MoS<sub>2</sub>/MXene纳米复合物的研究进展

谢杭明; 吴汉卿; 何志伟; 孔哲

doi:10.13801/j.cnki.fhclxb.20210701.001

MoS₂/MXene纳米复合物的研究进展

doi: 10.13801/j.cnki.fhclxb.20210701.001

谢杭明^{1, 2,},
吴汉卿^{1, 3,},
何志伟^{1, 2, 3, ,},
孔哲^{1, 2,}

1.
杭州电子科技大学　材料与环境工程学院，杭州 310018
2.
杭州电子科技大学　电子信息学院，杭州 310018
3.
杭州电子科技大学　机械工程学院，杭州 310018

基金项目: 国家自然科学基金(51803043)；杭州电子科技大学科研启动基金(KYS205618119)

详细信息

通讯作者:
何志伟，博士，副研究员，硕士生导师，研究方向为电子信息材料、功能高分子材料等　E-mail：zhiwei.he@hdu.edu.cn

中图分类号: TB333
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- 被引次数: 0
出版历程
- 收稿日期: 2021-05-31
- 修回日期: 2021-06-22
- 录用日期: 2021-06-27
- 网络出版日期: 2021-07-01
- 刊出日期: 2021-03-01

Research progress in MoS₂/MXene nanocomposites

XIE Hangmin^{1, 2
,},
WU Hanqing^{1, 3
,},
HE Zhiwei^{1, 2, 3
, ,},
KONG Zhe^{1, 2
,}

1.
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
2.
College of Electronics Information, Hangzhou Dianzi University, Hangzhou 310018, China
3.
College of Mechanical Engineering, Hangzhou Dianzi University, Hangzhou 310018, China

摘要

摘要: 与单一的二维材料MoS₂和MXene相比，MoS₂/MXene纳米复合物具有优异且稳定的物理化学性能，受到了国内外研究者的广泛关注。本论文对MoS₂/MXene纳米复合物的最新研究现状进行了综述。首先，阐述MoS₂/MXene纳米复合物的制备方法及其优缺点，包括水热法、插层法和热退火法等。其次，介绍MoS₂/MXene纳米复合物在各领域中的应用，包括储能、催化、传感器等。最后，对MoS₂/MXene纳米复合物的未来发展和应用进行了展望。
- 二维材料 /
- MXene /
- 二硫化钼 /
- 纳米复合物 /
- 异质结构 /
- 应用
Abstract: Compared with individual two-dimensional MoS₂ and MXene, MoS₂/MXene nanocomposites show excellent and stable physical and chemical properties, attracting widespread attention among domestic and foreign researchers. This paper reviews recent research progress in MoS₂/MXene nanocomposites. First, the preparation methods of MoS₂/MXene nanocomposites as well as their advantages and disadvantages are elaborated, including hydrothermal methods, intercalation methods and thermal annealing. Then, the applications of MoS₂/MXene composites in various fields are introduced, such as energy storage, catalysis and sensors. In the end, the prospects of future development and application of MoS₂/MXene nanocomposites are proposed.
- two-dimensional material /
- MXene /
- MoS₂ /
- nanocomposite /
- heterostructure /
- application

HTML全文

图 1 利用水热法制备MoS₂/MXene纳米复合物示意图^[20]

Figure 1. Schematic illustration of preparation of MoS₂/MXene nanocomposite via a hydrothermal process^[20]

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图 2 利用插层法制备MoS₂/MXene纳米复合物示意图^[44]

Figure 2. Schematic illustration of preparation of MoS₂/MXene nanocomposite via an intercalation process^[44]

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图 3 基于热退火的MoS₂/MXene复合物合成策略^[50]

Figure 3. Synthesis strategy of MoS₂/MXene composites based on thermal annealing^[50]

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表 1 MoS₂/MXene纳米复合物制备方法的优缺点

Table 1. Advantages and disadvantages of preparation methods for MoS₂/MXene nanocomposites

