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纤维增强环氧/乙烯基树脂复合材料性能优化与劣化机制研究进展

曹银龙 于桢琪 冯鹏 李荣 张鹏 张少杰 鲍玖文

曹银龙, 于桢琪, 冯鹏, 等. 纤维增强环氧/乙烯基树脂复合材料性能优化与劣化机制研究进展[J]. 复合材料学报, 2024, 41(3): 1179-1191. doi: 10.13801/j.cnki.fhclxb.20230914.002
引用本文: 曹银龙, 于桢琪, 冯鹏, 等. 纤维增强环氧/乙烯基树脂复合材料性能优化与劣化机制研究进展[J]. 复合材料学报, 2024, 41(3): 1179-1191. doi: 10.13801/j.cnki.fhclxb.20230914.002
CAO Yinlong, YU Zhenqi, FENG Peng, et al. Performance optimization and deterioration mechanism of fiber reinforced epoxy/vinyl resin composite materials: A review[J]. Acta Materiae Compositae Sinica, 2024, 41(3): 1179-1191. doi: 10.13801/j.cnki.fhclxb.20230914.002
Citation: CAO Yinlong, YU Zhenqi, FENG Peng, et al. Performance optimization and deterioration mechanism of fiber reinforced epoxy/vinyl resin composite materials: A review[J]. Acta Materiae Compositae Sinica, 2024, 41(3): 1179-1191. doi: 10.13801/j.cnki.fhclxb.20230914.002

纤维增强环氧/乙烯基树脂复合材料性能优化与劣化机制研究进展

doi: 10.13801/j.cnki.fhclxb.20230914.002
基金项目: 国家自然科学基金(U2106219;51922052;52378247);山东省自然科学基金(ZR2021JQ17);山东省高等学校青创科技计划创新团队(2021KJ019);山东省大学生创新创业训练计划资助项目(S202210429012)
详细信息
    通讯作者:

    鲍玖文,博士,副教授,博士生导师,研究方向为土木工程材料耐久性 E-mail: baojiuwen@qut.edu.cn

  • 中图分类号: TU532+.1;TB332

Performance optimization and deterioration mechanism of fiber reinforced epoxy/vinyl resin composite materials: A review

Funds: National Natural Science Foundation of China (U2106219; 51922052; 52378247); Natural Science Foundation of Shandong Province (ZR2021JQ17); Youth Innovation Team Development Plan of Shandong Province in China (2021KJ019); Undergraduate Innovation and Entrepreneurship Training Program Funding Project (S202210429012)
  • 摘要: 纤维增强聚合物(FRP)复合材料具有轻质高强、耐腐蚀、经济效益高的优势,在基础建设施设中表现出巨大潜力,但在复杂环境下长期服役后,FRP复合材料的力学性能下降超过50%,限制了其在工程中的应用。基于此,针对FRP复合材料各组分优化设计方法进行了总结,并分析了热氧、紫外线、腐蚀介质环境中FRP复合材料的长期性能演化规律;根据化学结构及微观形貌分析,阐述了FRP复合材料在复杂环境中的劣化机制,进一步归纳了其在复杂环境下的长期性能预测模型,可为保证FRP复合材料在复杂环境中的长期使用性能提供理论依据,促进其在实际工程中的应用。

     

  • 图  1  纤维优化机制:(a) 化学刻蚀;(b) 偶联剂改性;(c) 偶联剂改性刻蚀纤维机制

    Figure  1.  Enhancements of fibers: (a) Chemical etching; (b) Modification of coupling agent; (c) Mechanism of etched fiber modified with coupling agent

    图  2  纳米材料与纤维的界面形貌[12]

    Figure  2.  Interface morphology between nano material and fiber[12]

    图  3  树脂分子结构及相应性能:(a) 环氧树脂分子结构;(b) 乙烯基树脂分子结构

    Figure  3.  Corresponding performance of resin with molecular structure: (a) Molecular structure of epoxy resin; (b) Molecular structure of vinyl resin

    图  4  改性纳米材料增强树脂机制: (a) 纳米材料表面改性;(b) 纳米材料改性树脂基体

    Figure  4.  Enhancement mechanism of resin improved by modified nanomaterials: (a) Modification on surface of nanomaterials; (b) Resin matrix modified with nanomaterials

