma sprayed Al2O3 coatings[J]. Ceramics International, 2023, 49: 1667-1677. doi: 10.1016/j.ceramint.2022.09.129 [13] HAMID Z A, GOMAA M H, EL-HOUT S I, et al. α-Fe2O3/Fe3O4@GO nanosheets boost the functionality of Ni-P thin film deposited by electroless method[J]. Surface & Coatings Technology, 2023, 456: 129288. [14] LALA S R F, SRIVASTAVA C. Correlation Between Texture, Grain Boundary Constitution and Corrosion Behaviour of Copper-Chromium Coatings Containing Graphene Oxide[J]. Metallurgical and Materials Transactions A, 2023, 54A: 634-645. [15] BAGDE A, SHRIRAME S, BHANVASE B A, et al. Investigation on simultaneous enhancement in mechanical and anticorrosion performance of graphene oxide-zinc phosphate nanocomposite-based coatings[J]. Diamond & Related Materials, 2024, 144: 110960-. [16] 李智, 刘崇宇, 葛毓立等. 氧化石墨烯对纳米金属陶瓷复合镀层组织性能影响[J]. 表面技术, 2023, 52(10): 394-401.LI Zhi, LIU Chongyu, GE Yuli, et al. Effect of graphene oxide on microstructure and properties of nano-cermet composite coatings[J]. Surface Technology, 2023, 5(2): 1-13(in Chinese). [17] ZHANG Y H. Application of water-soluble polymer inhibitor in metal corrosion protection: Progress and challenges[J]. Frontiers in Energy Research, 2022, 10: 3389. [18] VAZIRINASAB E, JAFARI R, MOMEN G. Application of superhydrophobic coatings as a corrosion barrier: A review[J]. Surface & Coatings Technology, 2018, 341: 40-56. [19] ZHANG F Y, LIU W Q, LIANG L Y, et al. Applications of hydrophobic α, ω-bis(amino)-terminated polydimethylsiloxane) -graphene oxide in enhancement of anti-corrosion ability of waterborne polyurethane[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 600: 124981. doi: 10.1016/j.colsurfa.2020.124981 [20] WANG M J, WANG A, ZHAO W J, et al. The ion diffusion-directed self-assembled graphene oxide coating and its synergistic lubrication mechanism against environmental moisture[J]. Tribology International, 2024, 191: 109182-. doi: 10.1016/j.triboint.2023.109182 [21] GUO R T, LI W, WANG X Y, et al. Antimicrobial corrosion study of the epoxy coating with the graphene oxide supported Schiff base quaternary ammonium salt additives[J]. Materials Today Communications, 2023, 35: 105517. doi: 10.1016/j.mtcomm.2023.105517 [22] 李凤英, 鞠鹏飞, 陈磊等. 聚苯胺原位聚合改性氧化石墨烯制备复合涂层及其耐腐蚀性能研究[J]. 表面技术, 2021, 50(11): 287-296.LI Fengying, JU Pengfei, CHEN Lei, et al Preparation and corrosion resistance of polyaniline/ modified graphene oxide composite coating[J]. Surface Technology, 2021, 50 (11): 287-296(in Chinese). [23] ZHU X T, GAO Z S, LI F C, et al. Superlyophobic graphene oxide/polydopamine coating under liquid system for liquid/liquid separation, dye removal, and anti-corrosion[J]. Carbon, 2022, 190: 329-336. doi: 10.1016/j.carbon.2022.01.018 [24] GAUR M S, RAGHAV R K, SAGAR R, et al. Investigation of anticorrosion properties of epoxy GO nanocomposites spin coated aluminum alloy 7075[J]. Polymers and Polymer Composites, 2022, 30: 1-10. [25] DU X Q, LIU Y W, CHEN D C, et al. Co-electrodeposition of silane and graphene oxide on copper to enhance the corrosion protection performance[J]. Surface & Coatings Technology, 2022, 436: 128279. [26] PANG W T, JIANG H, WANG S, et al. Graphene oxides enhanced polyurethane based composite coating with long term corrosion resistance and self-healing property[J]. European Polymer Journal, 2024, 207: 112825. doi: 10.1016/j.eurpolymj.2024.112825 [27] 郭洪飞, 赵增祺, 朝宝等. 2-6二氨基吡啶改性氧化石墨烯复合涂层的制备及防腐性能[J]. 