Preparation methods	Advantages	Disadvantages	Ref.
Hydrothermal	Simple process (one-step hydrothermal method), 3D structure (MoS₂ nanoflakes high crystallinity and have abundant edges)	Long cycle (hydrothermal treatment requires reaction at 200℃ for at least 18 hours), residue of by-products (oxidation products of MXene and the precursor of MoS₂)	[8, 13-14, 16-17, 20-42]
Magneto-hydrothermal	Obtain 1T-MoS₂ (the conductivity is about 10⁵ times that of 2H phase)	Equipment dependence (an instrument that produces magnetic fields is required)	[43]
Intercalation	Simple operation with mixing and filtration, easy control of components and low cost	Single structures, follow-up treatment like exfoliation process and surface modification	[44-48]
Thermal annealing	High purity and good quality (after annealing, ammonium tetrathiomolybdate (ATM) will be converted into MoS₂ and some gases like NH₃ and H₂S)	High energy consumption (freeze drying before annealing, annealed at 400℃ for 3 h under a mixture gas of argon and hydrogen atmosphere)	[49-52]
Solid state sintering	Easy operation and high purity (just calcine the mixture of ATM and MXene)	High energy consumption (calcined at 450℃ and kept standing for 4 h in an atmosphere-protected tube furnace)	[53]
In situ sulfidation	Simple, stable (MoS₂ combines with MXene host through strong covalent bond: Mo—S)	Limitation (MXene is the source of molybdenum), high preparation conditions (heated under Ar flow at 500℃ for 4 h)	[54-56]
Microwave-assisted growth	Simple process, less time-consuming (heated at the desired temperature for 2 h)	Equipment dependence (need special microwave synthesizer)	[57]
Gamma radiation strategy	Fewer toxic chemicals and reaction at room temperature	Equipment dependence and high cost (Gamma ray sources and related devices are required)	[58]
Incipient wetness impregnation	Excellent structures (pore volume increases due to the introduction of MoS₂ into MXene layers)	Complex operation and harsh conditions (calcined at 300℃ under nitrogen)	[59-60]
Chemical conversion	Large-scale production, metal/semiconductor heterostructures	Limitation (only MoS₂/Mo₂C can be prepared), complex operation and harsh conditions (thermal annealing at 840℃ under CH₄ and H₂ using Cu foil as a catalyst)	[61-62]

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表 2 MoS₂/MXene纳米复合物在各领域的应用

Table 2. Application of MoS₂/MXene nanocomposites in various fields

Fields of application		Ref.
Energy storage	Li-ion battery	[17, 22, 51, 53-54, 66]
	Li/Na-ion battery	[49, 67]
	K-ion battery	[24]
	Na-ion battery	[25-27, 29, 45]
	Mg-ion battery	[28]
	Li-S battery	[16]
	Supercapacitor	[23, 43-44, 48, 59]
Catalysis	Electrocatalytic hydrogen evolution	[21, 31-32, 35, 50, 55-58]
	Photocatalytic hydrogen evolution	[8, 14, 30, 33-34, 38, 72]
	N₂ reduction reaction	[37]
	Oxygen reduction reaction and methanol oxidation reaction	[46]
	Hydrodesulfurization	[60]
	Photocatalytic degradation of ranitidine	[13]
Other applications	Antibacterial	[39]
	Microwave absorbing	[20, 40, 42]
	Detection thyroxine (T4)	[47]
	Detection microRNA-182 (miRNA-182)	[41, 73]
	High-efficiency solar steam generation	[36]

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表 3 MoS₂/MXene纳米复合物在储能领域中的应用

Table 3. Application of MoS₂/MXene nanocomposites in energy storage field

Energy storage	Nanocomposites	Preparation methods	Ref.
Li-ion battery	V₄C₃/MoS₂-C(C doped)	Thermal annealing	[51]
	MoS₂/Mo₂TiC₂	In situ sulfidation	[54]
	MoS₂/Ti₃C₂	Hydrothermal	[22]
	MoS₂/Ti₃C₂	–	[66]
	MoS₂/Ti₃C₂	Solid state sintering	[53]
	MoS₂/Ti₃C₂	Hydrothermal	[17]
Li/Na-ion battery	MoS₂/Ti₂CT_x	–	[67]
Li/Na-ion battery	MoS₂/Ti₃C₂	Thermal annealing	[49]
K-ion battery	MoS₂/Ti₃C₂	Hydrothermal	[24]
Na-ion battery	MoS₂/Ta₄C₃	Hydrothermal	[25]
	MoS₂/Ti₃C₂	Intercalation	[45]
	MoS₂/m-C@a-C@Ti₃C₂	Hydrothermal	[26]
	MoS₂/Ti₃C₂	Hydrothermal	[27]
	MoS₂/Nb₂CT_x@C	Hydrothermal	[29]
Mg-ion battery	MoS₂/Ti₃C₂	Hydrothermal	[28]
Li-S battery	1T-2H MoS₂-C/Ti₃C₂	Hydrothermal	[16]
Supercapacitor	MoS₂/Ti₃C₂	Incipient wetness impregnation	[59]
	MoS₂/Ti₃C₂	Intercalation	[48]
	MoS₂/Ti₃C₂	Hydrothermal	[23]
	MoS₂/Ti₃C₂	Intercalation	[44]
	1T-MoS₂/Ti₃C₂	Magneto-hydrothermal	[43]