    图  5  不同温度下纤维增强聚合物(FRP)复合材料强度保留率与老化时间关系[29-30]

    Figure  5.  Relationship between strength retention rate of fiber reinforced polymer (FRP) composite and aging time at different temperature [29-30]

    图  6  热氧老化后FRP复合材料微观形貌[28]

    Figure  6.  Microstructure of FRP after thermal oxygen aging[28]

    图  7  紫外线老化后混合FRP的断裂特征[34]

    Figure  7.  Fracture characteristics of FRP combined with different fibers after UV aging[34]

    图  8  水(a)和碱性溶液 ((b)~(c))中FRP复合材料劣化模式[62]

    Figure  8.  Deterioration mode of FRP composites in water (a) and alkaline solution ((b)-(c))[62]

    图  9  碱溶液中FRP复合材料劣化机制:(a) 硅氧键反应过程;(b) 树脂降解机制

    Figure  9.  Deterioration mechanism of FRP composites in alkali solution: (a) Reaction of silicon-oxygen bond; (b) Degradation mechanism of resin

    图  10  FRP长期性能分析:(a) 温度与降解速率的关系;(b) 服役时间与强度保留率的关系[77]

    Figure  10.  Long-term properties of FRP: (a) Relationship between temperature and degradation rate; (b) Between service time and strength retention[77]

    SBSS—Short beam shear strength

    表  1  FRP复合材料力学性能特征预测模型

    Table  1.   Features of mechanical properties prediction models of FRP composites

    Number Document Predicting value Prediction model Annotation
    1 [63] Porosity of composites, $ {{P}}_{\text{s}} $ $ \alpha=\dfrac{29.92}{t+13}+\dfrac{0.75}{t+0.48}P_{\mathrm{s}}+0.12P_{\mathrm{s}}^2 $ $ \alpha $ is the ultrasonic attenuation coefficient; $ {t} $ is the thickness of the FRP composite.
    2 [64] Strength of the composite at porosity $v $, $ {\sigma }_{{\mathrm{pre}}\left(v\right)} $ $ \sigma_{\rm{pre}} (v)=\sigma_{0(0)} \mathrm{e}^{-a_2 v}$ $ {\sigma }_{\text{0(0)}} $ is the strength of the composites when the porosity is 0; v is the porosity; b, a1, a2 are the coefficients, respectively.
    3 [65] $ \sigma_{\text {pre }(v)}=\sigma_{0(0)}-\dfrac{1}{1-a_1+a_1 \mathrm{e}^{b v}} $
    4 [66] Tensile strength of the composite, $ {\sigma }_{\text{cu}} $ $ \sigma_{{\mathrm{c u}}}=C_{{\mathrm{o s}}} \eta_{{\mathrm{1 s}}} \varPhi_{\mathrm{f}} \sigma_{{\mathrm{fu}}}+\sigma_{{{\mathrm{mu}}}}\left(1-\varPhi_{\mathrm{f}}\right) $ $ {{C}}_{\text{os}} $ is the fiber orientation coefficient; $ {\eta }_{\text{1}\text{s}} $ is the fiber length effective factor; $ {\sigma}_{\text{mu}} $ is the tensile strength of resin matrix; $ {\varPhi}_{\text{f}} $ is the fiber volume fraction; σfu is the tensile strength of fibers.
    5 [68] Elasticity modulus of FRP composites, $ {{E}}_{\text{a}} $ $ \dfrac{E_{\rm {a}}}{E_{\rm {m}}}=\dfrac{1+V_{\rm{f}}}{1-1.25 V_{\rm{f}}+4.3\left(E_{\rm{m}}/ E_{\rm{f}}\right) V_{\rm{f}}} $
    $ \sigma_{\mathrm{c}}=\left(1-d_{\mathrm{c}}\right) E_{\mathrm{a}} \varepsilon_0$
    $ {{E}}_{\text{m}} $ is the elasticity modulus of resin matrix; $ {{E}}_{\text{f}} $ is the elasticity modulus of fibers; $ {{V}}_{\text{f}} $ is the volume fraction of fibers; $ \sigma_{\mathrm{c}} $ is the strength of composites; $ {d}_{{\mathrm{c}}} $ is the damage factor; $ {\varepsilon }_{0} $ is the strain of composites.
    下载: 导出CSV