中国表面工程, 2022, 35(2): 126-139.GUO Hongfei, ZHAO Zengqi, CHAO Bao, et al. Preparation and anticorrosion performance of 2-6 diaminopyridine modified graphene oxide composite coating[J]. China Surface Engineering, 2022, 35(2): 126-139(in Chinese). [28] XUE B, YU M, LIU J, et al. Corrosion protection of AA2024-T3 by sol-gel film modified with graphene oxide[J] Journal of Alloys and Compounds, 2017, 725: 84-95. [29] PARHIZKAR N, RAMEZANZADEH B, SHAHRABI T. Corrosion protection and adhesion properties of the epoxy coating applied on the steel substrate pre-treated by a sol-gel based silane coating filled with amino and isocyanate silane functionalized graphene oxide nanosheets[J]. Applied Surface Science, 2018, 439: 45-59. doi: 10.1016/j.apsusc.2017.12.240 [30] 楠顶, 李鑫, 徐宇等. 硅烷偶联剂改性氧化石墨烯增强环氧树脂复合涂料的防腐性能[J]. 化学工业与工程, 2023, 40(6): 130-135.NAN Ding, LI Xin, XU Yu et al. Epoxy resin composite coating with silane coupling agent modified graphene oxide generating effective corrosion protection[J]. Chemical Industry and Engineering, 2023, 40(6): 130-135(in Chinese). [31] LI M M, ZHOU D N, ZHAO B F, et al. Simultaneously improved corrosion/wear resistances of epoxy coating on Mg alloy via the coupled hybridization of GO and nano-SiO2[J]. Diamond and Related Materials, 2022, 128: 109224. doi: 10.1016/j.diamond.2022.109224 [32] PRASETYA N B A, PUTRI M R, NGADIWIYANA, et al. Polyeugenol-gum arabic/graphene oxide composite coating for high performance anticorrosion material[J]. Case Studies in Chemical and Environmental Engineering, 2024, 9: 100658. doi: 10.1016/j.cscee.2024.100658 [33] DADKHAH S, GHARIEH A. UV-cured acrylated PANI/graphene oxide nanocomposite coating with superior anticorrosive protection and self-healing abilities[J]. Progress in Organic Coatings, 2024, 189: 108346. doi: 10.1016/j.porgcoat.2024.108346 [34] HUANG Y X, YANG S H, HU Y, et al. Construction of anticorrosive coatings with emergency response closure by introducing functionalized graphene oxide[J]. Chemical Engineering Journal, 2024, 487: 150539. doi: 10.1016/j.cej.2024.150539 [35] XIE C, ZHANG P, XUE M S, et al. Long-lasting anti-corrosion of superhydrophobic coating by synergistic modification of graphene oxide with polydopamine and cerium oxide[J]. Construction and Building Materials, 2024, 418: 135283. doi: 10.1016/j.conbuildmat.2024.135283 [36] WANG H H, YE M Y, WU J H, et al. Development of amine functionalized graphene oxide/fluorinated polyurethane topcoat with integrated anti-corrosion, anti-aging, and anti-bacterial performance[J]. Progress in Organic Coatings, 2024, 189: 108337. doi: 10.1016/j.porgcoat.2024.108337 [37] XU C A, CHU Z Z, LI X C, et al. Vanillin and organosilicon functionalized graphene oxide modified ester resin composite coatings with excellent anti-corrosion properties[J]. Progress in Organic Coatings, 2023, 183: 107804. doi: 10.1016/j.porgcoat.2023.107804 [38] SHU S S, WU L, LIU J M, et al. Synthesis and corrosion resistance of silane coupling agent modified graphene oxide/waterborne polyurethane [C] // National Defense Key Discipline Laboratory of Light Alloy Processing Science and Technology (Nanchang Hangkong University), Wuhan University of Science and Technology. Proceedings of 2019 5th International Conference on Applied Materials and Manufacturing Technology (ICAMMT 2019). IOP Publishing, 2019 (631): 022058. [39] WU H, CHENG L, LIU C B, et al. Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance[J]. Journal of Colloid and Interface Science, 2021, 587: 755-766. doi: 10.1016/j.jcis.2020.11.035 [40] XU C A, LIANG W Z, NI C L, et al. Silicone and nano-diamond modified graphene oxide anticorrosive coating[J]. Surface & Coatings Technology, 2024, 479: 130584. [41] ZHU J K, LI H, YANG Z Y, et al. CaIn2S4 nanosheets and SnO2 nanoflowers co-sensitized TiO2 nanotubes photoanode for continuous and efficient photocathodic protection of Q235 carbon steel[J]. Journal of Alloys and Compounds, 2024, 970: 172570. doi: 10.1016/j.jallcom.2023.172570 [42] 陈凡伟, 刘斌, 蹇冬辉, 等. 光生阴极保护技术的研究进展及其存在的问题[J]. 材料工程, 2021, 49(12): 83-90. doi: 10.11868/j.issn.1001-4381.2021.000469CHEN Fanwei, LIU Bin, JIAN Donghui, et al. Research progress and existing problems of photocathodic protection technology[J]. Journal of Materials Engineering, 2021, 49(12): 83-90(in Chinese). doi: 10.11868/j.issn.1001-4381.2021.000469 [43] HUANG W Q, CHAI Z L, ZHAO S R, et al. Design synthesis and excellent anti-corrosion property of GO/Mn-Zn2SiO4 composite materials[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 656: 130281. doi: 10.1016/j.colsurfa.2022.130281 [44] 陈廷廷, 李波, 张小龙等. GO/PANI改性环氧树脂@TiO2/CdS涂层的光生阴极保护性能[J]. 微纳电子技术, 2023, 60(8): 1211-1223.CHEN Ting-ting, Li Bo, Zhang Xiao-long, et al. P Photogenerated cathodic protection performance of GO/PANI modified epoxy resin@TiO2/CdS coating[J]. Micronanoelectronic Technology, 2023, 60(8): 1211-1223(in Chinese). [45] 李波, 何锦航, 余思伍等. TiO2/GO/EP复合涂层的光电化学防腐蚀性能研究[J]. 涂料工业, 2023, 53(1): 22-29+36. doi: 10.12020/j.issn.0253-4312.2022-194LI Bo, HE Jin-hang, YU Si-wu, et al. Study on photoelectrochemical corrosion protection performance of TiO2/GO/EP composite coating[J]. Paint & Coatings Industry, 2023, 53(1): 22-29+36(in Chinese). doi: 10.12020/j.issn.0253-4312.2022-194 [46] MA L W, WANG J K, ZHAO F T, et al. Plasmon-mediated photothermal and superhydrophobic TiN-PTFE film for anti-icing/deicing applications[J]. Composites Science and Technology, 2019, 181: 107696. doi: 10.1016/j.compscitech.2019.107696 [47] QIAN B, ZHENG Z L, MICHAILIDS M, et al. Mussel-inspired self-healing coatings based on polydopamine-coated nanocontainers for corrosion protection[J]. ACS Applied Materials & Interfaces, 2019, 10(11): 10283-10291. [48] MARINETTI S, VAVILOV V. IR thermographic detection and characterization of hidden corrosion in metals: general analysis[J]. Corrosion Science, 2010, 52(3): 865-872. doi: 10.1016/j.corsci.2009.11.005 [49] KHALILI P, CAWLEY P, The choice of ultrasonic inspection method for the detection of corrosion at inaccessible locations[J]. NDT & E International, 2018, 99: 80-92. [50] SILVA M Z, GUOYON R, LEPOUTRE F. Hidden corrosion detection in aircraft aluminum structures using laser ultrasonics and wavelet transform signal analysis[J]. Ultrasonics, 2003, 414: 301-305. [51] DU G, LI J, WANG W K, et al. Detection and characterization of stress-corrosion cracking on 304 stainless steel by electrochemical noise and acoustic emission techniques[J]. Corrosion Science, 2011, 53(9): 2918-2926. doi: 10.1016/j.corsci.2011.05.030 [52] TSANGOURI E, AGGELIS D G, TITTELBOOM K V, et al. Detecting the activation of a self-healing mechanism in concrete by acoustic emission and digital image correlation[J]. The Scientific World Journal, 2013, 2013: 424560. doi: 10.1155/2013/424560 [53] BUCHHEIT R G, GUAN H, MAHAJANAM S, et al. Active corrosion protection and corrosion sensing in