金属-有机骨架抗菌复合材料与纤维的研究进展及应用

裴震; 郭建栋; 张倩; 张爱琴; 贾虎生; 许并社

doi:10.13801/j.cnki.fhclxb.20210507.001

金属-有机骨架抗菌复合材料与纤维的研究进展及应用

doi: 10.13801/j.cnki.fhclxb.20210507.001

裴震^{1, 3,},
郭建栋^{2, 3,},
张倩^{1, 3,},
张爱琴^{1, 3, ,},
贾虎生^{2, 3,},
许并社^3,

1.
太原理工大学　轻纺工程学院，晋中 030600
2.
太原理工大学　材料科学与工程学院，太原 030024
3.
新材料界面科学与工程教育部重点实验室，太原 030024

基金项目: 国家自然科学基金(21972103；61904120)；山西省重点研发计划社会发展项目(201803D31042)；山西省应用基础研究计划面上项目(201901D111111；201801D221124)

详细信息

通讯作者:
张爱琴，博士，副教授，硕士生导师，研究方向为功能纤维　E-mail：ZAQ6014567@126.com

中图分类号: TB332
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- 文章访问数: 1607
- HTML全文浏览量: 613
- PDF下载量: 171
- 被引次数: 0
出版历程
- 收稿日期: 2021-03-17
- 录用日期: 2021-04-27
- 网络出版日期: 2021-05-07
- 刊出日期: 2021-08-15

Research progress and application of metal-organic frameworks antibacterial composite materials and fibers

PEI Zhen^{1, 3
,},
GUO Jiandong^{2, 3
,},
ZHANG Qian^{1, 3
,},
ZHANG Aiqin^{1, 3
, ,},
JIA Husheng^{2, 3
,},
XU Bingshe^3
,

1.
College of Textile and Engineering, Taiyuan University of Technology, Jinzhong 030600, China
2.
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
3.
Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, Taiyuan 030024, China

摘要

摘要: 金属-有机骨架(MOFs)抗菌材料因其具有比表面积大、孔隙率高且孔径可调及良好的生物相容性等优点而备受关注，是开发高效可循环使用抗菌医护口罩的热点材料。本文首先分析了MOFs抗菌复合材料的特点及其抗菌机制，然后综述了Ag、Cu、Zn基几类常用MOFs抗菌复合材料及其纤维的研究进展，最后探讨了MOFs抗菌功能纺织品在医疗卫生方面的应用，展望了MOFs抗菌复合纤维在医护口罩方面的潜在应用价值。
- MOFs抗菌材料 /
- 抗菌机制 /
- 纤维 /
- 功能纺织品 /
- 医护口罩
Abstract: Metal-organic frameworks (MOFs) antibacterial materials have attracted much attention owing to the advantages such as their large specific surface area, high porosity, adjustable pore size, and good biocompatibility. They are hot materials for the development of efficient and recyclable antibacterial surgical mask. Firstly, this paper analyzed the characteristics of MOFs antibacterial composite materials and their antibacterial mechanism. Then, it summarized the research progress of several types of common MOFs antibacterial composite materials and their fibers based on Ag, Cu, Zn. At last, it discussed the application of MOFs antibacterial functional textiles in the medical treatment and public health, and prospected the potential application value of MOFs antibacterial composite fibers in surgical mask.
- MOFs antibacterial materials /
- antibacterial mechanism /
- fibers /
- functional textiles /
- surgical mask

HTML全文

图 1 金属-有机骨架(MOFs)材料光催化抗菌机制^[8]

Figure 1. Photocatalytic antibacterial mechanism of metal-organic frameworks (MOFs) materials^[8]

下载: 全尺寸图片幻灯片

图 2 1,3,5-均苯三羧酸铜(HKUST-1)抗菌水凝胶对大鼠伤口的愈合效果^[36]

Figure 2. Effect of 1-(2-methyl-4-(2-oxopyrrolidin-1-yl) phenyl)-3-morpholino-5,6-dihydropyridin-2(1H)-one (HKUST-1) antibacterial hydrogel on wound healing in rats^[36]

PBS—Phosphate buffer saline

下载: 全尺寸图片幻灯片

图 3 基于2-甲基咪唑锌盐(ZIF-8)的集成式空气过滤示意图及抗菌口罩^[9]

Figure 3. Schematic diagram of integrated air filter based on 2-methyl imidazole zinc salt (ZIF-8)^[9]

ROS—Reactive oxygen species

下载: 全尺寸图片幻灯片

图 4 纳米Cu@ZIF-8口罩示意图^[39]

Figure 4. Schematic diagram of nano Cu@ZIF-8 mask^[39]

下载: 全尺寸图片幻灯片

表 1 MOFs抗菌材料与纤维的复合方法及优缺点

Table 1. Composite methods and advantages and disadvantages of MOFs antibacterial materials and fibers

Composite method	Advantage	Disadvantage
Direct coating	Simple operation, economical and convenient	Poor binding fastness, antibacterial agent is easy to fall off
Blend spinning	Firmly bound to the fibers, the fiber structure can be finely regulated to increase, surface active sites	Low fiber strength, low actual output
In situ growth	High fiber strength, strong combination with fibers	Growth conditions harsh, tedious process

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