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表 4 MoS₂/MXene复合物在催化领域中的应用

Table 4. Application of MoS₂/MXene nanocomposites in catalysis

Catalysis	Nanocomposites	Preparation	Ref.
Electrocatalytic hydrogen evolution	MoS₂/Ti₃C₂	Microwave-assisted growth	[57]
	MoS₂/Ti₃C₂	Hydrothermal	[31]
	MoS₂/Ti₃C₂	Gamma radiation strategy	[58]
	1T'-MoS₂/Ti₃C₂	Hydrothermal	[32]
	MoS₂/Ti₃C₂	Thermal annealing	[50]
	MoS₂/Mo₂CT_x	In situ sulfidation	[55]
	MoS₂/Nb₂CT_x	Hydrothermal	[21]
	MoS₂/Mo₂CT_x	In situ sulfidation	[56]
	MoS₂/Mo₂CT_x	Hydrothermal	[35]
	Co-MoS₂/Mo₂CT_x	Thermal annealing	[52]
Photocatalytic hydrogen evolution	CdS-MoS₂-Ti₃C₂	Hydrothermal	[30]
	MoS₂/Ti₃C₂	Hydrothermal	[14, 38, 72]
	Mo_xS@TiO₂@Ti₃C₂	Hydrothermal	[33]
	1T-MoS₂/Ti₃C₂/TiO₂	Hydrothermal	[8]
	MoS₂/Ti₃C₂/TiO₂	Hydrothermal	[34]
N₂ reduction reaction	1T-MoS₂/Ti₃C₂	Intercalation	[37]
Oxygen reduction reaction and methanol oxidation reaction	MoS₂QDs@Ti₃C₂T_xQDs@MMWCNTs	Intercalation	[46]
Hydrodesulfurization	Ni-MoS₂/Ti₃C₂	Incipient wetness impregnation	[60]
Photocatalytic degradation of ranitidine	MoS₂/Ti₃C₂	Hydrothermal	[13]
Notes: QDs—Quantum dots; MMWCNTS—Multi-walled carbon nanotube.

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表 5 MoS₂/MXene纳米复合物的其他应用

Table 5. Research achievements of MoS₂/MXene nanocomposites in other fields

Other applications	Nanocomposites	Preparation	Performance	Ref.
Antibacterial	MoS₂/Ti₃C₂	Hydrothermal	–	[39]
Microwave absorbing	MoS₂/Ti₃C₂(4 mm)	Hydrothermal	EAB (6-10.8 GHz), RL (−51 dB)	[40]
	MoS₂/Ti₃C₂(2 mm)	Hydrothermal	EAB (4.32 GHz), RL (−46.72 dB)	[20]
	CF@MXene@MoS₂ (3.5 mm)	Hydrothermal	EAB (10.4-18.0 GHz), RL (−61.51 dB)	[42]
Detection (T4)	MoS₂/Ti₃C₂	Intercalation	LOD (3.9×10⁻¹⁰ kg/m³)	[47]
Detection (miRNA-182)	MoS₂/Ti₃C₂T_x@AuNPs	Hydrothermal	Linear detection window (1×10⁻¹⁴−1×10⁻⁶ mol/m³), LOD (6.61×10⁻¹⁵ mol/m³)	[73]
Detection (miRNA-182)	MoS₂/Ti₃C₂T_x@AuNPs	Hydrothermal	Linear detection window (1×10⁻¹²−1×10⁻⁷ mol/m³), LOD (4.3×10⁻¹³ mol/m³)	[41]
High-efficiency solar steam generation	MoS₂/Ti₃C₂	Thermal annealing	Evaporation rate (1.36 kg/(m²·h)), conversion efficiency(87.2%)	[36]
Notes: EAB—Effective absorption bandwidth; RL—Reflection loss; LOD—Limit of detection; NPs—Nanoparticles.

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