MXene与纤维基材料复合应用研究进展

杨开勋; 张吉振; 谭娅; 方剑

doi:10.13801/j.cnki.fhclxb.20210805.005

MXene与纤维基材料复合应用研究进展

doi: 10.13801/j.cnki.fhclxb.20210805.005

杨开勋^{1, 2,},
张吉振^3,,
谭娅^{1, 2},
方剑^{1, 2, ,}

1.
苏州大学　纺织与服装工程学院，苏州 215021
2.
苏州大学　现代丝绸国家工程实验室，苏州 215123
3.
迪肯大学　前沿材料研究所，维多利亚 3216

详细信息

通讯作者:
方剑，教授，博士生导师，研究方向为电活性纤维材料和柔性智能可穿戴纺织品　E-mail：jian.fang@suda.edu.cn

中图分类号: TS102.6
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- 被引次数: 0
出版历程
- 收稿日期: 2021-05-31
- 修回日期: 2021-06-26
- 录用日期: 2021-07-16
- 网络出版日期: 2021-08-05
- 刊出日期: 2022-02-01

Research progress of MXene/fibrous material composites

YANG Kaixun^{1, 2
,},
ZHANG Jizhen^3
,,
TAN Ya^{1, 2},
FANG Jian^{1, 2
, ,}

1.
College of Textile and Clothing Engineering, Soochow University, Suzhou 215021, China
2.
National Engineering Laboratory for Modern Silk , Soochow University, Suzhou 215123, China
3.
Institute for Frontier Materials, Deakin University, Victoria 3216, Australia

摘要

摘要: 层状过渡金属碳/氮化物(MXene)是一种新兴的二维纳米材料。由于其独特的纳米结构和优异的电学性能，MXene在电学相关领域的潜在应用受到越来越多的关注。近年来，有众多研究将MXene与各类纤维与纺织材料进行复合，在纤维基柔性电子材料应用中体现出优异的性能。本文首先介绍了MXene纳米片的制备方法及性能，系统分析了MXene材料与不同维度纤维材料进行复合的最新研究，并总结了MXene/纤维复合材料的各种应用性能。最后，对今后MXene与纤维材料复合应用的前沿及所面临的挑战进行了探讨。
- MXene /
- 纤维材料 /
- 复合应用 /
- 智能纺织品 /
- 超级电容器 /
- 应变传感 /
- 电磁屏蔽
Abstract: Layered transition metal carbonitride (MXene) is a new type of two-dimensional nanomaterials. It has attracted increasing attention due to its unique crystal characteristics and structural characteristics, especially its excellent performance in electrical and electronic applications. In recent years, there have been many studies on the composite applications of MXene and textile materials, their outstanding performance have been found in the applications of fiber-based flexible electronics. This paper introduced the preparation approaches and properties of MXene nanosheets, systematically analyzed the latest research of the composite application of MXene and fibrous materials at different dimensions and then summarized the application performance of MXene-based fibrous composite materials. Finally, the cutting-edge research and current challenges of composite applications of MXene and fibrous materials were discussed.
- MXene /
- fibrous material /
- composite application /
- intelligent textiles /
- supercapacitors /
- strain sensing /
- electromagnetic interference shielding

HTML全文

图 1 MAX相剥离过程和MXene形成示意图^[14]

Figure 1. Schematic for the exfoliation process of MAX phases and formation of MXene^[14]

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图 2 BMX纱制作工艺示意图^[29]

Figure 2. Schematic diagram of BMX yarn manufacturing process^[29]

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图 3 MXene/聚氨酯(PU)纤维纺丝过程示意图^[30]

Figure 3. MXene/polyurethane (PU) fiber spinning process diagram^[30]

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图 4 交替真空过滤的方法制备纤维素纳米纤维(CNF)@Mxene薄膜原理图(a)、折叠后放在植物叶子上的不同形状的数字图像(b)^[28]

Figure 4. Schematic diagram of cellulose nanofiber (CNF)@Mxene thin film prepared by alternating vacuum filtration (a), digital images with different shapes after folding and standing on a plant leaf (b)^[28]

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图 5 碳纤维(CF)-MXene/环氧复合材料的制备工艺^[37]

Figure 5. Preparation process of carbon fiber (CF)-MXene/epoxy composites^[37]

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表 1 MXene与纤维材料结合的应用

Table 1. Application of MXene in combination with fibrous materials

Application	Structure (Dimension)	Method	Performance	Ref.
Supercapacitor	1D	Dipcoating	Conductivity: (440.3±0.9) S·cm⁻¹ (MXene content 77wt%)	^[24]
	1D	Coated twisting	Capacitance: 1083 F·cm⁻³(3188 mF·cm⁻²)	^[29]
	1D	Electrospinning	Capacitance: 205 mF·cm⁻² (50 mV·s⁻¹)	^[26]
Strain sensing fiber	1D	Wet spinning	Strain: 152%, GF: 12900, GF: 238 (50% of the strain)	^[30]
	1D	Dipcoating	GF: 872.79 (200% of the strain) at 6 V, the temperature reached 80℃	^[31]
	2D	Spray drying coating	At 6 V, the temperature reached 150℃, 2wt%, 4wt% GF: 1.16；>6wt% GF: 0.76. In the bending range of 0.86%-2.09%, the GF of the above sensors is increased to 3.18, 2.08 and 1.76, respectively.	^[25]
Conductive fiber	1D	Wet spinning	Conductivity: 750 S·cm⁻¹	^[27]
Electromagnetic shielding	2D	Dipcoating	Conductivity: 1000 S·m⁻¹	^[32]
	2D	Layer by layer self-assembly	EMI: 54 dB (120 μm thickness, X-band) surface resistance: 0.8 Ω·sq⁻¹	^[33]
	1D	Dipcoating	Electrical conductivity: 670.3 S·m⁻¹, EMI:31.04 dB(X-band) at 6 V, the temperature reached 64.3℃	^[34]
	2D	Vacuum filtration	EMI: 55.5 dB, tensile strength: 112.5 MPa, tenacity: 2.7 MJ·m⁻³, EMI: 40 dB (X-band, 0.035 mm), EMI: 7029 dB (K-band, 0.035 mm)	^[28]
Wearable heater	2D	Dipcoating	EMI: 42.1 dB(X-band) at 2.5 V, the temperature reached 110℃ (20 s) at 3.5 V, the temperature reached 174℃ (20 s)	^[35]
Textile conductive electrode	2D	Dipcoating	MXene coated textile electrode ratio capacitance: 182.70 F·g⁻¹: coated textile electrode ratio: 343.20 F·g⁻¹	^[36]
Heat dissipation material	3D	Freeze drying	Thermal conductivity (TC): 9.68 W/(m·K)	^[37]
Notes: EMI—Electro magnetic interference; GF—Guage factor.

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