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基于碳纳米材料的肾上腺素电化学传感器研究进展

刘雪茹 金彪 孟龙月

刘雪茹, 金彪, 孟龙月. 基于碳纳米材料的肾上腺素电化学传感器研究进展[J]. 复合材料学报, 2022, 40(0): 1-14
引用本文: 刘雪茹, 金彪, 孟龙月. 基于碳纳米材料的肾上腺素电化学传感器研究进展[J]. 复合材料学报, 2022, 40(0): 1-14
Xueru LIU, Biao JIN, Longyue MENG. Research progress of adrenaline electrochemical sensors based on carbon nanomaterials[J]. Acta Materiae Compositae Sinica.
Citation: Xueru LIU, Biao JIN, Longyue MENG. Research progress of adrenaline electrochemical sensors based on carbon nanomaterials[J]. Acta Materiae Compositae Sinica.

基于碳纳米材料的肾上腺素电化学传感器研究进展

基金项目: 国家自然科学基金(22166034, 51703192, 22064017);吉林省科技厅主题引导项目(YDZJ202201 ZYTS542);延边大学创新团队项目
详细信息
    通讯作者:

    金彪,博士,副教授,硕士生导师,研究方向为分析化学 E-mail:jinbiao@ybu.edu.cn

    孟龙月,博士,副教授,博士生导师,研究方向为碳基材料的制备及其电化学传感器研究 E-mail:lymeng@ybu.edu.cn

  • 中图分类号: (TB33)

Research progress of adrenaline electrochemical sensors based on carbon nanomaterials

Funds: National Natural Science Foundation of China (22166034, 51703192, 22064017);Theme guidance project of Jilin Provincial Department of science and technology (YDZJ202201 ZYTS542), Yanbian University innovation Tean Project
  • 摘要: 肾上腺素(AD)作为一种神经递质在人体内扮演重要角色,其含量的高低直接影响人体身体健康,因此对AD进行快速检测具有重要的实际意义。其检测方法中电化学方法具有灵敏度高、检测速度快、操作简便的优点,因而构建性能优异的肾上腺素电化学传感器成为研究热点。为提高传感器的电化学性能,碳纳米材料被采纳作为修饰传感器的新型材料而广泛应用,取得了检测限低、灵敏度高并有希望应用于临床检测的巨大进步。本文从碳点、石墨烯、碳纳米颗粒等碳纳米材料出发,分析AD在电极表面的电氧化还原机制,对近年来基于碳纳米材料的肾上腺素电化学传感器制备方法及检测结果进行分类统计,并对今后的检测提出展望,以期获得更有效的肾上腺素电化学传感器。

     

  • 图  1  碳纳米材料及电化学应用示意图

    Figure  1.  Schematic diagram of carbon nanomaterials and electrochemical applications

    图  2  本论文的逻辑框架图

    Figure  2.  The logical framework of this paper

    图  3  肾上腺素在电极表面的电氧化还原机制

    Figure  3.  Electroredox Mechanism of Adrenaline on Electrode Surface

    图  4  石墨烯(GR)、氧化石墨烯(GO)、还原氧化石墨烯(RGO)的平面结构图

    Figure  4.  Planar structures of graphene (GR), graphene oxide (GO), and reduced graphene oxide (RGO)

    表  1   

    Table  1.   Performance comparison of electrochemical sensors based on carbon nanomaterials for the detection of adrenaline

    碳纳米复合材料检测方法线性范围 (μM)检测限(μM)实际样品文献
    GCE/C-dotsDPV50 - 2006.1Human urine[31]
    GQD-CS/CPESWV0.36 - 3800.3Blood serum32
    CQDs/CPECA0.02 - 200.006--33
    GCE/GQDs/LacCV1 - 1200.083EP injection34
    MIP/g-C3N4/NCQDs/GCEDPV0.001 - 10.0003Human urine35
    GNRs/GCEDPV6.4 - 1002.1Medicine38
    GR/BDDLSV1 - 101.44--39
    GR/Au/GCECV50 - 8007.0--40
    PBCB/GR/GCECV1 - 10000.24--41
    GR/CHIT/Bi2O3/GCEDPV0.1 - 0.50.00356--42
    GO/GCDPV1 - 1000.50 ± 0.01--50
    GO/CPEDPV0.1-20000.05--51
    EDDPT/GO/CPEDPV1.5 - 6000.65Drug sample52
    MGO/AuNPs/CPEDPV0.01 - 0.50.005Human urine/ Blood53
    rGO/GCEDPV0.015 - 400.003Human urine56
    RGO/TiO2/GCEDPV5 - 10001.4Medicine57
    NiO-rGO/GCECV50 - 1000101Human biology fluid82
    rGO/Pd/GCEDPV1 - 100.03--83
    MXene/N-rGODPV0.01 - 900.003Human urine60
    DH–CN/CPEDPV5 - 6001.0--64
    Nafion-OMC/GCIt0.1 - 12000.035--74
    OMC-NiO/GCECV,DPV0.8 - 500.085Human Serum /AD Injection75
    MWCNT/CFECV1 - 2003.4--78
    DOPA-MWCNT-GCEDPV2 - 460.62--79
    MgO-MWCNTs-MCPECV10 - 800.83--80
    IL/CNTPEDPV1 - 3501.0Serum/tablet/ urine82
    MIP/PIL-MWNTs/ITOCV0 - 0.20.0006--83
    POXMCNTPEDPV10 - 1100.031Ampoule84
    pyrolytic-CNTDPV0.16 - 800.65--85
    下载: 导出CSV
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出版历程
  • 收稿日期:  2022-04-25
  • 录用日期:  2021-06-20
  • 修回日期:  2021-05-30
  • 网络出版日期:  2022-06-29

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