基于金属有机框架的光子晶体制备与应用研究进展

柳浩; 赵嘉欣; 张耘箫; 金梦婷; 周岚; 刘国金

doi:10.13801/j.cnki.fhclxb.20210531.003

基于金属有机框架的光子晶体制备与应用研究进展

doi: 10.13801/j.cnki.fhclxb.20210531.003

浙江理工大学　纺织科学与工程学院(国际丝绸学院)，杭州 310018

基金项目: 国家自然科学基金(52003242)；浙江省自然科学基金(LQ19E030022；LY20E030006)；浙江理工大学科研启动基金(18012212-Y)；2020年国家级大学生创新创业训练计划项目(202010338003)

详细信息

通讯作者:
刘国金，博士，讲师，硕士生导师，研究方向为光子晶体及其结构生色　E-mail：guojin900618@163.com

中图分类号: O734
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出版历程
- 收稿日期: 2021-04-15
- 录用日期: 2021-05-20
- 网络出版日期: 2021-06-01
- 刊出日期: 2021-10-01

Research progress in the preparation and application of photonic crystals based on metal-organic framework

College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, China

摘要

摘要: 近年来，基于光子晶体优异的光学性能和金属有机框架(MOFs)特殊的多孔结构，使基于MOFs的光子晶体研究备受研究者们的关注。本文综述了近年来MOFs材料及其在光子晶体中的应用研究进展。首先简单介绍了MOFs和光子晶体的基本概况及MOFs与光子晶体相结合的优势，然后阐述了基于MOFs的光子晶体的制备方法，进一步概括了其应用现状，并总结了当前基于MOFs的光子晶体研究所存在的困境，最后展望了其未来的发展方向。这些工作为MOFs材料在光子晶体中的实际应用提供了策略支撑。
- 金属有机框架(MOFs) /
- 多孔结构 /
- 光子晶体 /
- 光学性能 /
- 制备方法
Abstract: In recent years, due to the excellent optical properties of photonic crystals and the special porous structure of metal-organic framework (MOFs), the research of photonic crystals based on MOFs has attracted much attention from researchers. In this paper, the research progress of MOFs and their applications in photonic crystals in recent years were reviewed. Firstly, MOFs, photonic crystals and the advantages of MOFs combined with photonic crystals were briefly introduced. Then, the preparation methods of photonic crystals based on MOFs were described, and their application status was further summarized. Finally, the difficulties existing in the current researches of photonic crystals based on MOFs were summarized, and the future development direction was prospected. These works provide strategic support for the practical application of MOFs-based photonic crystals.
- metal-organic framework (MOFs) /
- porous structure /
- photonic crystals /
- optical properties /
- preparation methods

HTML全文

图 1 金属有机框架(MOFs)的结构模型图^[3]

Figure 1. Structural model diagram of metal-organic framework (MOFs)

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图 2 ZIF-8(a)^[4]、UiO-66的八面体(b)^[5]、MIL-101(c)^[6]、MIL-53(d)^[6]、MOF-5(e)^[7]的结构示意图

Figure 2. Structure diagram of ZIF-8 (a)^[4], UiO-66 octahedron structure (b)^[5], MIL-101 (c)^[6], MIL-53 (d)^[6] and schematic diagram of MOF-5 (e)^[7]

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图 3 一维光子晶体(a)、二维光子晶体(b)、三维光子晶体(c)示意图^[24]

Figure 3. Schematic diagram of one-dimensional photonic crystal (a), two-dimensional photonic crystal (b) and three-dimensional photonic crystals (c)^[24]

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图 4 ZIF-8/TiO₂光子薄膜截面SEM图像及对应的UV-Vis反射光谱^[27]

Figure 4. SEM images of cross section of ZIF-8/TiO₂ photonic film and corresponding UV-Vis reflection spectrum^[27]

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图 5 Cu-1,3,5 苯三甲酸(BTC)合成路线示意图^[33]

Figure 5. Schematic diagram of Cu-benzene tricarbonic acid (BTC) synthesis route^[33]

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图 6 蒸发沉积示意图

Figure 6. Schematic diagram of evaporation deposition

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图 7 垂直沉积示意图

Figure 7. Schematic diagram of vertical deposition

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图 8 ZIF-8颗粒(左)和ZIF-8@光子晶体(右)的SEM图像^[37]

Figure 8. SEM images of ZIF-8 particles (left) and ZIF-8@ photonic crystals (right)^[37]

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图 9 重力沉降法示意图

Figure 9. Schematic diagram of gravity settlement method

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图 10 MCC光学传感器件制备流程^[4]

Figure 10. Preparation process of MOF coated ultra-thin MCC optical sensor^[4]

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图 11 基于MOFs的蛋白石型光子晶体的制备过程^[40]

Figure 11. Preparation process of opal photonic crystals based on MOFs^[40]

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图 12 基于MOFs的反蛋白石型光子晶体的制备过程^[41]

Figure 12. Preparation process of MOFs-based inverse opal photonic crystals^[41]

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图 13 HKUST-1@光子晶体在暴露于乙醇蒸汽之前和之后的UV-Vis光谱(a)；ZIF-8@光子晶体暴露于甲醇蒸汽之前和之后的UV-Vis光谱(b)^[41]

Figure 13. UV-Vis spectra of HKUST-1@photonic crystals before and after exposure to ethanol vapor (a); UV-Vis spectra of ZIF-8@photonic crystals before and after exposure to methanol vapor (b)^[41]

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图 14 ZIF@PS阵列(a)和ZIF-8阵列(b)的响应时间^[42]

Figure 14. Response time of ZIF@PS array (a) and ZIF-8 array (b)^[42]

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图 15 吸收CS₂分子前后，基于HKUST-1的光子晶体复合材料的近红外区吸收峰变化(a)；基于HKUST-1的光子晶体复合材料在近红外区的吸收峰偏移大小和CS₂称线性正相关(b)；基于HKUST-1的光子晶体复合材料对不同蒸汽的传感(c)^[26]

Figure 15. Changes of absorption peaks in the near infrared region of HKUST- based photonic crystal composites before and after absorption of CS₂ molecules (a); Absorption peak deviation of HKUST-1 based photonic crystal composites in the near infrared region is linear positive correlation with CS₂ (b); Sensing of different vapors by photonic crystal composites based on HKUST-1 (c)^[26]

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