基于纳米材料改善生物降解薄膜气体阻隔性的研究进展

殷飞翔; KAPAMBWE Bwalya; 林芷芊; 朱俊辉; 申梦洋; 谢丹; 贺枳椋; 戴进峰

doi:10.13801/j.cnki.fhclxb.20240401.003

基于纳米材料改善生物降解薄膜气体阻隔性的研究进展

doi: 10.13801/j.cnki.fhclxb.20240401.003

殷飞翔¹,
KAPAMBWE Bwalya¹,
林芷芊¹,
朱俊辉¹,
申梦洋¹,
谢丹^{1, 2, ,},
贺枳椋¹,
戴进峰^{1, 2, ,}

1.
浙江农林大学　化学与材料工程学院，杭州 311300
2.
浙江省木材科学与技术重点实验室，杭州 311300

基金项目: 国家自然科学基金青年项目(51903222)；国家级大学生创新创业训练计划项目(202210341055)；浙江农林大学人才引进启动基金资助项目(2017FR017)；浙江农林大学大学生科研训练项目(2021KX0035；2023KX029)；浙江农林大学人才引进启动基金资助项目(2023LFR134)

详细信息

通讯作者:
谢丹，博士，讲师，研究方向为新型高分子助剂开发与功能材料的制备　E-mail: 20230195@zafu.edu.cn

戴进峰，博士，副教授，硕士生导师，主要从事复合材料的高性能化和高分子材料无卤阻燃等研究　E-mail: jinfengdai0601@gmail.com

中图分类号: TB324；TB332
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出版历程
- 收稿日期: 2024-02-05
- 修回日期: 2024-03-12
- 录用日期: 2024-03-16
- 网络出版日期: 2024-04-02
- 刊出日期: 2024-10-15

Research progress on improving the gas barrier of biodegradable films using nanomaterials

1.
School of Chemical and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China
2.
Zhejiang Key Laboratory of Wood Science and Technology, Hangzhou 311300, China

Funds: National Natural Science Foundation Youth Project (51903222); National Undergraduate Innovation and Entrepreneurship Training Program Project (202210341055); Zhejiang A&F University Talent Introduction Startup Fund Aid Project (2017FR017); Zhejiang A&F University Undergraduate Research Training Program (2021KX0035; 2023KX029); Zhejiang A&F University Talent Introduction Startup Fund Aid Project (2023LFR134)

摘要

摘要: 传统塑料的大量使用及其废弃后无法降解给生态环境造成了严重污染，同时也给日益严峻的石化能源造成了巨大压力。薄膜材料是塑料的主要制品之一，其中生物降解薄膜因具有绿色环保、实现碳循环目标等优点，且能够在很大程度上改善全球环境污染和能源短缺的困境，被认为是当前薄膜发展的重要趋势。然而，生物降解薄膜也存在性能不理想、成本较高等问题，其较差的阻隔性更是限制了它在包装方面的应用。本文综述了纳米材料用于生物降解薄膜气体阻隔性的研究现状，主要从纳米材料的种类、组合方式以及生产纳米复合薄膜的加工方式三部分展开介绍，并对生物降解薄膜未来的研究发展做了展望。
- 生物降解 /
- 复合薄膜 /
- 纳米材料 /
- 碳循环 /
- 阻隔性
Abstract: The extensive use of traditional plastics and their non-degradable nature after disposal have led to severe pollution in the ecological environment and exerted enormous pressure on the increasingly critical petrochemical energy resources. Thin film material is one of the primary plastic products currently in application. The biodegradable films, known for their environmental friendliness and contribution to achieving carbon cycling goals, hold the potential to make substantial strides in mitigating global environmental pollution and addressing energy shortages. However, biodegradable films face challenges such as suboptimal performance and higher costs, with their poor barrier properties particularly limiting their application in packaging films. This article reviews the current research status of nanomaterials for enhancing the gas barrier properties of biodegradable films. The discussion is divided into three main parts: The types of nanomaterials, their combinations, and the processing methods for producing nanocomposite films. The article also provides insights into the future research and development of biodegradable films.
- biodegradable /
- composite films /
- nanomaterials /
- carbon recycling /
- barrier properties

HTML全文

图 1 (a)气体在聚合物中的渗透路径图解(路径1：纯聚合物的气体透过路径；路径2：纳米聚合物复合材料的气体透过路径)；(b)气体渗透弯曲度计算示意图

Figure 1. (a) Diagram of the permeation path of a gas in a polymer (Path 1: Permeation path of a pure polymer; Path 2: Gas permeability path of nanopolymer composites); (b) Schematic diagram of gas permeability bending calculation

n—Nanoplatelet normal unit vector; m—Permeation direction; θ—Orientation angle; L—Length

