石墨烯导热测试方法、影响因素及其应用研究进展

Research progress on testing methods, influencing factors and applications of graphene thermal conductivity

  • 摘要: 石墨烯以其独特的结构和优异的导热性能引起研究者的广泛关注。石墨烯作为一种具有较高热导率的二维材料,在含能材料、电池材料、导热复合材料等领域都有重要应用。石墨烯导热的理论和实验研究有助于加强对固体导热机制的理解,可以为能源技术、电子器件热管理和散热技术的发展及高效导热材料的设计提供参考。近年来,有较多关于石墨烯热导率的报道,对石墨烯热导率报道进行总结有利于相关研究人员更好地开展工作。本文对石墨烯热导率的测试方法、影响因素及应用现状进行了总结。首先介绍单层石墨烯、少层和多层石墨烯及石墨烯基复合材料热导率测试方法,包括拉曼光谱法、热桥法、激光闪射法和3ω法。然后总结石墨烯热导率的理论研究成果,介绍石墨烯本征热导率的影响因素,如尺寸、层数和缺陷等对热导率的影响。随后归纳总结石墨烯导热材料在含能材料、电池材料和改性复合材料中的应用情况。最后,对石墨烯导热的研究进行了总结,提出目前石墨烯导热研究中的问题和挑战,并且对未来可能的发展方向作出展望。

     

    Abstract: Graphene has attracted much attention due to its unique structure and excellent thermal conductivity, which is widely used in energy materials, battery materials, thermal composite materials fields as a two-dimensional material with high thermal conductivity. It is of great significance to deepen the understanding of solid-state heat transfer mechanisms by theoretical and experimental research on the thermal conductivity of graphene, and it can guide the design of the development of energy technology, thermal management and heat dissipation technology of electronic devices and the high-efficiency thermal conductivity materials. In recent years, there are numerous reports on the thermal conductivity of graphene, and it is beneficial for researchers to carry out their work more effectively by summarizing these reports on the thermal conductivity of graphene. This work summarizes the testing methods, influencing factors, and application status of the thermal conductivity of graphene. Firstly, the thermal conductivity measurement methods of single-layer, few-layer and multilayer graphene and graphene matrix composites are introduced, including Raman spectroscopy, thermal bridge, laser flash and 3ω method. Then, the theoretical research achievements on the thermal conductivity of graphene was summarized and the influence factors of the intrinsic thermal conductivity of graphene such as size, number of layers and defects were discussed. Next, the application of graphene as a thermal conductor in energy materials, battery materials and modified composite materials is summarized. Finally, the research on graphene's thermal conductivity is concluded and the current challenges and issues was highlighted in graphene's thermal conductivity research. Moreover, the prospect for future development direction is proposed.

     

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