仿生生物质基胶黏剂研究进展

罗晶; 李任杰; 马睿; 陈琳钰; 周莹; 曾国栋; 高强; 郭永胜

doi:10.13801/j.cnki.fhclxb.20230926.004

仿生生物质基胶黏剂研究进展

doi: 10.13801/j.cnki.fhclxb.20230926.004

罗晶¹,
李任杰¹,
马睿¹,
陈琳钰¹,
周莹¹,
曾国栋¹,
高强³,
郭永胜^2, ,

1.
南京林业大学　材料科学与工程学院，南京 210037
2.
山东千森木业集团有限公司，临沂 273400
3.
北京林业大学　材料科学与技术学院，北京 100083

基金项目: 国家自然科学基金青年科学基金项目(31901255)；山东省重点研发计划(重大科技创新工程)，山东省碳达峰碳中和专项“绿色宜居”科技示范工程-高性能新型木质新材料低碳制造关键技术研发与产业化(2021 SFGC0203)；江苏省研究生科技创新项目 (KYCX22_1086)；南京林业大学引进高层次和高学历人才留学回国人员科研启动基金(163020127)

详细信息

通讯作者:
郭永胜，硕士，硕士生企业导师，研究方向为木质复合材料与胶黏剂　E-mail: guoyongsheng2022@163.com

中图分类号: TQ432；TQ430.3；TB332
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- 被引次数: 0
出版历程
- 收稿日期: 2023-06-29
- 修回日期: 2023-08-18
- 录用日期: 2023-09-11
- 网络出版日期: 2023-09-27
- 刊出日期: 2024-02-01

Research progress of biomimetic biomass-based adhesives

1.
College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
2.
Shandong Qiansen Wood Industry CO., LTD., Linyi 273400, China
3.
College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China

Funds: National Natural Science Foundation of China (31901255)；Key Research and Development Program of Shandong Province (Major Scientific and Technological Innovation Project), Shandong Province Carbon Peak and Carbon Neutrality Special Project "Green Livable" Technology Demonstration Project - Research and Industrialization of Key Technologies for Low-carbon Manufacturing of High-performance New Wood-based Materials (2021 SFGC0203)；Postgraduate Research & Practice Innovation Program of Jiangsu Province (KYCX22_1086)；Scientific Research Start-up Funds of Nanjing Forestry University (163020127)

摘要

摘要: 目前以石油化工产物为主要原料的工业用合成树脂胶黏剂占市场主导地位，不可持续发展，并且在其合成和使用过程中释放有机挥发物，带来环境污染问题。利用可再生生物质资源开发环保胶黏剂具有重大研究意义和发展前景。但生物质胶黏剂普遍存在黏度大、施胶性能差、耐水性差、产品稳定性差等缺点制约其实际应用。对此，广大研究者采用物理化学手段进行改性研究，以提高胶黏剂胶接和使用性能，其中受自然界启发，利用仿生手段改性胶黏剂是研究热点之一。本文综述了仿生改性在大豆蛋白胶黏剂、木质素胶黏剂、单宁胶黏剂、糖基胶黏剂的研究进展，探讨了生物质胶黏剂仿生改性研究前景，并对其应用进行展望，以期对生物质胶黏剂改性和性能提高提供研究思路和方法，推动生物质胶黏剂的规模化应用。
- 仿生 /
- 大豆蛋白胶黏剂 /
- 木质素胶黏剂 /
- 单宁胶黏剂 /
- 糖基胶黏剂 /
- 改性研究
Abstract: Currently, industrial synthetic resin adhesives, which mainly use petroleum-based chemicals as raw materials, dominate the market. However, their unsustainable development and the release of volatile organic compounds during synthesis and application lead to environmental pollution. Therefore, it is of significant research significance and development prospects to develop environmentally friendly adhesives using renewable biomass resources. However, biomass-based adhesives generally suffer from high viscosity, poor adhesive performance, low water resistance, and poor product stability, which limit their practical application. To address these issues, researchers have used physical and chemical methods to modify these adhesives, aiming to improve their bonding and usage performance. Inspired by nature, the use of biomimetic approaches to modify adhesives is one of the hotspots in research. This article reviews the research progress on biomimetic modification of soy protein adhesives, lignin adhesives, tannin adhesives, and polysaccharide adhesives, discusses the research prospects of biomimetic modification of biomass-based adhesives, and provides an outlook on their applications. These efforts aim to provide new ideas and methods for the modification and performance improvement of biomass-based adhesives and promote their large-scale application.
- biomimic /
- soy protein adhesives /
- lignin adhesives /
- tannin adhesives /
- saccharide-based adhesives /
- modification research

HTML全文

图 1 大豆蛋白(SP)-多巴胺功能化聚氨酯(D-PU)的合成过程及SP-D-PU树脂的内部微观结构和相互作用^[28]

Figure 1. Description for the synthetic procedure of the soy protein (SP)-dopa-polyurethane (D-PU) and the interior microstructure and interactions within the SP-D-PU resin^[28]

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图 2 仿生大豆蛋白胶黏剂制备流程图^[29]

CS-DA—Chitosan-dihydroxybenzaldehyde; Ag NPs—Agnanoparticle;

Figure 2. Diagram of preparation of bionic soybean protein adhesive^[29]

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图 3 纸纤维(PF) (a)、羧基纸纤维(CPF) (b) 和 UiO66-NH₂@CPF (c)的SEM图像； (d) UiO66-NH₂@CPF宏观形态；(e) Zr元素分布图；(f) UiO66-NH₂的SEM图像^[41]

Figure 3. SEM images of paper fiber (PF) (a), carboxyl paper fibers (CPF) (b) and UiO66-NH₂@CPF (c); (d) Macromorphology of UiO66-NH₂@CPF;(e) Element mapping of Zr; (f) SEM image of UiO66-NH₂^[41]

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图 4 壁虎仿生大豆蛋白胶黏剂(SP)/白藜芦醇基环氧化物(RE)/UiO66-NH₂@CPF增强机制图^[41]

F—Force

Figure 4. Strengthening mechanism of SP/resveratrol epoxide (RE)/UiO66-NH₂@CPF adhesive^[41]

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图 5 仿生胶黏剂模型化合物3-甲氧基-4-羟基苯基丙烷(LMG)羟甲基化和马来化示意图^[52]

Figure 5. Schematic illustration of hydroxymethylation and maleation of model compound 3-methoxy-4-hydroxyphenylpropane (LMG)^[52]

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图 6 缩合单宁类黄酮和多巴胺化学结构图^[69]

Figure 6. Flavonoid units in condensed tannins and the chemical structure of dopa^[69]

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图 7 仿贻贝胶黏剂合成机制图^[71]

Figure 7. Mussel-inspired design strategy for adhesive preparation^[71]

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图 8 羧基淀粉和多巴淀粉的合成机制图^[84]

DMSO—Dimethyl sulfoxide

Figure 8. Synthesis scheme of Starch-COOH and Starch-dopa^[84]

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图 9 果聚糖儿茶酚凝胶(LC)合成机制^[87] (果聚糖(上)、多巴胺(中)和LC(下))

Figure 9. Synthesis of levan-catechol (LC)^[87] (Levan (top), dopamine (middle) and LC (bottom))

下载: 全尺寸图片幻灯片

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