纤维素材料的改性与研究进展

何江; 王大威

doi:10.13801/j.cnki.fhclxb.20220314.001

纤维素材料的改性与研究进展

doi: 10.13801/j.cnki.fhclxb.20220314.001

何江,
王大威^,

武汉工程大学　材料科学与工程学院，武汉 430205

详细信息

通讯作者:
王大威，博士，副教授，硕士生导师，研究方向为智能医用材料、柔性功能材料、生物降解材料　E-mail: wangdawei@wit.edu.cn

中图分类号: TQ352.7
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- 被引次数: 0
出版历程
- 收稿日期: 2022-01-10
- 修回日期: 2022-02-18
- 录用日期: 2022-03-07
- 网络出版日期: 2022-03-15
- 刊出日期: 2022-07-30

Modification and research progress of cellulose materials

HE Jiang,
WANG Dawei^,

School of Materials Science & Engineering , Wuhan Institute of Technology , Wuhan 430205, China

摘要

摘要: 纤维素具有来源广泛、绿色可再生、生物相容性好等诸多优点，但是纤维素由于热塑性能差、亲水性过强及机械强度不足等问题难以作为单一材料应用于生产生活中。从纤维素材料的增塑改性、疏水改性与增强改性三方面出发，对现阶段国内外开展的纤维素改性研究工作的进展进行了论述与分析，并对纤维素基材料的未来研究方向和研究重点进行了展望。
- 纤维素 /
- 增塑改性 /
- 疏水改性 /
- 增强改性 /
- 可再生
Abstract: There are many advantages in cellulose such as extensive sources, recyclability, good biocompatibility, etc. However, it is difficult to be used individually because of poor thermoplastic properties, excessive hydrophilicity and insufficient mechanical strength. The research progress of cellulose modification at home and abroad are discussed and analyzed from plasticization modification, hydrophobic modification and reinforcement modification of cellulose materials, as well as research focus and development direction of cellulose-based materials are prospected in future.
- cellulose /
- plasticization modification /
- hydrophobic modification /
- enhanced modification /
- recyclability

HTML全文

图 1 纤维素材料的改性方向及方法

Figure 1. Modification directions and methods of cellulose materials

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图 2 增塑剂增塑改性示意图：(a)未加入增塑剂；(b) 增塑剂进入纤维素非结晶区； (c) 增塑剂进入纤维素结晶区； (d) 纤维素结晶区消失；(e) 纤维素链段迁移

Figure 2. Schematic diagram of a plasticizing modification of plasticizer: (a) No plasticizer added; (b) Plasticizer enters the non-crystalline area; (c) Plasticizer enters crystalline area; (d) Crystalline area disappears; (e) Cellulose chain stretches

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图 3 不同增塑剂处理后的纤维素薄膜

Figure 3. Cellulose film treated with different plasticizers

G—Glycerin; S—Sorbitol

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图 4 由再生纤维素合成热塑性纤维素接枝聚氨酯的原理图

Figure 4. Schematic diagram of the synthesis of thermoplastic cellulose grafted polyurethane from regenerated cellulose

PCL—Polycaprolactone; HDI—Hexamethylene diisocyanate; RC—Regenerated cellulose; DMSO—Deuterated dimethyl sulfoxide; PU—Polyurethane

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图 5 纤维素吸湿机制图

Figure 5. Cellulose moisture absorption mechanism

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图 6 甘蔗渣纤维素纤维的吸附机制图

Figure 6. Adsorption mechanism of bagasse cellulose fiber

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图 7 柠檬酸改性纤维素纳米晶

Figure 7. Citric acid modified cellulose nanocrystals

CNC—Cellulose nanocrystals; LNP—Lignin nanoparticles

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图 8 木质纤维素/磷酸氢钙复合材料合成图

Figure 8. Synthesis diagram of lignocellulose/calcium hydrogen phosphate composite material

DNLC—Delignified nano-lignocellulose

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图 9 TEMPO-CNF薄膜双交联过程的示意图

Figure 9. Schematic diagram of the double crosslinking process of TEMPO-CNF film

TEMPO—2,2,6,6-Tetramethylpiperidine-1-oxy-oxidized; ECH—Epichlorohydrin

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