chromate-free organic coatings[J]. Progress in Organic Coatings, 2003, 74(3-4): 174-182. [54] ZHELUDKEVICH M L, TEDIM J, FERREIRA M G S. “Smart” coatings for active corrosion protection based on multi-functional micro and nanocontainers[J]. Electrochimica Acta, 2012, 82: 314-323. doi: 10.1016/j.electacta.2012.04.095 [55] FUGOLIN A P P, FERRACANE J L, PFEIFER C S. “Fatigue-crack propagation behavior in microcapsule-containing self-healing polymeric networks”[J]. Materials & Design, 2022, 223: 111142. [56] EXBRAYAT L, SALALUK S, UEBEL M, et al. Nanosensors for monitoring early stages of metallic corrosion[J]. ACS Applied Energy Materials, 2019, 2(2): 812-818. [57] HU M H, PEIL S, XING Y W, et al. Monitoring crack appearance and healing in coatings with damage self-reporting nanocapsules[J]. Materials Horizons, 2018, 1: 51-58. [58] MAIA F, TEDIM J, BASTOS A C, et al. Nanocontainer-based corrosion sensing coating[J]. Nanotechnology, 2013, 24(41): 415502. doi: 10.1088/0957-4484/24/41/415502 [59] ZHENG X, WANG Q, LI Y, et al. Microcapsule-based visualization smart sensors for damage detection: principles and applications[J]. Advanced Materials Technologies, 2019, 52: 1900832. [60] LIU J G, HUANG W R, ZHANG K L, et al. Early warning and self-repair properties of o-phenanthroline modified graphene oxide anti-corrosion coating[J]. Progress in Organic Coatings, 2024, 189: 108274. doi: 10.1016/j.porgcoat.2024.108274 [61] PENG W T, JIANG H, WANG S, et al. Graphene oxides enhanced polyurethane based composite coating with long term corrosion resistance and self-healing property[J]. European Polymer Journal, 2024, 207: 112825. doi: 10.1016/j.eurpolymj.2024.112825 [62] LI Y F, NING C Y. Latest research progress of marine microbiological corrosion and bio-fouling, and new approaches of marine anti-corrosion and anti-fouling[J]. Bioactive Materials, 2019, 4: 189-195. doi: 10.1016/j.bioactmat.2019.04.003 [63] MELCHERS R E. Microbiological and abiotic processes in modelling longer-term marine corrosion of steel[J]. Bioelectrochemistry, 2014, 97: 89-96. doi: 10.1016/j.bioelechem.2013.07.002 [64] LI Z C, LIU P, CHEN S W, et al. Bioinspired marine antifouling coatings: Antifouling mechanisms, design strategies and application feasibility studies[J]. European Polymer Journal, 2023, 190: 111997. doi: 10.1016/j.eurpolymj.2023.111997 [65] LEONARDI A K, OBER C K. Polymer-based marine antifouling and fouling release surfaces: Strategies for synthesis and modification[J]. Annual Review of Chemical and Biomolecular Engineering, 2019, 10: 241-264. doi: 10.1146/annurev-chembioeng-060718-030401 [66] XIE Q Y, PAN J S, MA C F, et al. Dynamic surface antifouling: mechanism and systems[J]. Soft Matter, 2019, 6: 1087-1107. [67] BEYER J, SONG Y, TOLLEFSEN K E, et al. The ecotoxicology of marine tributyltin (TBT) hotspots: A review[J]. Marine Environmental Research, 2022, 179: 105689. doi: 10.1016/j.marenvres.2022.105689 [68] HU P, XIE Q Y, MA C F, et al. Silicone-based fouling-release coatings for marine antifouling[J]. Langmuir, 2022, 36: 2170-2183. [69] LI C, YANG J J, HE W J, et al. A review on fabrication and application of tunable hybrid micro-nano array surfaces[J]. 2023, 10: 3-17. [70] ZHEGN N, JIA B, WANG X J, et al. Multi- strategy combined bionic anti-fouling coating for long-term and stable protection against marine biofouling[J]. 2025, 210: 265-277. -
下载:
点击查看大图
计量
- 文章访问数: 34
- HTML全文浏览量: 18
- 被引次数: 0