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图 2 (a)氧渗透性与碳纳米管(ChNT)体积含量的关系^[37]；(b)不同浓度纤维素纳米纤维(CNFs)对CNFs负载纳米复合材料的水蒸气透过率(WVTR)的研究^[38]；(c)聚己二酸/对苯二甲酸丁二酯(PBAT)/ZnO纳米复合薄膜的力学性能^[39]；(d) PBAT和PBAT/ZnO纳米复合薄膜在25℃时的氧渗透速率^[39]

Figure 2. (a) Relationship between oxygen permeability and the volume content of carbon nanotubes (ChNT)^[37]; (b) Study of water vapor transmission rate (WVTR) of different concentrations of cellulose nanofiber (CNFs) on CNFs-supported nanocomposites^[38]; (c) Mechanical properties of poly(butylene adipate-co-terephthalate) (PBAT)/ZnO nanocomposite films^[39]; (d) Oxygen permeation rate of PBAT and PBAT/ZnO nanocomposite films at 25℃^[39]

PLA—Polylactic acid

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图 3 (a)蒙脱土(MMT)纳米复合薄膜的双轴拉伸过程示意图^[47]；(b) PBAT/碳化钛(Ti₃C₂TX)纳米复合双轴拉伸膜的制备示意图^[48]；(c)单层层状双氢氧化物(LDH)纳米片制备工艺示意图^[49]；(d)用于防腐保护的两亲表面活性剂修饰的水滑石纳米片/聚二甲基硅氧烷(LDH-80/PDMS)_n薄膜在铝箔衬底上的组装工艺示意图^[52]

Figure 3. (a) Schematic diagram of the biaxial stretching process of montmorillonite (MMT) nanocomposite films^[47]; (b) Schematic diagram of the preparation of PBAT/titanium carbide (Ti₃C₂TX) nanocomposite biaxial stretch films^[48]; (c) Schematic diagram of the preparation process of single-layer layered double hydroxide (LDH) nanosheets^[49]; (d) Schematic diagram of the assembly process of hydrotalcite nanosheets/polydimethyloxysilicone (LDH-80/PDMS)_n films modified by amphiphilic surfactants for anti-corrosion protection on aluminum foil substrates^[52]

TCF—Thermo-compressed films; BOF—Biaxially oriented film; TA—Tannic acid

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图 4 (a)层层自组装(LBL)法制备聚二烯丙基二甲基氯化铵(氧化石墨烯)和聚乙烯醇(钠离子蒙脱土)(PDDA(GO)/PVA(Na⁺-MMT))薄膜的顺序和电键合制备的PDDA(GO)/PVA(Na⁺-MMT)薄膜的结构^[53]；(b)自组装沉积技术方案及得到的多层纳米结构的三维横截面图^[60]；(c)阳离子聚乙烯亚胺(PEI)、阴离子蒙脱土(MMT)和阴离子聚丙烯酸(PAA)组成的三层(TL)体系示意图^[61]；(d)具有机械和气体阻隔性能的二维层状蛭石(VMT)-PVA复合膜的形成过程示意图^[62]

Figure 4. (a) Structure of polydiallyl dimethylammonium chloride (graphene oxide) and polyvinyl alcohol (sodium ion montmorillonite) (PDDA(GO)/PVA(Na⁺-MMT)) films prepared by sequential and electrical bonding of PDDA(GO)/PVA(Na⁺-MMT) films prepared by layer self-assembly (LBL) method^[53]; (b) Self-assembly deposition technology scheme and three-dimensional cross-sectional diagram of the obtained multilayer nanostructures^[60]; (c) Schematic diagram of a three-layer (TL) system composed of cationic polyethylenimine (PEI), anionic montmorillonite (MMT) and anionic polyacrylic acid (PAA)^[61]; (d) Schematic diagram of the formation process of a vermiculite (VMT)-PVA composite film with mechanical and gas barrier properties^[62]

PEN—Polyethylene naphthalate; DI—Deionized DI; LLDPE—Linear low density polyethylene pellets

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图 5 (a)逐层沉积工艺示意图^[11]；(b)使用GO片作为带负电荷的材料和聚丙烯胺盐酸盐(PAH)作为带正电荷的聚电解质的旋转逐层组装过程示意图^[68]；(c)理论研究(上)和原理图(下)的剪切流诱导纳米薄片在超铺展过程中的对准机制示意图^[69]；(d)连续离心铸造(CCC)示意图^[70]

Figure 5. (a) Schematic diagram of layer-by-layer deposition process^[11]; (b) Schematic diagram of rotational layer-by-layer assembly process using GO sheet as negatively charged material and polyacrylamine hydrochloride (PAH) as positively charged polyelectrolyte^[68]; (c) Schematic diagram of the alignment mechanism of shear-flow-induced nanosheets during superspreading for theoretical study (top) and schematic diagram (bottom)^[69]; (d) Schematic diagram of continuous centrifugal casting (CCC)^[70]

H—Height of the droplet; R—Radius of the droplet

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