    表  2  FRP复合材料长期性能预测模型

    Table  2.   Features of long-term performance prediction models of FRP composites

    Number Document Predicting value Prediction model Annotation
    1 [72] Tensile strength retention rate, $ \mathit{{Y}} $ $ Y =100\left(1-\dfrac{\sqrt{2 D_0 C_t}}{r_0}\right)^2 $
    $ \dfrac{M_t}{M_{\infty}} =1-\exp \left[7.3\left(\dfrac{D_0 t}{h^2}\right)^{0.75}\right]$
    $ {D}_{0} $ is the diffusion coefficient; $ {{C}}_{{t}} $ is the ion concentration of solution; $ {{r}}_{\text{0}} $ is the radius of the composites; $ {{M}}_{{t}} $ is the hygroscopicity of the FRP composites at time t; $ {{M}}_{\text{∞}} $is the saturated hygroscopicity; $ {h} $ is the thickness of material.
    2 [74] Alculated diffusion coefficients after long-term aging, $ {D}_{{\mathrm{{\mathrm{c}}}}} $ $ {D}_{{\mathrm{c}}}={D}_{0}{{\mathrm{e}}}^{-\dfrac{{E}_{{\mathrm{a}}}}{RT}} $ $ {{E}}_{\text{a}} $ is the activation energy; $ {R} $ is the universal gas constant; $ {T} $ is the absolute temperature.
    3 [75] Deterioration rate, K $K = A{\rm{exp}}\left( {\dfrac{{ - {E_{\rm{a}}}}}{{RT}}} \right) $ A is a constant.
    4 [76] Temperature time-shift factor, $ \mathrm{TSF} $ $ \mathrm{TSF}=\exp\left[\dfrac{E_{\mathrm{a}}}{R}\left(\dfrac{1}{T_0}-\dfrac{1}{T_1}\right)\right] $ $ {{T}}_{\text{0}} $, $ {{T}}_{\text{1}} $ are the ambient temperature, respectively.
    5 [77] Temperature-corrected time-shift factor, η $\eta=\dfrac{12}{\sum_1^{12} \exp \left[{E_{\mathrm{a}}}/{{R}}\left({1}/{T_{{\mathrm{A T}}}}-{1}/{T_{{\mathrm{M T}}}}\right)\right]}$ $ {{T}}_{\text{AT}} $ is the average annual temperature; $ {{T}}_{\text{MT}} $ is the average monthly temperature.
    6 [76] Design value of tensile strength, $ {f}_{{\rm{ftd}}} $ $ {\mathrm{E R F}}=1-\beta\left[\varDelta_1-\rho \lg \left(\dfrac{{\mathrm{D L}}}{\alpha \cdot {\mathrm{T S F}} \cdot \eta}\right)\right]$
    $ {{f}}_{\text{ftd}}\text{=}{{f}}_{\text{ftd}}\text{}{{\mathrm{ERF}}} $
    $ {{\mathrm{ERF}}} $ is the environmental factor; $ \beta $ is the correction factor of FRP composites; $ \alpha $is the correction factor of normal FRP composite; $ \varDelta _{\text{1}} $the strength decay rate of composites after one year exposure; $ \rho $is the slope of the linear regression of Arrhenius' formula; DL is design life in years.
    7 [78] Strength retention rate, Yt ${Y_t} = (100 - {Y_\infty }){\rm{exp}}\left( {\dfrac{{ - t}}{\tau }} \right) + Y $ t is the exposure time; $ \tau $ is the fitting parameter; Y is the strength retention of the composite when the exposure time is infinity.
    下载: 导出CSV
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  • 收稿日期:  2023-06-25
  • 修回日期:  2023-08-22
  • 录用日期:  2023-09-04
  • 网络出版日期:  2023-09-15
  • 刊出日期:  2024-03-01

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