Preparation and application of cellulose-based metal nanoparticles composite catalysts
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摘要: 纤维素是一种来源广泛、比表面积大、多羟基且环境友好型的生物高分子材料，其水悬浮液可形成三维网络缠结结构，从而为具有催化活性的金属纳米粒子提供负载位点，使其均匀分散并固定于基底内部或表面构建复合催化剂材料，进而有效提高催化性能。本文综述了纤维素基金属纳米粒子复合催化剂的制备及应用的相关研究，重点介绍了不同纤维素基材料作为基底制备金属纳米粒子复合催化剂的方法及其优缺点，归纳了金属纳米粒子在纤维素基材料中的负载途径及原理，重点阐述了纤维素基材料在复合催化剂中的主要作用，最后对纤维素基材料在金属纳米粒子复合催化剂领域的研究工作进行了总结与展望，为纤维素基复合催化剂材料的制备和应用提供参考。Abstract: Cellulose is the most abundant organic polymer in nature, with many advantages like broad resource of raw material, large specific surface area, abundant hydroxyl groups and environmentally friendly. Besides, cellulose can form three-dimensional network structure in aqueous suspension, which provides loading sites for metal nanoparticles to make them disperse well and binds well with cellulose and prepares the composite catalysts with improved catalytic performance. Herein, the preparation and application of cellulose-based composite catalysts with metal nanoparticles were summarized, the methods and merits of the composite catalysts with various cellulosic materials were highlighted. Furthermore, the loading methods and principles of metal nanoparticles were generalized, and the main functions of cellulosic materials in composite catalysts were elaborated. Finally, the researches of cellulose-based composite catalysts with metal nanoparticle were summarized. This work can be a reference for the preparing and applying of cellulosic composite catalysts.
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Key words:
- cellulose /
- metal nanoparticles /
- load /
- composite catalysts /
- catalytic performance
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图 2 纤维素纤维(CF)基金属纳米粒子(NPs)复合催化剂合成路线示意图 (a)、加入催化剂后在不同反应时间下催化4-硝基苯酚(4-NP)降解的UV-vis (b) 及ln(At/A0)与反应时间t在400 nm处的关系 (c)[47]
Figure 2. Synthesis route of cellulose fiber (CF)-based metal nanoparticles (NPs) composite catalyst (a), UV-vis absorption spectra of 4-nitrophenol (4-NP) after adding the composite catalyst at different time (b) and ln(At/A0) versus reaction time (at 400 nm) (c)[47]
BTC—1,3,5-Benzenetricarboxylic acid; CCF—Carboxymethyl cellulose fiber; MOF—Metal-organic frame materials; A0—Absorbance of the mixture at the initial moment of reaction; At—Absorbance at 400 nm (4-NP) after reaction time t
图 4 纳米纤维素晶体(CNC)基NPs复合催化剂的制备流程图 (a)、不同时间下催化4-NP降解的紫外-可见光谱与At/A0 (b) 及ln(At/A0) (c) 随时间变化图[64]
Figure 4. Schematic of preparation of crystal nanocellulose (CNC)-based NPs composite catalyst (a), UV-vis absorption spectra after adding the composite catalyst at different time (b) and In(At/A0) versus reaction time (at 400 nm) (c)[64]
图 6 纳米纤维素纤维(CNF)基纳米复合催化剂的制备流程图 (a)、Pd NPs@纤维素海绵(CS)在芳基卤化物与芳基硼酸的交叉耦合反应中的催化活性 (b) 及可回用性 (c)[75]
Figure 6. Schematic of preparation of cellulose nanofibers (CNF) based mental nanoparticles composite catalyst (a), catalytic performance (b) and recyclability (c) of Pd NPs@cellulose sponge (CS) in the cross-coupling reaction between aryl halide and aryl boric acid[75]
GPTMS—γ-(2,3-Epoxypropoxypropyl) propyl trimethoxy silane
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